Source identification of PM2.5 particles measured in Gwangju, Korea

The UNMIX and Chemical Mass Balance (CMB) receptor models were used to investigate sources of PM_2.5 aerosols measured between March 2001 and February 2002 in Gwangju, Korea. Measurements of PM_2.5 particles were used for the analysis of carbonaceous species (organic (OC) and elemental carbon (EC)) using the thermal manganese dioxide oxidation (TMO) method, the investigation of seven ionic species using ion chromatography (IC), and the analysis of twenty-four metal species using Inductively Coupled Plasma (ICP)-Atomic Emission Spectrometry (AES)/ICP-Mass Spectrometry (MS). According to annual average PM_2.5 source apportionment results obtained from CMB calculations, diesel vehicle exhaust was the major contributor, accounting for 33.4% of the measured PM_2.5 mass (21.5 μg m^− 3), followed by secondary sulfate (14.6%), meat cooking (11.7%), secondary organic carbon (8.9%), secondary nitrate (7.6%), urban dust (5.5%), Asian dust (4.4%), biomass burning (2.8%), sea salt (2.7%), residual oil combustion (2.6%), gasoline vehicle exhaust (1.9%), automobile lead (0.5%), and components of unknown sources (3.4%). Seven PM_2.5 sources including diesel vehicles (29.6%), secondary sulfate (17.4%), biomass burning (14.7%), secondary nitrate (12.6%), gasoline vehicles (12.4%), secondary organic carbon (5.8%) and Asian dust (1.9%) were identified from the UNMIX analysis. The annual average source apportionment results from the two models are compared and the reasons for differences are qualitatively discussed for better understanding of PM_2.5 sources.Additionally, the impact of air mass pathways on the PM_2.5 mass was evaluated using air mass trajectories calculated with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) backward trajectory model. Source contributions to PM_2.5 collected during the four air mass patterns and two event periods were calculated with the CMB model and analyzed. Results of source apportionment revealed that the contribution of diesel traffic exhaust (47.0%) in stagnant conditions (S) was much higher than the average contribution of diesel vehicle exhaust (33.4%) during the sampling period. During Asian dust (AD) periods when the air mass passed over the Korean peninsula, Asian dust and secondary organic carbon accounted for 25.2 and 23.0% of the PM_2.5 mass, respectively, whereas Asian dust contributed only 10.8% to the PM_2.5 mass during the AD event when the air mass passed over the Yellow Sea. The contribution of biomass burning to the PM_2.5 mass during the biomass burning (BB) event equaled 63.8%.     

Dynamics of sea-surface temperature anomalies in the Southern Ocean diagnosed from a 2D mixed-layer model

We analyze the processes responsible for the generation and evolution of sea-surface temperature anomalies observed in the Southern Ocean during a decade based on a 2D diagnostic mixed-layer model in which geostrophic advection is prescribed from altimetry. Anomalous air–sea heat flux is the dominant term of the heat budget over most of the domain, while anomalous Ekman heat fluxes account for 20–40% of the variance in the latitude band 40°?60°S. In the ACC pathway, lateral fluxes of heat associated with anomalous geostrophic currents are a major contributor, dominating downstream of several topographic features, reflecting the influence of eddies and frontal migrations. A significant fraction of the variability of large-scale SST anomalies is correlated with either ENSO or the SAM, each mode contributing roughly equally. The relation between the heat budget terms and these climate modes is investigated, showing in particular that anomalous Ekman and air–sea heat fluxes have a co-operating effect (with regional exceptions), hence the large SST response associated with each mode. It is further shown that ENSO- or SAM-locked anomalous geostrophic currents generate substantial heat fluxes in all three basins with magnitude comparable with that of atmospheric forcings for ENSO, and smaller for the SAM except for limited areas. ENSO-locked forcings generate SST anomalies along the ACC pathway, and advection by mean flows is found to be a non-negligible contribution to the heat budget, exhibiting a wavenumber two zonal structure, characteristic of the Antarctic Circumpolar Wave. By contrast SAM-related forcings are predominantly zonally uniform along the ACC, hence smaller zonal SST gradients and a lesser role of mean advection, except in the SouthWest Atlantic. While modeled SST anomalies are significantly correlated with observations over most of the Southern Ocean, the analysis of the data-model discrepancies suggests that vertical ocean physics may play a significant role in the nonseasonal heat budget, especially in some key regions for mode water formation.     

