A mathematical model to aid management of outflow from the Okavango swamp,Botswana

A series of mathematical models permitted a 20-year sequence of flows to be routed through the complex river and swamp system thus facilitating simulation of the behaviour of the Mopipi off-channel storage from which the Orapa Diamond Mine draws its water supply. From the results of the simulation it was possible to judge the reliability of the Orapa water supply scheme.Although the scheme would evidently have met the design demand throughout the simulation period, the source area, located many kilometres upstream of Orapa, is highly sensitive to relatively minor vegetational changes and possibly also to seismic activity. For this reason, coupled with the fact that future developmental pressures are likely to conflict with the desire to preserve this wilderness environment, it seems imperative that the scope of the model be widened to embrace the whole of the Okavango delta and that ecological studies be directed towards establishing interrelationships among the biological, hydrological and other parameters of the broader conceptual model.     

Banda arc of eastern indonesia: Petrology and geochemistry of the volcanic rocks

A detailed petrological study of the Banda Arc volcanism, documented by extensive microprobe whole-rock and mineral analysis, shows that the apparent geographical eastwards continuity of the Sunda Arc conceals a major geochemical discontinuity adjacent to the southern end of the Weber Deep beneath Serua. The alkali contents and Sr isotope ratios suggest that Nila, Teun and Damar form one volcanic group distinct from Banda and Manuk, and Serua is in the border discontinuity, reflected in its widely fluctuating Fe/Mg partitioning between mineral phases and its variable Sr isotope ratios. With the exception of basalt from S. W. Ambon, all lavas are quartz normative and typical of an ensimatic oceanic island arc. They range from tholeiitic basalt and dacite on S. W. Ambon and Banda, through low-K calc-alkaline andesites on Manuk and Serua, to high-K calc-alkaline andesites on Nila, Teun, Damar, Gunung Api north of Wetar, and Romang which also contains dacite. The higher potassium contents are normally contained in biotite and hornblende, and occasionally in the groundmass glass. Increasing potassium from Banda to Manuk may be related to increasing Benioff Zone depth between the 100 to 200 km contours, but the lavas of Gunung Api north of Wetar have insufficient potassium to be derived from the underlying 400–500 km Benioff Zone. Older cordierite dacites (ambonites) on North Ambon must be derived from a underlying continental crust, but the younger tholeiitic lavas of S.W. Ambon and Banda may be related to a shallow subduction zone dipping southwards from Seram.     

Ophiolite metamorphism in northeast Borneo

The Darvel Bay ophiolite consists of a conformable sequence of mantle harzburgite, a gabbro layer of about 2 km thickness, a basalt layer and associated chert-spilite association of Late Cretaceous to Eocene age, and overlying Miocene melange and olistostrome deposits. The ophiolite is an extension into Borneo of the recently inactive Sulu Archipelago non-volcanic arc. Generally the gabbro layer has been converted to banded plagioclase-amphibole gneisses and the basalt layer to crudely foliated epidote amphibolite. Igneous relicts occur sporadically, especially in the lower gabbro horizons. They have either cumulus granular or gabbroic textures and contain diopsidic augite, bronzite, and a dark brown pargasitic hornblende. The labradorite is occasionally clouded. The partitioning of Fe/Mg between the two pyroxenes and the hornblende suggests an igneous paragenesis and the former allocation of these pyroxene-bearing rocks to the granulite facies is now rejected.The basites have undergone metamorphic re-equlibration, frequently sporadic and imperfec, through amphibolite facies, characterized by hornblende, to greenschist facies, characterized by actinolite. Igneous labradorite frequently persists to the lower grades. The partitioning of Ca/Na between amphibole and plagioclase may be correlated with metamorphic grade.Sub sea-floor retrogressive metamorphism, combined with large scale metasomatism resulting from the circulation of hot brine, appears to be the most appropriate mechanism to explain the sodium enrichment in the basalt layer and the imperfect metamorphic re-equilibration of the ophiolite generally.     

Two-dimensional lattice images of stacking disorder in wollastonite

Two-dimensional lattice images of low-temperature triclinic wollastonite (-CaSiO₃) indicate that two types of stacking disorder occur: (1) simple stacking faults and (2) twinning which also involves displacement in the composition plane. Both types of defect produce very similar structures with monoclinic symmetry (parawollastonite). Dislocations are involved at the termination of lamellae of parawollastonite in a triclinic matrix and a model for the dislocation core is proposed.Now at the Edward Davies Chemical Laboratories, Aberystwyth, SY23 1NE, U.K.     

Experimental calibration of the sphalerite cosmobarometer

The pressure and temperature dependence of the composition of sphalerite in equilibrium with troilite + metallic iron has been determined experimentally at 2.5 and 5.0 kbar between 400° and 800°C using both the aqueous and anhydrous alkali halide flux recrystallization techniques. The measured pressure effect is larger than that calculated by us and by Schwarczet al. (1975a), and is described by the equation (T in Kelvins), P (kbar) = ?3.576 + 0.0551T ?0.0296Tlogmole % FeS.Assuming temperatures of final equilibration between sphalerite and troilite of 350°C for iron meteorites and 600°C for enstatite chondrites, published analyses of sphalerites provide estimates of pressures of formation and possible radii of parent objects of meteorites as follows: IA irons (Landes, Sardis, Gladstone, Bogou, Odessa, Toluca) 0.0 to 3.5 kbar, 0 to 442 km; E6 enstatite chondrites (Yilmia, Pillistfer) ?0.2 to 0.7 kbar, 0 to 198 km.     

