Sustainable groundwater development in the coastal Tra Vinh province in Vietnam under saltwater intrusion and climate change

Three-dimensional transient groundwater flow and saltwater transport models were constructed to assess the impacts of groundwater abstraction and climate change on the coastal aquifer of Tra Vinh province (Vietnam). The groundwater flow model was calibrated with groundwater levels (2007–2016) measured in 13 observation wells. The saltwater transport model was compared with the spatial distribution of total dissolved solids. Model performance was evaluated by comparing observed and simulated groundwater levels. The projected rainfalls from two climate models (MIROC5 and CRISO Mk3.6) were subsequently used to simulate possible effects of climate changes. The simulation revealed that groundwater is currently depleted due to overabstraction. Towards the future, groundwater storage will continue to be depleted with the current abstraction regime, further worsening in the north due to saltwater intrusion from inland trapped saltwater and on the coast due to seawater intrusion. Notwithstanding, the impact from climate change may be limited, with the computed groundwater recharge from the two climate models revealing no significant change from 2017 to 2066. Three feasible mitigation scenarios were analyzed: (1) reduced groundwater abstraction by 25, 35 and 50%, (2) increased groundwater recharge by 1.5 and 2 times in the sand dunes through managed aquifer recharge (reduced abstraction will stop groundwater-level decline, while increased recharge will restore depleted storage), and (3) combining 50% abstraction reduction and 1.5 times recharge increase in sand dune areas. The results show that combined interventions of reducing abstraction and increasing recharge are necessary for sustainable groundwater resources development in Tra Vinh province.

     

Titan's atmospheric chemistry: Photolysis of gas mixtures containing hydrogen cyanide and carbon monoxide at 185 and 254 nm

The formation of organic compounds in the atmosphere of Titan is an ongoing process of the generation of complex organics from the simplest hydrocarbon, methane. Solar radiation and magnetosphere electrons are the main energy sources that drive the reactions in Titan's atmosphere. Since energy from solar radiation is 200 times greater than that from magnetosphere electrons, we have investigated the products formed by the action of UV radiation (185 and 254 nm) on a mixture of gases containing nitrogen, methane, hydrogen, acetylene, ethylene, and cyanoacetylene, the basic gas mixture (BGM) that simulates aspects of Titan's atmosphere using a flow reactor [Tran, B.N., Ferris, J.P., Chera, J.J., 2003a. Icarus 162, 114-124; Tran, B.N., Joseph, J.C., Force, M., Briggs, R.G., Vuitton, V., Ferris, J.P., 2005. Icarus 177, 106-115]. The present research extends these studies by the addition of carbon monoxide and hydrogen cyanide to the BGM. Quantum yields for the loss of reactants and the formation of volatile products were determined and compared with those measured in the absence of the hydrogen cyanide and carbon monoxide. The GCMS analyses of the volatile photolysis products from the BGM, with added hydrogen cyanide, had a composition similar to that of the BGM while the photolysis products of the BGM with added carbon monoxide contained many oxygenated compounds. The infrared spectrum of the corresponding solid product revealed the absorption band of a ketone group, which was probably formed from the reaction of carbon monoxide with the free radicals generated by photolysis of acetylene and ethylene. Of particular interest was the observation that the addition of HCN to the gas mixture only resulted in a very small change in the C/N ratio and in the intensity of the CN frequency at 2210 cm⁻¹ in the infrared spectrum suggesting that little HCN is incorporated into the haze analog. The C/N ratio of the haze analogs was found to be in the 10-12 range. The UV spectra of the solid products formed when HCN or CO added to the BGM is similar to the UV absorption formed from the BGM alone. This result is consistent with absence of additional UV chromophores to the solid product when these mixtures are photolyzed. The following photoproducts, which were not starting materials in our photochemical studies, have been observed on Titan: acetonitrile, benzene, diacetylene, ethane, propene, propane, and propyne.     