A semi-continuous measurement of gaseous ammonia and particulate ammonium concentrations in PM<Subscript>2.5</Subscript> in the ambient atmosphere

Ammonia has a short residence time in the atmosphere and rapidly neutralizes acid gases that occur near its source, requiring a rapid measurement system for ammonia and particulate ammonium concentrations to better understand their sources, temporal variation of ammonia emissions, and the formation of secondary ammonium aerosols. A semi-continuous measurement system, consisting of a diffusion scrubber, a particle growth chamber, an air-liquid separator, and a fluorescent detector, was developed to determine both gaseous ammonia (NH₃) and particulate ammonium (NH ₄ ⁺ ) in PM_2.5 in the ambient atmosphere of Gwangju, South Korea, during the months of March, April, July, and September of 2007. During the sampling periods, the average concentrations of ammonia and ammonium were found to be 2.33?±?1.29 μg/m³ and 1.89?±?0.99 μg/m³, respectively. Although the average gaseous ammonia concentration was highest in March, the particulate ammonium concentration was higher during the warmer season, reaching 2.08?±?1.07 μg/m³ and 2.32?±?0.94 μg/m³ in April and July, respectively, while only 1.68?±?0.61 μg/m³ in March and 1.24?±?0.99 μg/m³ in September. It is proposed that the higher availability of acid species during the warmer months produced a significant amount of particulate ammonium sulfate. Diurnal fluctuation of ammonia and ammonium during the warmer months showed that their peak time occurred at approximately 10:00 am. Both ammonia and ammonium concentrations were better correlated during the warmer months than during the cooler months. Further, the data suggest that the ammonia and ammonium were measured under well dispersed conditions, and multiple sources contributed to the ammonia at the sampling site.     

Focal mechanisms of recent earthquakes in the Southern Korean Peninsula

We evaluate the stress field in and around the southern Korean Peninsula with focal mechanism solutions, using the data collected from 71 earthquakes ( M_L = 1.9–5.2) between 1999 and 2004. For this, the hypocentres were relocated and well-constrained fault plane solutions were obtained from the data set of 1270 clear P -wave polarities and 46 SH / P amplitude ratios. The focal mechanism solutions indicate that the prevailing faulting types in South Korea are strike-slip-dominant-oblique-slip faultings with minor reverse-slip component. The maximum principal stresses (σ₁) estimated from fault-slip inversion analysis of the focal mechanism solutions show a similar orientation with E–W trend (269°–275°) and low-angle plunge (10°–25°) for all tectonic provinces in South Korea, consistent with the E–W trending maximum horizontal stress (σ_Hmax) of the Amurian microplate reported from in situ stress measurements and earthquake focal mechanisms. The directions of the intermediate (σ₂) and minimum (σ₃) principal stresses of the Gyeongsang Basin are, however, about 90 deg off from those of the other tectonic provinces on a common σ₂–σ₃ plane, suggesting a permutation of σ₂ and σ₃. Our results incorporated with those from the kinematic studies of the Quaternary faults imply that NNW- to NE-striking faults (dextral strike-slip or oblique-slip with a reverse-slip component) are highly likely to generate earthquakes in South Korea.     

Nitrogen budget of the eelgrass, Zostera marina in a bay system on the south coast of Korea

Above- and below-ground productivities and tissue N content were measured monthly to quantify N incorporation to sustain eelgrass growth in Koje Bay on the south coast of Korea from January to December 2002. N acquisition was also estimated through measurements of N uptake kinetics, tissue biomass, and in situ inorganic N concentrations in water column and sediments. Above- and below-ground productivities were highest in summer and lowest in late fall and winter. Leaf tissue N content was highest in December and lowest in July, while rhizome tissue N content was highest in October and lowest in April. Estimated monthly N incorporation by leaf tissues based on the leaf productivity and N content ranged from 0.4 g N m^?2 month^?1 in November to 2.0 g N m^?2 month^?1 in May. N incorporation by below-ground tissues ranged from 0.1 g N m^?2 month^?1 in February to 0.2 g N m^?2 month^?1 in October. Annual whole plant N incorporation was 14.5 g N m^?2 y^?1, and N incorporation by leaf tissues accounted for about 87 % of total N incorporation. Maximum uptake rate (V _max ) and half saturation constant (K _m ) of leaf NH₄ ⁺ uptake were significantly lower than those of root NH₄ ⁺ uptake. Above- and below-ground biomass ranged from 20.8 g DW m^?2 and 8.6 g DW m^?2 in winter to 350.0 g DW m^?2 and 81.3 g DW m^?2 in spring, respectively. NH₄ ⁺ concentrations varied from 0.2 to 4.3 mM in water column and from 93.0 to 551.7 mM in sediment pore water. Based on these measurements, annual N acquisition by root tissues contributed slightly higher than that by leaf tissues to total plant N acquisition. During winter, monthly leaf N acquisition was lower than monthly leaf N incorporation. This implies that Z. marina has internal nitrogen retention system to offset the shortage and excess of nitrogen.     

