Synthesis of Calix[4]arene‐grafted Magnetite Nanoparticles and Evaluation of Their Arsenate as Well as Dichromate Removal Efficiency

In this study, 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy‐calix[4]arene ( 3 ) has been prepared by the treatment of calix[4]arene with a secondary amine (4‐benzylpiperidine) and formaldehyde by means of Mannich reaction. The prepared Mannich base ( 3 ) has been grafted onto [3‐(2,3‐epoxypropoxy)‐propyl]‐trimethoxysilane‐modified Fe₃O₄ magnetite nanoparticles (EPPTMS‐MN) in order to obtain 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy calix[4]arene‐grafted EPPTMS‐MN (BP‐calix[4]arene‐grafted Fe₃O₄). All new compounds were characterized by a combination of FTIR and ¹H‐NMR analyses. The morphology of the magnetic nanoparticles was examined by transmission electron microscopy. Moreover, the studies regarding the removal of arsenate and dichromate ions from the aqueous solutions were also carried out by using 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy‐calix[4]arene in liquid–liquid extraction and BP‐calix[4]arene‐grafted Fe₃O₄ ( 4 ) in solid–liquid extraction experiments. The extraction results indicated that 3 is protonated at proton‐switchable binding sites in acidic conditions. Hence, facilitating binding of arsenate and dichromate is resulted from both electrostatic interactions and hydrogen bonding. To understand the selectivity of 3 , the retention of dichromate anions in the presence of Cl⁻, NO, and SO anions at pH 1.5 was also examined.     

Relevance of building site categories implementation into the land use plan in underground mining area in the region of Petrvald (Czech Republic)

Deep mining of mineral resources causes extensive changes in rock environment and ground morphology and must be considered in the land use planning. Subsidence as a result of underground mining activities in terrains is one of the serious geological hazards because they can effect slopes and damage engineering structures, settlement areas, natural lakes and allow infiltration of contaminant into the groundwater. The main aim of this article was implementation of the building site categories of underground mining regions into the land use plans. This case study area was selected from the region of Orlova town within the Ostrava-Karvina Coal district, and this region is one of the most affected areas by underground mining of black coal in the Czech Republic. Certain risk categories of land, where the individual categories express generalized influence of deep mining of coal in current and planned constructions were also represented in this article. Extensive variations caused by underground mining were identified within a wide variability of risk categories. An important finding was also the extensive variability over time, manifested by spatial variations in the stated categories in the studied time periods. Moreover, technical documentation of environmental impacts related to underground mining activities was provided; importance of existing and proposed underground mining projects that may significantly impact the land use was discussed and pointed out in this article, especially.     

Liquefaction-induced ground deformations at Hotel Sapanca during Kocaeli (Izmit),Turkey earthquake

This paper presents a study of liquefaction-induced ground deformations at the Hotel Sapanca site during the 1999 Kocaeli (Izmit)—Turkey earthquake. The paper discusses: (1) observed ground deformations and displacements after the earthquake, (2) the results of field investigations by means of borings and in situ index tests including standard penetration tests (SPT), static cone penetration tests (CPT) and piezocone (CPTU) tests, (3) analyses of observed ground settlements and lateral deformations by a suite of methods, and (4) comparisons of observed and calculated ground movements.     

Monitoring of protected bands of Terkos drinking water reservoir of metropolitan Istanbul near the Black Sea coast using satellite data

In this study, remote sensing (RS) with computer-based geographic information systems (GIS) techniques are used as a tool for monitoring the water basin area and water quality in Istanbul's relatively less polluted and comparatively less destroyed catchment of the metropolis drinking water dam reservoir named Terkos. It is necessary to work with recent data to be able to identify the effects of urbanization on the water quality of the Terkos dam catchment area that supplies drinking water to the metropolis. RS is an important tool to monitor water quality and urban terrain. For this aim, a project has been initiated at the Technical University Remote Sensing Laboratory, under the Istanbul Water and Sewerage Administration (ISKI) sponsorship in Istanbul. The project uses SPOT-PAN, XS and IRS-1C/D PAN and satellite data of 1993 and 2000 for urban analysis and Landsat-TM and LISS-III satellite data of 1992 and 2000 for water quality. For calibration and validation, ground truth samples are collected from the experimental area. The RS data was converted into the UTM coordinate system and image enhancement and classification techniques are used. Raster data is converted to vector data to assess the study area for analyzing in GIS for the purpose of planning and decision-making on protected water basin zones. As a result of monitoring land use and water quality changes, recommendations are made for planning and management of the protected environment of the Terkos catchment protected area. Measuring land use change is a very important issue for controlling the future development of the basin, GIS techniques are performed and results are illustrated in established models on the four protected zones of Terkos water basin.     