Anisotropic Closure in Squeezing Rocks: The Example of Saint-Martin-la-Porte Access Gallery

In this paper, we analyse the convergence measurements recorded in a gallery excavated in severely squeezing ground. The procedure consists in a preliminary geometrical treatment of the raw data to evaluate the principal axes of deformation by assuming an elliptic deformation of the walls of the gallery. Then the convergence law proposed by Sulem et al. (Int J Rock Mech Min Sci Geomech Abstr 24(3):145–154, 1987a), which is extended to account for anisotropic closure, is fitted on the displacements along the two axes of the obtained ellipse. This procedure is more robust and relevant than fitting the convergence recorded on the most deforming segment or fitting the average value of the convergence along the various segments. An attempt is made to correlate the amount and the direction of anisotropic deformation with the lithology and some geological features described by the dominant discontinuity families.     

Floodplain hydrology of the Mekong Delta,Vietnam

The Mekong Delta is one of the largest and most intensively used estuaries in the world. Each year it witnesses widespread flooding which is both the basis of the livelihood for more than 17 million people but also the major hazard. Therefore, a thorough understanding of the hydrologic and hydraulic features is urgently required for various planning purposes. While the general causes and characteristics of the annual floods are understood, the inundation dynamics in the floodplains in Vietnam which are highly controlled by dikes and other control structures have not been investigated in depth. Especially, quantitative analyses are lacking, mainly due to scarce data about the inundation processes in the floodplains. Therefore, a comprehensive monitoring scheme for channel and floodplain inundation was established in a study area in the Plain of Reeds in the northeastern part of the Vietnamese Delta. This in situ data collection was complemented by a series of high‐resolution inundation maps derived from the TerraSAR‐X satellite for the flood seasons 2008 and 2009. Hence, the inundation dynamics in the channels and floodplains, and the interaction between channels and floodplains, could be quantified for the first time. The study identifies the strong human interference which is governed by flood protection levels, cropping patterns and communal water management. In addition, we examine the tidal influence on the inundation in various parts of the Delta, since it is expected that climate change‐induced sea level rise will increase the tidal contribution to floodplain inundation. Copyright © 2011 John Wiley & Sons, Ltd.     

Study on the kinetics of iron oxide leaching by oxalic acid

The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO₄²⁻ and Cl⁻, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe₂O₃) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)^2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]^1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate.     

Adaptive fisheries management in Vietnam: The use of indicators and the introduction of a multi-disciplinary Marine Fisheries Specialist Team to support implementation

Vietnam is in the process of introducing adaptive management based on indicators and time-series to manage its marine fisheries. The development of indicator-based frameworks for fisheries management has accelerated in recent years. This article describes the suite of indicators being suggested or used in Vietnam including the data-collection system. The Vietnamese approach is supported by an institutional structure consisting of a multi-disciplinary advisory system to facilitate the process of using indicators and to introduce knowledge-based management. The article concludes by identifying current problems and weaknesses and by providing suggestions for future improvement of the system.     

Assessment with satellite data of the urban heat island effects in Asian mega cities

This study focuses on using remote sensing for comparative assessment of surface urban heat island (UHI) in 18 mega cities in both temperate and tropical climate regions. Least-clouded day- and night-scenes of TERRA/MODIS acquired between 2001 and 2003 were selected to generate land-surface temperature (LST) maps. Spatial patterns of UHIs for each city were examined over its diurnal cycle and seasonal variations. A Gaussian approximation was applied in order to quantify spatial extents and magnitude of individual UHIs for inter-city comparison. To reveal relationship of UHIs with surface properties, UHI patterns were analyzed in association with urban vegetation covers and surface energy fluxes derived from high-resolution Landsat ETM+ data. This study provides a generalized picture on the UHI phenomena in the Asian region and the findings can be used to guide further study integrating satellite high-resolution thermal data with land-surface modeling and meso-scale climatic modeling in order to understand impacts of urbanization on local climate in Asia.     