Distribution of deep near-inertial waves observed in the Kuroshio Extension

The distribution of deep near-inertial waves (NIWs) is investigated using data mainly from an array of 46 near-bottom acoustic current meter sensors spanning a 600 km × 600 km region as part of the Kuroshio Extension System Study during 2004–2006. The deep NIW distribution is interpreted in the context of both upper-layer and near-bottom mapped circulations. The wintertime-mean mixed-layer NIW energy input, modeled from observed wind stress, has the same range of values north and south of the Kuroshio Extension in this region. Yet, the wintertime-mean deep NIW energy distribution reveals a sharp factor-of-5 decrease from north to south of the Kuroshio jet. This direct observational evidence shows that the Kuroshio Extension blocks the equatorward propagation of NIWs. The NIW energy that does reach the sea floor within the subset of wintertime observations in the subtropical gyre arrives with patchy spatial and temporal distribution. Elevated NIW energy in deep water is associated with anticyclones in the deep barotropic flow and unassociated with upper layer eddies.     

Benthic habitat quality change as measured by macroinfauna community in a tidal flat on the west coast of Korea

Yellow Sea tidal flats are internationally recognised for their contribution to biological diversity and yet are under enormous pressure from reclamation, pollution and overexploitation. The benthic macroinfauna community is the dominant community on these tidal flats and a reliable indicator of benthic environmental changes. We surveyed the current benthic macroinfauna community of the Ganghwa Southern Tidal Flat, the largest remaining Korean mud flat in the Yellow Sea, in order to examine changes in the environmental situation of this benthic ecosystem. The results show a significant decline in species diversity from the last survey made in 2003, and a shift in species composition with appearances of polychaetes indicative of pollution and physical disturbances and other opportunistic species becoming dominant in both density and biomass. The benthic community shift observed during the two study periods may be associated with increased nutrient pollution as well as increased physical disturbances in this area. However, we recognise the limitations of the data both in frequency and scope but believe the significant changes to the composition of the benthic fauna are sufficient to warrant concern. Observations are required to examine the extent to which these human activities induce benthic community shift in this tidal flat.     

Pathologic survey on the Manila clam <Emphasis Type="Italic">Ruditapes philippinarum</Emphasis> (Adams and Reeve 1850) from Haeju off the western coastal Yellow Sea

Pathologic condition of Manila clam, Ruditapes philippinarum collected from Haeju off the west coast of North Korea in February and March 2007 was investigated in this study. The diagnostics included a protozoan parasite, Perkinsus olseni, the brown ring disease (BRD) caused by bacteria Vibrio tapetis and metazoan parasites Trematod and Cestod. P. olseni infection was examined using histology and Ray’s fluid thioglycollate medium (RFTM) assay along with Choi’s NaOH digestion technique. Trematode and cestode infection was also examined from the histology. A total of 140 clams with 35–45 mm in shell length (2–3 years old) were analyzed. Condition factor (CF), a ratio of the wet tissue weight to the shell dry weight, ranged from 0.445±0.074 (February) to 0.544±0.132 (March). Total body burden of P. olseni (i.e. infection intensity) ranged from 18,644±37,755 (February) to 26,933±80,611 cells/g wet tissue (March) with the prevalence of 76.7–43.3% (March) respectively. Prevalence of trematode and cestode infection in February and March varied 22.5–25.0 and 15.0–22.5% respectively. Infection intensity of V. tapetis ranged 1–2 and the prevalence was 1.4 (February) and 5.7% (March). Prevalence and infection intensity of P. olseni in clams from Haeju was comparatively lower than those of clams reported on the west coast of Korea. BRD and the other metazoan parasite infection were also relatively lower or similar to the condition of the clams reported previously. CF of Haeju clams was also relatively higher than the clams in Gyeonggi Bay and Taean, suggesting that Haeju clams had relatively better pathologic and health condition.     

Optimal design of two-dimensional wings in ground effect using multi-objective genetic algorithm

The shape optimization of the 2-dimensional wing in ground effect (WIG) has been performed by the integration of CFD (computational fluid dynamics) and MOGA (multi-objective genetic algorithm). Because of the trade-off between the aerodynamic forces and the height stability, it is difficult to satisfy the design requirements of efficiency and stability at the same time. In this study, the lift coefficient, the lift-drag ratio and the static height stability are chosen as the objective functions to obtain the optimal wing profiles of a WIG craft. An NACA0015 airfoil is used for the baseline model; the aerodynamic characteristics of the base model are compared with that of the optimal solutions. The profile of the airfoil is constructed by four Bezier curves with fourteen control points resulting in the eighteen coordinates, which are adopted as the design variables. The optimal solutions of the multi-objective optimization are not unique but a set of the non-dominated optima: the Pareto frontiers or a Pareto set. As the results of the multi-objective optimization, the forty Pareto optima, which include high-lift, high-efficiency, and more stable airfoils on the edge of the 3-dimensional objective space, are obtained at thirty evolutions of the generation.