Migration and dispersion of trace elements in the rock–soil–plant system in areas underlain by black shales and slates of the Okchon Zone, Korea

The Okchon black shale in Korea provides a typical example of natural geological materials enriched with potentially toxic elements. The Chung-Joo, Duk-Pyung, Geum-Kwan, I-Won, Bo-Eun and Chu-Bu areas are underlain by these black shales and slates of the Guryongsan Formation or the Changri Formation, which are parts of the Okchon Group in the central part of the southern Korean Peninsula. In order to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock–soil–plant system, environmental geochemical surveys were undertaken in the above six study areas in the Okchon Zone. After appropriate preparation, rock and soil samples were analyzed for potentially toxic elements by instrumental neutron activation analysis (INAA) and inductively coupled plasma atomic emission spectrometry (ICP-AES), and plant samples by atomic absorption spectrometry (AAS). In particular, Ba, Cd, Mo, V and U in Okchon black shales are highly enriched, and their mean concentrations are significantly higher than those in black slates. These elements are geochemically associated, and might be enriched simultaneously. The highest mean concentrations of 42.0 μg g⁻¹ As, 2100 μg g⁻¹ Ba, 10.9 μg g⁻¹ Cd, 213 μg g⁻¹ Mo, 83 μg g⁻¹ U, 938 μg g⁻¹ V and 394 μg g⁻¹ Zn are found in black shales from the Duk-Pyung area. Mean concentrations of As, Mo and U in soils overlying black shales occurring in the Duk-Pyung area (30 μg g⁻¹ As, 24 μg g⁻¹ Mo and 50 μg g⁻¹ U) and Chu-Bu area (39 μg g⁻¹ As, 15 μg g⁻¹ Mo and 27 μg g⁻¹ U) are higher than the permissible level. Enrichment index values of the six study areas decrease in the order of Duk-Pyung > Chu-Bu > Bo-Eun > Chung-Joo > Geum-Kwan = I-Won areas. Relationships between trace element concentrations in soils and plants are significantly correlated, and the biological absorption coefficients (BAC) in plants are in the order of Cd > Zn = Cu > Pb, which suggests that Cd is more bioavailable to plants than the other elements. Cadmium concentrations in plant species decrease in the order of chinese cabbage > red pepper > soybean = sesame > rice stalk > corn > rice grain. From the result of sequential extraction analysis of soils, relatively high proportions of Cu, Pb and Zn are present as residual fractions, and that of Cd as non-residual fractions. Cadmium occurs predominantly as exchangeable/water-acid soluble phase in soils, and this is in agreement with the findings of high Cd concentrations in plants.     

Quantitative Assessment of Extrinsic Damage in Rock Materials

Summary   Comminution (crushing and grinding) of rock materials is energy-intensive and expensive. Much effort has been directed to improve the efficiency of conventional milling practice, but relatively little attention has been given to the potential benefits of blast-induced (extrinsic) damage on comminution processes. The objective of this research is to investigate the effect of shock-induced “crack-like” damage on rock properties for three petrologically distinct rock materials under laboratory conditions. In order to evaluate the effect of shock-induced damage, a quantitative measure of rock damage is needed. Shock loading of rock material was accomplished with an explosively driven split Hopkinson pressure bar. Laboratory measurements show that the average uniaxial compressive strengths for damaged specimens are slightly lower than those for intact specimens. Based on damage mechanics, the scalar damage variable () was experimentally determined as the relative reduction in ultrasonic wave velocity of damaged versus intact rock. increases as the shock energy dissipated in rock material increases. A crack density was determined by confocal image analysis. Measurements following shock loading indicate that ultrasonic wave velocity in rock partially recovers with time. Ultrasonic wave velocity and confocal image analysis may be useful in quantitatively assessing the internal crack-like damage in rock materials.     

Discrimination of small earthquakes and artificial explosions in the Korean Peninsula using Pg/Lg ratios

