Raman spectroscopic study of K-lingunite at various pressures and temperatures

K-lingunite is a high-pressure modification of K-feldspar that possesses the tetragonal hollandite structure. Variations of the Raman spectra of K-lingunite were studied up to ~31.5 GPa at room temperature, and in the range 79–823 K at atmospheric pressure. The Raman frequencies of all bands were observed to increase with increasing pressure, and decrease with increasing temperature for K-lingunite. This behavior is in line with those observed for most of other materials. New sharp Raman bands appear at pressures greater than 13–15 GPa, suggesting a phase transition in K-lingunite with increasing pressure. The transition is reversible when pressure was released. The appearance of these new Raman bands may correspond to the phase transition revealed earlier at around 20 GPa by X-ray diffraction studies. Instead of transforming back to its stable minerals, such as orthoclase, microcline or sanidine, K-lingunite became amorphous in the temperature range 803–823 K at atmospheric pressure.     

研究花岗岩类成因类型和幔壳成分比的同位素方法探讨

Sm-Nd法及其参数εNd（O）、εNd（T）、TCHUR^Nd、εDM^Nd及x,是测定花岗岩形成年龄及研究花岗岩成因类型、模式年龄及地幔物质百分比的重要手段,但因其测试费用高等原因,难以广泛使用。作者提出了Rb-Sm法的相应参数εSr（O）、εSr（T）、TUR^Sr、εDM^Sr及μ做为补充,在没有Sm-Nd同位素资料的情况下,Rb-Sr同位素参数基本上可以代替Sm-Nd同位素参数。经对比,求花岗岩中幔源物质百分比时,Rb-Sr法计算值与Sm-Nd法计算值相比,误差一般不超过10％。此外,作者还提出了计算花岗岩山幔源物质百分比的简化式,使该计算更为简便易行。     

Downstream patterns of bed sediment-borne metals,minerals and organic matter in a stream system receiving acidic mine effluent: A preliminary study

Different downstream variation patterns were observed for a range of bed sediment-borne metals (aqua regia-extractable fraction) in a subtropical stream system receiving acid mine drainage. Mine-originated Fe tended to be deposited in the acidic (mean pH < 4.9) upstream reach in forms of goethite and/or hematite. In contrast, other metals tended to be transported farther downstream and settled in a low-gradient reach with high pH (mean pH > 5.6). The peak of sediment-borne Al, Be, Ca, Cd, Co, Cu, La, Mn, Ni and Zn corresponded very well with the peak of the sediment-borne organic matter, suggesting a close association between the water-borne organic colloids and the inorganic metal oxides/hydroxides during their transport. The marked increase in the sediment-borne Al and Pb started more upstream than the other metals, suggesting that the water-borne Al and Pb were more susceptible to pH rise-induced precipitation, as compared to the other metals. It appeared that the organic colloids played no important role in Pb transport and settlement. The iron precipitates had a limited role to play in affecting the transport and fates of other metals since they were predominantly formed and deposited in the acidic reach, which made them incapable of scavenging cationic metals by co-precipitation or adsorption.     

基于模糊数学综合评判的库岸稳定性分段——以新疆某水电站近坝库岸为例

从影响库岸稳定性的诸因素中筛选出六个主要因素：坡度、坡体形态、坡体完整性程度、库水面宽度、主风向与库岸夹角及坡体结构,根据其影响程度确定了它们的权重,将库岸稳定性分为良好、较好、较差和差四级。按照各个影响因素对斜坡和各级稳定性的影响不同,对各单因素进行离散化处理,得到各影响因素的隶属度矩阵。通过对各单因素矩阵与影响因素权重运算,得到各个单元分区的稳定性评价结果。运用该方法对新疆某水电站近坝库岸段20km的稳定性进行了评价,认为稳定性较差库岸段总长约4.1km,占20.3%,主要为地质灾害分布处及工程地质条件较差的地段。该综合评判成果与现场勘察及遥感解译结果较为一致。     

鸟粪石结晶法预处理垃圾渗滤液中高浓度氨氮的研究

利用鸟粪石结晶法预处理垃圾渗滤液中的高浓度氨氮,通过单因素实验和正交实验探讨了pH值、添加剂种类、添加剂比例、反应时间4个因素对氨氮去除率的影响,结合反应过程中的经济成本得出鸟粪石结晶法最佳工艺条件为:pH=9,添加剂为MgC12·6H2O和Na2HPO4·12H2O,n(Mg2+):n(NH4+):n(PO43-)=1:1:1,反应时间15min,氨氮去除率达到90.13%,剩余氨氮在300mg/L以下。通过XRD和ESEM分析,沉淀产物为鸟粪石。实验表明鸟粪石结晶法可以有效去除垃圾渗滤液中的高浓度氨氮,为后续使用生物法处理提供条件,也可以弥补矿物吸附法去除氨氮的不足。可将其与生物法、矿物吸附法等方法组合使用,综合处理垃圾渗滤液。     

The effects of soil sand contents on characteristics of humic acids along soil profiles

It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E₄/E₆ ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches.     