Geotechnical evaluation of Miocene gypsum from Sivas (Turkey)

Gypsum is widely distributed in Sivas (Turkey), occurring chiefly in the formations of Miocene age. The gypsum is generally of the alabastrine type with a little of the porphiroblast type and contains traces of clay minerals, anhydrite and calcite. It is a moderately strong rock in terms of its unconfined compressive strength which is related to the crystal size. Strength increases as the crystal size decreases. The strength of gypsum was reduced by approximately 55%, when the samples were kept in the water for 20 days. Most samples exhibit plastic–elastic–plastic deformation. The gypsum has a high modulus ratio, and is a moderately deformable rock. High lateral deformations and low vertical deformations are observed under the vertical stress conditions in accordance with the relationship between modulus ratio and strain.     

Assessment of excavatability,abrasivity and slope stability in a sandstone quarry in Istanbul,Turkey

The Cebeci region is characterized by outcrops of Carboniferous sandstone, including diabase dykes. This region is very important area for aggregate production in Istanbul, Turkey. The aim of this study is to determine the engineering geological properties of sandstones to assess the excavatability, abrasivity and stability of cut slopes in a quarry site. Firstly, the sandstone samples were used to determine their petrographical and mineralogical characteristics. Then, physico-mechanical tests were performed on these samples. In order to determine rock mass properties, scan-line surveys were performed, and the major orientations of discontinuities were analyzed through the stereographic projection technique. Kinematical analyses were also made to determine the potential failures at the quarry site. According to the results obtained, excavatability is changed from easy ripping to hard ripping on sandstones; the carbonated sandstone is less abrasive than other sandstones. Based on the field studies and stability analyses of the cut slopes, optimum slope geometry and necessary support measures, such as wire mesh and rock fall barriers, are suggested.     

Fourier analysis of the light curves of eclipsing variables,XX

In the present paper _n ⁰ , for occulation and transit eclipses of partial phases, are evaluated numerically by means of the Runge-Kutta methods. Section 2 contains the required differential equations of _n ⁰ with respect to the modulusX orC, and Section 3 includes the numerical method of the solutions of these differential equations. Theoretical values of ₀ ⁰ and ₁ ⁰ , with corresponding values ofC, are also added in this section.     

Validation of a TRMM-based global Flood Detection System in Bangladesh

Although the TRMM-based Flood Detection System (FDS) has been in operation in near real-time since 2006, the flood ‘detection’ capability has been validated mostly against qualitative reports in news papers and other types of media. In this study, a more quantitative validation of the FDS over Bangladesh against in situ measurements is presented. Using measured stream flow and rainfall data, the study analyzed the flood detection capability from space for three very distinct river systems in Bangladesh: (1) Ganges– a snowmelt-fed river regulated by upstream India, (2) Brahmaputra – a snow-fed river that is braided, and (3) Meghna – a rain-fed and relatively flashier river. The quantitative assessment showed that the effectiveness of the TRMM-based FDS can vary as a function of season and drainage basin characteristics. Overall, the study showed that the TRMM-based FDS has great potential for flood prone countries like Bangladesh that are faced with tremendous hurdles in transboundary flood management. The system had a high probability of detection overall, but produced increased false alarms during the monsoon period and in regulated basins (Ganges), undermining the credibility of the FDS flood warnings for these situations. For this reason, FDS users are cautioned to verify FDS estimates during the monsoon period and for regulated rivers before implementing flood management practices. Planned improvements by FDS developers involving physically-based hydrologic modeling should transform the system into a more accurate tool for near real-time decision making on flood management for ungauged river basins of the world.     

Numerical Modelling of Steep Slopes in Open Rock Quarries

The key question regarding steep rock slopes along rock quarries is their stability because a rock slope failure can have critical results. In this study, the aim is to investigate the areas with potential risk for jointed karstic limestones in a rock quarry. First, to determine rock mass properties, scan-line surveys were performed, and the major orientations of discontinuities were analyzed using stereographic projection. Then, the physicomechanical properties of the slope-forming rock were determined in the laboratory, and geomechanical properties of the rock mass were determined using an empirical failure criterion. Finally, the quarry slope stability was assessed in accordance with numerical modelling. According to the results obtained, the numerical modelling of steep rock slopes can be efficiently evaluated by using finite element method. Beside this, the presence of joints intersecting the main discontinuity sets, the filling materials of discontinuities resulting from weathering of limestone and surface deposits, surcharge load due to mine waste dumped on the slopes and excavation blasting during construction of quarry area play a key role when modelling the steep rock slopes by using finite element method.