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151.
Regulatory authorities require estimates of ambient background concentrations (ABCs) of potentially harmful elements (PHEs) in topsoil; such data are currently not available in many countries. High resolution soil geochemical data exist for only part of England and Wales, whilst stream sediment data cover the entire landscape. A novel methodology is presented for estimating soil equivalent ABCs for PHEs from high-resolution (HR) stream sediment geochemical data grouped by common parent materials (PM), using arsenic (As) as an example. Geometric mean (GM) values for local PM groups are used to investigate different approaches for transforming sediment to soil equivalent concentrations. Holdout validation is used to assess: (i) the optimum number of samples for calculating local GM values, and (ii) the optimum scale at which to group data when using linear regression analysis to estimate GM soil ABCs from local sediment geochemical values. Holdout validation showed that the smallest differences were generally observed when five observations were used to calculate the GM and that these should be grouped over the smallest possible area in order to encompass soils over PMs with elevated GM As concentrations. Geometric mean ABCs are estimated and mapped for As in mineral soil across all of England and Wales within delineations of PM polygons. Errors for the estimation of soil equivalent GM As ABCs based on sediment data for an independent validation set were of a similar magnitude to those from holdout validation applied to the original data suggesting the approach is robust. The estimates of soil equivalent ABCs suggest that As exceeds the regulatory threshold used in risk assessments for residential land use (20 mg kg−1) across 16% of the landscape of England and Wales. The applicability of the method for cognate landscapes, and potential refinements is discussed. 相似文献
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H. M. Hussein K. M. Abou Elenean I. A. Marzouk A. Peresan I. M. Korrat E. Abu El-Nader G. F. Panza M. N. El-Gabry 《Natural Hazards》2008,47(3):525-546
The aim of the present work is to compile and update a catalogue of the instrumentally recorded earthquakes in Egypt, with
uniform and homogeneous source parameters as required for the analysis of seismicity and seismic hazard assessment. This in
turn requires a detailed analysis and comparison of the properties of different available sources, including the distribution
of events with time, the magnitude completeness, and the scaling relations between different kinds of magnitude reported by
different agencies. The observational data cover the time interval 1900–2004 and an area between 22°–33.5° N and 25°–36° E.
The linear regressions between various magnitude types have been evaluated for different magnitude ranges. Using the best
linear relationship determined for each available pair of magnitudes, as well as those identified between the magnitudes and
the seismic moment, we convert the different magnitude types into moment magnitudes M
W, through a multi-step conversion process. Analysis of the catalogue completeness, based on the M
W thus estimated, allows us to identify two different time intervals with homogeneous properties. The first one (1900–1984)
appears to be complete for M
W ≥ 4.5, while the second one (1985–2004) can be considered complete for magnitudes M
W ≥ 3. 相似文献
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Whole rock RbSr measurements were made on associatedbasic and acid intrusives and extrusives from the northern andsouthern ends of the Lebombo monocline with a view to determineif the acid rocks came from the mantle or from the crust. Inthe south, in Swaziland (now called Ngwame) and Zululand, rhyolitesand granophyres (age 202 14 m.y.) have an initial Si87Sr86ratio of 0.7042 0.0005; in the north, in the Nuanetsi syncline,rhyolites (age 206 13 m.y.) and granites from ring complexes(age 177 7 m.y.) have initial ratios of 0.7081 0.0008 and0.7085 0.0007, respectively. The initial ratios of the basicrocks, basalts and gabbros, vary in both areas and have a rangefrom 0.7042 to 0.7125 which can be explained by crustal contamination.The low initial ratios and isotopic homogeneity of the acidmagmas over long distances (160 km) in Swaziland and Zululandare interpreted as implying that they were derived from themantle. 相似文献
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I. Iovtschev 《Mineralium Deposita》1966,1(3):251-257
Résumé On peut, en résumé, caractériser ainsi les principales provinces de la Bulgarie: — les Rhodopes constituent une zone typiquement polymétallique avec une prépondérance soulignée de Pb, Zn; le F, Cr, Ni, y existent en quantité subordonnée; en traces viennent encore: le Ba, Mn, Cd, Sb, W, Mo, Bi, As, Au, Ag, V; — la Sredna Gora est caractérisée comme une zone de cuivre typique, avec la présence de Fe, Mn, et en quantitée subordonnée de Pb, Zn, Mo, Ti, V, Au. — les Balkans portent les particularités d'une zone polymétallique (Pb, Zn, Cu) avec fer. On y remarque souvent des gîtes individualisés de cuivre, polymétallique avec fer, argent, ainsi que des gîtes complexes. Le Mn, Ba, Au, Ag, Co, Mo, As, Hg, V, W viennent en quantité subordonnée; — la zone des Kraistides, analogue à la précédente, se caractérise par des gisements polymétalliques pauvres et des gîtes à or et scheelite. Les éléments principaux sont: Au, Ba et secondaires: Pb, Zn, Cu, V et en partie du Fe et Hg; — la plateforme mésique, outre le gaz, se caractérise par le manganèse de la dépression de Varna.
The metallogenic map of Bulgaria displays the following four major and distinct provinces: The Rhodopes as a typically polymetallic zone, mainly with Pb and Zn, but also with F, Cr and Ni, and minor or trace amounts of Ba, Mn, Cd, Sb, Mo, Bi, As, Au, Ag, V. The Sredna-gora is a distinct copper zone, with Fe and Mn, and minor amounts of Pb, Zn, Mo, Ti, V, Au. The Balkan is again a polymetallic zone of Pb, Zn and Cu with Fe; but Cu-Fe-Ag-deposits also occur. The other elements are present in minor quantities only. The Kraiste-Zone resembles the previous one and contains low grade polymetallic and scheelite deposits. The main elements are Au, Ba, and minor quantities of Pb, Zn, Cu, V and in part Fe and Hg. The zone of the Mésie platform contains only the manganese deposits of the Varna depression, in addition to natural gas.相似文献