Multiple-chain and other unusual faults in amphiboles

A combination of high resolution transmission electron microscopy and computer simulation has revealed the existence of multiple-chain and other faults in nephrite jade. Attention is drawn to the subunit cell reorganization involved with many of these faults, which generally appear to be free from severe structural strain.     

Corundum inclusions in diamonds—discriminatory criteria and a corundum compositional dataset

Mineral inclusions of corundum are reported from diamonds from alluvial deposits of tributaries of the Rio Aripuanã, Juina, Brazil. We present the first recorded occurrence of sapphire as an inclusion in diamond and expand on the database of ruby and white corundum inclusions. Ruby inclusions are found to occur both as isolated and touching grains with aluminous pyroxene and associated with ferropericlase. Mineral chemistry and phase relations place the origin of such ruby-bearing diamonds within the lower mantle at 770 km. Mineral associations indaving other corundum inclusions were not observed; hence, their depth of origin is less certain.

Compositions of corundum samples were characterised by electron and ion microprobe. Given the scarcity of literature data, corundum samples from a variety of other geological settings were also analysed. Samples comprised corundums associated with granitic emplacement, metasomatism, amphibolite-facies and granulite-facies rocks, gem and industrial synthetic origins and carmine-coloured corundums recovered from kimberlite drill cores.

In addition to variable amounts of Cr, Fe, Ti, Mg and Si, measurable quantities of other transition elements and high field strength elements were also detected. Corundums from similar geological settings show very similar compositions and are easily distinguishable from other settings. Irrespective of locality, rubies from Norwegian, Tanzanian and Kenyan amphibolite-facies rocks are compositionally indistinguishable. Additionally, corundums from metasomatised zones associated with contact metamorphism from Arizona and Japan were very similar, particularly characterised by unusually high abundance of mobile Zr and Nb (tens of ppm). All Juina inclusions are particularly distinguishable from other corundums by high concentrations of Ni (18–171 ppm weight), typically at least an order of magnitude enriched over the same corundum varietal types from elsewhere. Furthermore, the sapphire inclusion exhibited much larger ratios of Ga and Ge to HFSE elements compared to otherwise similar samples, and ruby inclusions are distinguished by high Mg/Fe ratios (0.27–1.56 by weight). Compositional differences between inclusions in diamonds and corundums from other settings in addition to corundum's physical and chemical durability suggest that with the employment of rapid identification tools such as energy dispersive spectrometry (EDS) and laser-ICPMS, corundum has promise as an indicator of diamond prospectivity.     

The irradiation history of the Ghubara (L5) regolith breccia

Abstract— We measured cosmic‐ray products—noble gases, radionuclides, thermoluminescence, and nuclear tracks—and trace element contents and mineralogy of samples of three orthogonal and mutually intersecting cores (41–46 cm long) of a 101.6 kg Ghubara individual (1958,805) at The Natural History Museum, London. The xenoliths, like the host, have high concentrations of trapped solar gases and are heavily shocked. While contents of noble gases and degree of shock‐loading in this individual and three others differ somewhat, the data indicate that Ghubara is a two‐generation regolith breccia. Contents of cosmogenic ²⁶Al and ¹⁰Be and low track densities indicate that the Ghubara individuals were located more than 15 cm below the surface of an 85 cm meteoroid. Because of its large size, Ghubara's cosmic‐ray exposure age is poorly defined to be 15–20 Ma from cosmogenic nuclides. Ghubara's terrestrial age, based on ¹⁴C data, is 2–3 ka. Not only is Ghubara the first known case of a two‐generation regolith breccia on the macroscale, it also has a complicated thermal and irradiation history.     

Petrographic classification of Middle Ordovician fossil meteorites from Sweden

Abstract— The maximum diameter of chromite (FeCr₂O₄) grains within L chondrites reflects the petrographic type of the sample. On the basis of our measurements of nine recent L chondrites, L3 chromite D_max = 34–50 μm, L4 = 87–150 μm, L5 = 76–158 μm, and L6 = 253–638 μm. This variation reflects the crystallization of the chromite grains during parent body thermal metamorphism. We use this calibration to classify six fossil meteorites from the Middle Ordovician in Sweden as type 3 (or 4) to 6. The high flux of L chondrites at 470 Ma contained a range of petrographic types and may have had a higher proportion of lower petrographic type meteorites than are found in recent L chondrite falls. The fossil meteorites have in places preserved recognizable chondrule textures, including porphyritic olivine, barred olivine, and radiating pyroxene. A large relict clast and fusion crust have also been tentatively identified in one fossil meteorite. Apart from chromite, all of the original meteorite minerals have been replaced by carbonate (and sheet silicate and sulfate) during diagenesis within the limestone host. The preservation of chondrule definition has allowed us to measure the mean diameters of relict chondrules. The range (0.4–0.6 mm) is consistent with measurements made in the same way on recent L chondrites.