The purpose of this study is to develop a technique to discriminate artificial explosions from local small earthquakes ( M ≤ 4.0) in the time–frequency domain. In order to obtain spectral features of artificial explosions and earthquakes, 3-D spectrograms (frequency, time and amplitude) have been used. They represent a useful tool for studying the frequency content of entire seismic waveforms observed at local and regional distances (Kim, Simpson & Richards 1994). P and S(L g ) waves from quarry blasts show that the frequency content associated with the dominant amplitude appears above 10  Hz and Rg phases are observed at close distances. P and S(L g ) waves from the Tongosan earthquake have strong amplitudes below 10  Hz. For the Munkyong earthquake, however, a broader frequency content up to 20  Hz is found.
  For discrimination between small earthquakes and explosions, Pg/L g spectral ratios are used below 10  Hz, and through spectrogram analysis we can see different frequency contents of explosions and earthquakes. Unfortunately, because explosion data recorded at KSRS array are digitized at 20  sps, we cannot avoid analysing below 10  Hz because of the Nyquist frequency. In order to select time windows, the group velocity was computed using multiple-filter analysis (MFA), and free-surface effects have been removed from all three-component data in order to improve data quality. Using FFT, a log-average spectral amplitude is calculated over seven frequency bands: 0.5 to 3, 2 to 4, 3 to 5, 4 to 6, 5 to 7, 6 to 8 and 8 to 10  Hz. The best separation between explosions and earthquakes is observed from 6 to 8  Hz. In this frequency band we can separate explosions with log ( Pg/L g ) above −0.5, except EXP1 recorded at SIHY1-1, and earthquakes below −0.5, except the Munkyong earthquake record at station KMH.     

On a Physically Realistic Fast Dynamo

As a step towards a physically realistic model of a fast dynamo, we study numerically a kinematic dynamo driven by convection in a rapidly rotating cylindrical annulus. Convection maintains the quasi-geostrophic balance whilst developing more complicated time-dependence as the Rayleigh number is increased. We incorporate the effects of Ekman suction and investigate dynamo action resulting from a chaotic flow obtained in this manner. We examine the growth rate as a function of magnetic Prandtl number Pm, which is proportional to the magnetic Reynolds number. Even for the largest value of Pm considered, a clearly identifiable asymptotic behaviour is not established. Nevertheless the available evidence strongly suggests a fast dynamo process.     

Computational microstructure modeling to estimate progressive moisture damage behavior of asphaltic paving mixtures

This paper presents a computational microstructure model to estimate the progressive moisture damage of multiphase asphaltic paving mixtures. Moisture damage because of water transport is incorporated with mechanical loading through a finite element method. To simulate nonlinear damage evolution in the mixtures, the model includes Fickian moisture diffusion, a cohesive zone model to simulate the gradual fracture process, and a degradation characteristic function to represent the reduction of material properties because of moisture infiltration. With the model developed, various parametric analyses are conducted to investigate how each model parameter affects the material‐specific moisture damage mechanism and damage resistance potential of the mixtures. Analysis results clearly demonstrate the significance of physical and mechanical properties of mixture components and geometric characteristics of microstructure for the better design of asphaltic paving mixtures and roadway structures. Copyright © 2012 John Wiley & Sons, Ltd.     

Importance of no‐rain measurements on the comparison of radar and rain gauge rain rate

This study evaluated four possible cases of comparing radar and rain gauge rain rate for the detection of mean‐field bias. These four cases, or detection designs, consider in this study are: (1) design 1‐uses all the data sets available, including zero radar rain rate and zero rain gauge rain rate, (2) design 2—uses the data sets of positive radar rain rate and zero or positive rain gauge rain rate, (3) design 3—uses the data sets of zero or positive radar rain rate and positive rain gauge rain rate and (4) design 4—uses the data sets of positive radar rain rate and positive rain gauge rain rate. A theoretical review of these four detection designs showed that only the design 1 causes no design bias, but designs 2, 3 and 4 can cause positive, negative and negative design biases, respectively. This theoretical result was also verified by applying these four designs to the rain rate field generated by a multi‐dimensional rain rate model, as well as to that of the Mt Gwanak radar in Korea. The results from both applications showed that especially the design 4, which is generally used for the detection of mean‐field bias of radar rain rate, causes a serious design bias; therefore, is inappropriate as a design for detecting the mean‐field bias of radar rain rate. Copyright © 2009 John Wiley & Sons, Ltd.     

3He, 20,21,22Ne, 14C, 10Be, 26Al,and 36Cl in magnetic fractions of cosmic dust from Greenland and Antarctica

Abstract— We report on studies of the concentrations of cosmogenic nuclides in the magnetic fraction of cosmic dust particles recovered from the South Pole Water Well (SPWW) and from Greenland. Our results confirm that cosmic dust material from these locations contains measurable amounts of cosmogenic nuclides. The Antarctic particles (and possibly those from Greenland as well) also contain minor amounts of solar Ne. Concentrations of cosmogenic nuclides are consistent with irradiation of this material as small objects in space, with exposure ages similar to the expected Poynting‐Robertson (P‐R) lifetimes of 50–200 kyr for particles 25–100 μm in size.