The physical and chemical properties of circumstellar envelopes

An overview is given of recent results on some basic properties of the circumstellar envelopes of evolved stars. The focus is on well studied examples which illustrate envelopes of different types and at different stages of evolution. The close connection between the physical and chemical properties of the envelopes is emphasized.     

Environmental assessment of elements and polyaromatic hydrocarbons emitted from a Canadian coal-fired power plant

A detailed assessment of elements was carried out at a power plant rated at approximately 760 MW of electricity using western Canadian subbituminous coal. The concentrations of elements of environmental concern (As, Cd, Cr, Hg, Ni, and Pb) in milled coals, ashes, stack-emitted materials. Speciation of As, Cr, and Ni were determined. The polyaromatic hydrocarbons (PAHs) emitted from the stack were also measured. The rates of input of elemental input for As, Cd, Cr, Hg, Ni, and Pb were 28, 0.94, 230, 0.44, 44, and 88 kg/day, respectively; of which only 0.16, 0.01, 0.40, 0.27, 0.15, and 0.04 kg/day, respectively, were stack emitted. The total stack emission of toxic elements is 1.02 kg/day, with Cr being the highest contributor to this group with 0.4 kg/day. However, Hg at 0.27 kg/day has the highest percentage rate of emission at about 60%, while Cd has the lowest at about 1%. The electrostatic precipitator (ESP) removes a significant portion of the elements indicated by their relative enrichment (RE) ratios greater than 0.7. The results show that most of the elements in milled coal are low compared to world coals and other Canadian milled coals.Mercury is mostly ( 81%) emitted as gaseous elemental mercury (GEM), with 19% as reactive gaseous mercury (RGM). Particulate mercury is very low and averages about 0.1% of the total mercury at this station. Most of the arsenic in the milled coal is primarily associated with pyrite or as arsenate in its less toxic form of As⁺⁵ (> 95%). In both bottom and fly ashes, more than 95% of the total arsenic is present as As⁺⁵. Chromium in the milled coal and bottom ash is mostly non-toxic (Cr⁺³). The more toxic Cr⁺⁶ comprise less than 5% of the total Cr in the ESP fly ash and the stack-emitted ash. Nickel in milled coal and ashes is in the form of non-toxic Ni⁺², predominantly in coordination with oxygen.The emitted PAHs include acenapthene, fluorene, 2-methyl-fluorene, phenathrene, anthracene, fluoanthene, and pyrene; which are emitted from stack at the combined rate of 3.6 g/day. The concentrations of elements of environmental concern (As, Cd, Hg, Ni, and Pb) emitted to the atmosphere by the power plant in the zone of maximum impact at ground level are lower than those listed in the Health Guidelines of the USEPA and Canadian National Air Pollution Surveillance. This is based on stable meteorological conditions, down wind from the power plant for a maximum distance of 3 km.     

ICT-driven projects for land governance in Kenya: disruption and e-government frameworks

Critical academic research has yet to comprehensively identify conceptual linkages and tensions between information communication technologies (ICTs) and land governance projects. In order to make a contribution to these complex research fields, this article examines three Kenyan projects to illustrate different aspects of competing theoretical frameworks for ICT-based land rights projects. The projects documented land and property in the informal settlements of Kibera and Mathare in Nairobi, and in the rural community of Lari in Kiambu County. Drawing particularly on conceptual frameworks that emphasize the ‘disruptive’ potentials of ICTs, and frameworks based on e-government models, the article argues that these projects include both disruptive aspects, which work through applying pressure on the state, and more ‘integrative’ approaches which seek to build state capacity. The projects also rely on multiple stakeholders, and cannot be easily categorized within simple narratives of crowdsourcing, for example. Instead the realities are more complex and ‘success’ is difficult to assess, and potential uses of such projects are open and multiple.