Immobilization of As and Pb in contaminated sediments using waste resources

As and Pb-contaminated sediment obtained from the Nakdong Lake and Yeongsan River in the Republic of Korea was stabilized using a combination of calcined oyster shell (COS), waste cow bone (WCB) and coal mine drainage sludge (CMDS). The effectiveness of the stabilization treatment was evaluated using the Korean Standard Test (KST). The KST tests were performed using 1 N HCl extraction fluid for As and 0.1 N HCl extraction fluid for Pb. Scanning electron microscopy–energy dispersive X-ray spectroscopy (SEM–EDX) analyses were performed to investigate the mechanism responsible for As and Pb immobilization upon treatment. The treatment results showed that effective stabilization of As and Pb-contaminated sediment was obtained. Specifically, 10 wt% COS–5 wt% CMDS was the best treatment for As immobilization and 5 wt% COS–5 wt% WCB was the best treatment for Pb immobilization. The COS–WCB treatment outperformed the COS–CMDS treatment in immobilizing Pb in the contaminated sediment. SEM–EDX results indicated that Pb immobilization was strongly associated with Ca, Si, Al and P while As immobilization was strongly associated with Fe and O. Therefore, utilization of COS, WCB and CMDS is beneficial for the stabilization of contaminated sediment.     

Simultaneous stabilization of arsenic, lead, and copper in contaminated soil using mixed waste resources

In the present study, stabilization treatment using waste resource stabilizers was performed for soil contaminated with As and heavy metals (Pb and Cu). Calcined oyster shell (COS) and coal mine drainage sludge (CMDS) were used as a mixed stabilizing agent for a wet-curing duration of 28 days. After the stabilization treatment, the treatment process efficiency was evaluated by the results of various batch- and column-leaching tests. Neutral and weak acid extraction methods, such as water-soluble extraction and SPLP, did not exhibit satisfactory results for heavy metal stabilization, even if they showed very low leachability. On the other hand, TCLP and 0.1 M HCl extraction showed that the stabilizers significantly reduced the amount of heavy metals leached from the soil, which strongly supports the thesis that the stabilization treatment is efficient in the acidic leaching conditions that were explored. Specifically, in the 0.1 M HCl extraction, the reduction efficiencies of As, Pb, and Cu leachings were more than 90 %, compared with control experiments. This study demonstrates that the application of waste resources for the stabilization of As and heavy metals is feasible. However, some limitations observed in the experiments should be considered in future studies, such as the mobilization of alkali-soluble elements, and in particular, exchangeable fractions of Cu. In addition, the treatment efficiency can be evaluated by different leaching methods, which suggests that multidirectional approaches are required for the proper evaluation of stabilization treatment.     

Comparison of the Ordovician-Carboniferous Boundary Between Korea and NE China: Implications for Correlation and Tectonic Evolution

There is a great hiatus between Ordovician and Carboniferous strata in the Northeast China and Korean Peninsula. In order to understand geology and tectonic evolution, and to find out the similarities and differences in both regions, two sections in the Western Hill near Beijing in NE China and several sections in the Korean Peninsula were selected to examine their geologic boundaries between Lower and Upper Paleozoic strata to compare their characteristic features. At four sites in the two sections in the Western Hill near Beijing were examined their contact relations. The Hui Yu section is the same horizon where one site is top of a quarry hill and the other of down hill. Mid-Carboniferous Qingshuijian Formation rests on the Ordovician Majiagou Formation. Limestone beds are more commonly intercalated with shale and sandstone at site 2 of the Hui Yu section, while at site 1, conglomerate beds are dominant. Site 1 of the Se Shu Fen section shows eroded and concealed karst topography and conglomerate beds are intercalated within shale beds. Silurian and Devonian strata are absent in these areas. In the Korean Peninsula, most O-C contacts occur between Ordovician limestone formation and Carboniferous strata, although Silurian strata occur beneath the Carboniferous strata in the Jeongseon area and Pyeongnam Basin. Most contact relations are parallel unconformity and angular unconformity is rarely seen. The O-C relations in both regions are similar to each other, and these indicate that the Korean Peninsula was located near or belonged to the Sino-Korean paraplatform during Paleozoic time.     