大气污染物SOx输送方程的尺度分析

文中用量纲分析方法分析了控制大气污染物输送方程的动力学特性。提出了 6种反映大气污染物输送过程中各种动力、物理和化学过程相对重要性的动力学参数。并以硫氧化物为例进行了各参数量级大小分析 ,尤其对 3种起汇作用 (去除机理 )的机理 (化学转化、干沉降和湿清除 )在不同尺度大气污染过程中的作用进行了详细分析。结果表明 :在一般情况下 ,SO2 的气相化学作用小于干沉降和湿清除的作用 ;干沉降作用很依赖于模式最底层厚度的选取 ;在有降雨时湿清除作用一般较大。文中还对大气污染物SOx 输送方程各项特征量的量级作了分析对比 ,得出了控制不同尺度大气污染物输送过程的零级近似方程和一级近似方程 ,并指出了这些方程的基本特征     

北太平洋海表持续加热对夏季中国降水及大气环流的影响

用海温距平累积和讨论了北太平洋海温异常持续加热对夏季中国降水和大气环流的影响。结果表明：ＳＴＰＮＡ（海温的太平洋北美遥相关型）指数距平累积和与江淮流域夏季降水有密切的相关,与全国雨带的类型也有较好的联系。进而讨论了ＳＴＰＮＡ指数距平累积和对大气环流的影响。     

机载粉剂催化剂播撒设备的研制及其在奥运和残奥消云中的应用

人为引发的下沉气流可以抑制对流云的发展,这一现象已在试验中得到验证。用“人工下沉气流法”实施人工消云试验时,需在云顶大剂量的播撒粉剂催化剂。北京市人工影响天气办公室研制了能完成此类大剂量播撤任务的设备,并通过外场飞行试验对设备进行检验和改进。这是国内人工影响天气领域首个采用空投播撒法的粉剂催化剂播撤设备;可减少催化剂对飞机和播撤设备的污染。分析发现,新设备能够满足人工消云作业中播撒大剂量粉剂催化剂的需要。该设备在北京奥运会、残奥会开闭幕式当日的消云试验作业中投入使用,共实施消云飞行作业9架次,累计利用新设备播撒吸湿性粉剂催化剂34吨。     

The mesoscale convection life cycle: Building block or prototype for large-scale tropical waves?

A cumulonimbus cloud may ascend and spawn its anvil cloud, precipitation, and downdrafts within an hour or so. This paper inquires why a similar progression of events (life cycle) is observed for tropical weather fluctuations with time scales of hours, days, and even weeks. Regressions using point data illustrate the characteristic unit of rain production: the mesoscale convective system (MCS), covering tens of kilometers and lasting several hours, with embedded convective rain cells. Meanwhile, averages over larger spatial areas indicate a self-similar progression from shallow to deep convection to stratiform anvils on many time scales.Synthetic data exercises indicate that simple superpositions of fixed-structure MCS life cycles (the Building Block hypothesis) cannot explain why longer period life cycles are similar. Rather, it appears that an MCS may be a small analogue or prototype of larger scale waves. Multiscale structure is hypothesized to occur via a Stretched Building Block conceptual model, in which the widths (durations) of zones of shallow, deep, and stratiform anvil clouds in MCSs are modulated by larger scale waves.Temperature (T) and humidity (q) data are examined and fed into an entraining plume model, in an attempt to elucidate their relative roles in these large-scale convection zone variations. T profile variations, with wavelengths shorter than troposphere depth, appear important for high-frequency ( 2–5-day period) convectively coupled waves, as density directly links convection (via buoyancy) and large-scale wave dynamics (via restoring force). Still, the associated q anomalies are several times greater than adiabatic, suggesting a strong amplification by shallow convective feedbacks. For lower frequency (intraseasonal) variability, q anomalies are considerably larger compared to T, and may be dominant.