Geochemistry and petrogenesis of Permian ultramafic-mafic complexes of the Jinping–Song Da rift (southeastern Asia)

The Jinping–Song Da rift structure in the Emeishan Large Igneous Province is composed of Permian high- and low-Ti volcanic and volcanoplutonic ultramafic-mafic associations of different compositions and genesis. High-Ti picrites, picrobasalts, basalts, and dolerites are enriched in LREE and depleted in HREE and show low Al₂O₃/TiO₂ ratios (~4), commensurate ε_Nd(T) values (+0.5 to +1.1), and low (Th/Nb)_PM ratios similar to those of OIB-enriched mantle source. The established geochemical characteristics evidence that the parental melts of these rocks were generated from garnet lherzolite at the depths of garnet stability (~200 to 400 km). Later, high-Mg low-Ti volcanics (komatiites, komatiitic basalts, and basalts) and associating small peridotite-gabbro massifs and komatiite-basalt dikes were produced as a result of ~20% partial melting of depleted water-poor (≤0.03 wt.% H₂O) peridotite substratum from the hottest upper part of mantle plume at relatively shallow depths (100–120 km). The LREE-depleted komatiites and komatiitic basalts are characterized by low (Ce/Yb)_CH values, ¹⁸⁷Re/¹⁸⁸Os = 0.05–1.2, ⁸⁷Sr/⁸⁶Sr = 0.704–0.706, positive ε_Nd(T) values (+3 to +8), γ_Os = –0.5 to +0.9, and strong negative anomalies of Ba, K, and Sr on the spidergrams. The scarcer LREE-enriched komatiites, komatiitic basalts, and basalts vary greatly in chemical composition and values of ε_Nd(t) (+6.4 to –10.2), ⁸⁷Sr/⁸⁶Sr (0.706–0.712), and γ_Os (+14.8 to +56), which is due to the different degrees of crustal contamination of parental magmas. The Rb-Sr isotopic age of basaltic komatiite is 257 ± 24 Ma. The Re-Os age determined by analysis of 12 komatiite samples is 270 ± 21 Ma. These data agree with the age of flood basalts of the Emeishan Large Igneous Province. The komatiite-basalt complex of the Song Da rift is still the only Phanerozoic PGE-Cu-Ni-complex of this composition. The geochemistry of accompanying Cu-Ni-PGE-ores confirms their relationship with komatiite-basaltic magmatism.     

Assessment of earthquake hazard for the northwestern Vietnam from geological and geophysical data using an original program package

The highest seismic activity in Vietnam is observed in the northwest of the country, hence the practical significance of more accurate assessment of the earthquake hazard for the area. The worldwide experience of seismicity, in particular, the recent Tohoku mega-earthquake (March 11, 2011, M _w = 9.0, Japan) shows that instrumental and historical data alone are insufficient to reliably estimate earthquake hazard. This is all the more relevant in relation to Vietnam where the period of instrumental observation is short and historical evidence is nearly lacking. In this connection we made an attempt to construct maps of earthquake hazard based on known seismicity data using the available geological and geophysical data and the method of G.I. Reisner and his associates for classification of areas by seismic potential. Since the question of what geological and geophysical parameters are to be used and with what weights remains unresolved, we developed a program package to estimate Mmax based on different options in the use of geological and geophysical data. In this paper we discuss the first results and the promise held by this program package.     

Construction and analysis of higher order finite difference schemes for the 1D wave equation

In this article, we propose to: 1. Establish most of the properties conjectured in [2] about the higher order finite difference approximation of the 1D Laplace operator. 2. Generalize to any order the fourth-order accurate scheme in space and time of Shubin and Bell [20] and Cohen [6]. For this new family of 2m–2m schemes, we establish, via elementary mathematics, various stability and dispersion results that are helpful to compare these schemes to the 2–2m schemes of Anné et al. [2]. This revised version was published online in July 2006 with corrections to the Cover Date.