Petrology of the Yugu peridotites in the Gyeonggi Massif,South Korea: Implications for its origin and hydration process

Peridotites exposed in the Yugu area in the Gyeonggi Massif, South Korea, near the boundary with the Okcheon Belt, exhibit mylonitic to strongly porphyroclastic textures, and are mostly spinel lherzolites. Subordinate dunites, harzburgites, and websterites are associated with the lherzolites. Amphiboles, often zoned from hornblende in the core to tremolite in the rim, are found only as neoblasts. Porphyroclasts have recorded equilibrium temperatures of about 1000°C, whereas neoblasts denote lower temperatures, about 800°C. Olivines are Fo_90–91 in lherzolites and Fo₉₁ in a dunite and a harzburgite. The Cr# (= Cr/(Cr + Al) atomic ratio) of spinels varies together with the Fo of olivines, being from 0.1 to 0.3 in lherzolites and around 0.5 in the dunite and harzburgite. The Na₂O content of clinopyroxene porphyroclasts is relatively low, around 0.3 to 0.5 wt% in the most fertile lherzolite. The Yugu peridotites are similar in porphyroclast mineral chemistry not to continental spinel peridotites but to sub‐arc or abyssal peridotites. Textural and mineralogical characteristics indicate the successive cooling with hydration from the upper mantle to crustal conditions for the Yugu peridotites. Almost all clinopyroxenes and amphiboles show the same U‐shaped rare earth element (REE) patterns although the level is up to ten times higher for the latter. The hydration was associated with enrichment in light REE, resulting from either a slab‐derived fluid or a fluid circulating in the crust. The mantle‐wedge or abyssal peridotites were emplaced into the continental crust as the Yugu peridotite body during collision of continents to form a high‐pressure metamorphic belt in the Gyeonggi Massif. The peridotites from the Gyeonggi Massif exhibit lower‐pressure equilibration than peridotites, with or without garnets, from the Dabie–Sulu Collision Belt, China, which is possibly a westward extension of the Gyeonggi Massif.     

Early Cretaceous paleogeography of Korea and Southwest Japan inferred from occurrence of detrital chromian spinels

The Sindong Group was deposited in the north–south trending half‐graben Nakdong Trough, southern Korean peninsula. The occurrence of detrital chromian spinels from the Jinju Formation of the Sindong Group in the Gyeongsang Basin means that the mafic to ultramafic rocks were exposed in its provenance. The chromian spinels from the Jinju Formation are characterized by extremely low TiO₂ and Fe³⁺. Moreover, their range of Cr# is from 0.45 to 0.80 and makes a single trend with Mg#. The chemistry of chromian spinels implies that the source rocks for chromian spinels were peridotites or serpentinites, which originated in the mantle wedge. To more narrowly constrain their source rocks, the Ulsan and Andong serpentinites exposed in the Gyeongsang Basin were examined petrographically. Chromian spinels in the Andong serpentinite differ from those of the Jinju Formation and those in the Ulsan serpentinite partly resemble them. Furthermore, the Jinju chromian spinel suite is similar to the detrital chromian spinels from the Mesozoic sediments in the Circum‐Hida Tectonic zone, which includes the Nagato Tectonic zone in Southwest Japan and the Joetsu Belt in Northeast Japan. This suggests that the basement rocks, which were located along the main fault bounding the eastern edge of the Nakdong Trough, had exposures of peridotite or serpentinite. It is possible that the Nakdong Trough was directly adjacent to the Circum‐Hida Tectonic zone before the opening of the Sea of Japan (East Sea).     

Results of the study of anisotropy of elastic properties of rocks from the Luchlompolo fault zone (Pechenga region,Kola Peninsula)

Elastic characteristics of rock samples from the Luchlompolo fault zone taken from outcrop surfaces are compared with elastic characteristics of core samples of the Kola ultradeep borehole taken in an analogous interval. An inversion consisting of a discrepancy between the schistosity levels of rocks in the borehole (below the Luchlompolo fault) and their analogues at the surface (above the fault) is explained by a considerable difference in the force actions that caused the schistosity and layering of rocks in the borehole and at the surface. A kinematic scheme of the fault is constructed, and a hypothesis about the existence of an inversion point (region) in the fault zone and its probable collecting properties is put forward.An inverse dependence of variations in density characteristics of rocks on acoustic dichroism and their elastic anisotropy coefficient for transverse waves is established for the first time.     

Porous dust grains in the shells of Herbig Ae/Be stars

The transfer of polarized radiation in inhomogeneous circumstellar shells with a spheroidal spatial distribution of porous dust particles is computed. The grains are modeled by an MRN mixture of silicate and graphite particles. The optical properties of porous particles (considered separately in the Appendix) are computed by using effective medium theory and Mie theory. The following observational characteristics have been computed for WW Vul, a typical Herbig Ae star with Algol-like minima: the spectral energy distribution from the ultraviolet to the far infrared, the color-magnitude diagrams, the wavelength dependence of linear polarization, and the shell brightness distribution. The effect of grain porosity on the results is considered. It has been found that only moderate particle porosity (the volume fraction of matter is f ～0.5) can explain available observational data in terms of the approach used. Since radiation pressure must rapidly sweep submicron-sized grains out of the vicinity of Herbig Ae/Be stars, we briefly discuss how particle porosity can affect this process.     

Sequential extraction and leaching characteristics of heavy metals in abandoned tungsten mine tailings sediments

The chemical speciation of potentially toxic elements (As, Cd, Cu, Pb, and Zn) in the contaminated soils and sulfides-rich tailings sediments of an abandoned tungsten mine in Korea was evaluated by conducting modified BCR sequential extraction tests. Kinetic and static batch leaching tests were also conducted to evaluate the potential release of As and other heavy metals by acidic rain water and the leaching behaviors of these heavy metals. The major sources of the elements were As-, Zn- and Pb-bearing sulfides, Pb carbonates (i.e., cerussite), and Pb sulfates (i.e., anglesite). The biggest pollutant fraction in these soil and tailing samples consists of metals bound to the oxidizable host phase, which can be released into the environment if conditions become oxidative, and/or to residual fractions. No significant difference in total element concentrations was observed between the tailings sediments and contaminated soils. For both sample types, almost no changes occurred in the mobility of As and the other heavy metals at 7 days, but the mobility increased afterwards until the end of the tests at 30 days, regardless of the initial pH. However, the mobility was approximately 5–10 times higher at initial pH 1.0 than at initial pHs of 3.0 and 5.0. The leached amounts of all the heavy metal contents were higher from tailings sediments than from contaminated soils at pH > 3.0, but were lower at pH < 3.0 except for As. Results of this study suggest that further dissolution of heavy metals from soil and tailing samples may occur during extended rainfall, resulting in a serious threat to surface and groundwater in the mine area.     

East Asian monsoon variation and climate changes in Jeju Island, Korea, during the latest Pleistocene to early Holocene

A 4.96-m-long sediment core from the Hanon paleo-maar in Jeju Island, Korea was studied to investigate the paleoclimatic change and East Asian monsoon variations during the latest Pleistocene to early Holocene (23,000-9000 cal yr BP). High-resolution TOC content, magnetic susceptibility, and major element composition data indicate that Jeju Island experienced the coldest climate around 18,000 cal yr BP, which corresponds to the last glacial maximum (LGM). Further, these multi-proxy data show an abrupt shift in climatic regime from cold and arid to warm and humid conditions at around 14,000 cal yr BP, which represents the commencement of the last major deglaciation. After the last major deglaciation, the TOC content decreased from 13,300 to 12,000 cal yr BP and from 11,500 to 9800 cal yr BP, thereby reflecting the weakening of the summer monsoon. The LGM in Jeju Island occurred later in comparison with the Chinese Loess Plateau. Such a disparity in climatic change events between central China and Jeju Island appears to be caused by the asynchrony between the coldest temperature event and the minimum precipitation event in central China and by the buffering effect of the Pacific Ocean.     

A copula-based multivariate analysis of Canadian RCM projected changes to flood characteristics for northeastern Canada

In the present work, climate change impacts on three spring (March–June) flood characteristics, i.e. peak, volume and duration, for 21 northeast Canadian basins are evaluated, based on Canadian regional climate model (CRCM) simulations. Conventional univariate frequency analysis for each flood characteristic and copula based bivariate frequency analysis for mutually correlated pairs of flood characteristics (i.e. peak–volume, peak–duration and volume–duration) are carried out. While univariate analysis is focused on return levels of selected return periods (5-, 20- and 50-year), the bivariate analysis is focused on the joint occurrence probabilities P1 and P2 of the three pairs of flood characteristics, where P1 is the probability of any one characteristic in a pair exceeding its threshold and P2 is the probability of both characteristics in a pair exceeding their respective thresholds at the same time. The performance of CRCM is assessed by comparing ERA40 (the European Centre for Medium-Range Weather Forecasts 40-year reanalysis) driven CRCM simulated flood statistics and univariate and bivariate frequency analysis results for the current 1970–1999 period with those observed at selected 16 gauging stations for the same time period. The Generalized Extreme Value distribution is selected as the marginal distribution for flood characteristics and the Clayton copula for developing bivariate distribution functions. The CRCM performs well in simulating mean, standard deviation, and 5-, 20- and 50-year return levels of flood characteristics. The joint occurrence probabilities are also simulated well by the CRCM. A five-member ensemble of the CRCM simulated streamflow for the current (1970–1999) and future (2041–2070) periods, driven by five different members of a Canadian Global Climate Model ensemble, are used in the assessment of projected changes, where future simulations correspond to A2 scenario. The results of projected changes, in general, indicate increases in the marginal values, i.e. return levels of flood characteristics, and the joint occurrence probabilities P1 and P2. It is found that the future marginal values of flood characteristics and P1 and P2 values corresponding to longer return periods will be affected more by anthropogenic climate change than those corresponding to shorter return periods but the former ones are subjected to higher uncertainties.