The importance of aspect for modelling the hydrological response in a glacier catchment in Central Asia

Understanding how explicit consideration of topographic information influences hydrological model performance and upscaling in glacier dominated catchments remains underexplored. In this study, the Urumqi glacier no. 1 catchment in northwest China, with 52% of the area covered by glaciers, was selected as study site. A conceptual glacier‐hydrological model was developed and tested to systematically, simultaneously, and robustly reproduce the hydrograph, separate the discharge into contributions from glacier and nonglacier parts of the catchment, and establish estimates of the annual glacier mass balance, the annual equilibrium line altitude, and the daily catchment snow water equivalent. This was done by extending and adapting a recently proposed landscape‐based semidistributed conceptual hydrological model (FLEX‐Topo) to represent glacier and snowmelt processes. The adapted model, FLEX^G, allows to explicitly account for the influence of topography, that is, elevation and aspect, on the distribution of temperature and precipitation and thus on melt dynamics. It is shown that the model can not only reproduce long‐term runoff observations but also variations in glacier and snow cover. Furthermore, FLEX^G was successfully transferred and up‐scaled to a larger catchment exclusively by adjusting the areal proportions of elevation and aspect without the need for further calibration. This underlines the value of topographic information to meaningfully represent the dominant hydrological processes in the region and is further exacerbated by comparing the model to a model formulation that does not account for differences in aspect (FLEX^G,nA) and which, in spite of satisfactorily reproducing the observed hydrograph, does not capture the influence of spatial variability of snow and ice, which as a consequence reduces model transferability. This highlights the importance of accounting for topography and landscape heterogeneity in conceptual hydrological models in mountainous and snow‐, and glacier‐dominated regions.     

Evolution of cutoffs across meander necks in Powder River,Montana, USA

Over a period of several decades, gullies have been observed in various stages of forming, growing and completing the cutoff of meander necks in Powder River. During one episode of overbank flow, water flowing over the down-stream bank of the neck forms a headcut. The headcut migrates up-valley, forming a gully in its wake, until it has traversed the entire neck, cutting off the meander. The river then follows the course of the gully, which is subsequently enlarged as the river develops its new channel. The complete process usually requires several episodes of high water: in only one of the five cases described herein was a meander cutoff initiated and completed during a single large flood. © 1998 John Wiley & Sons, Ltd.     

Susceptibility to oxidative stress of mussels (Mytilus galloprovincialis) in the Venice Lagoon (Italy)

The aim of this study was to evaluate the susceptibility to pollutant mediated oxidative stress of the Mediterranean mussel Mytilus galloprovincialis in the Venice lagoon (Italy).

In June 2003, mussels from a farm were transplanted to eight sites in the lagoon for five weeks. Oxidative stress responses were measured by: (i) total oxyradical scavenging capacity (TOSC) assay, for an overall evaluation of the oxidative stress response capability; (ii) catalase (CAT), as a key enzyme involved in the antioxidant defence system; (iii) malondialdehyde (MDA), as an indicator of lipid peroxidation, to evaluate an oxidative damage; (iv) metallothioneins (MTs), as they play a role in the antioxidant defence.

The TOSC analysis revealed a reduced capability to eliminate: (i) peroxyl radical in mussels transplanted at Palude della Rosa, Valle Millecampi and Chioggia; (ii) hydroxyl radical at Campalto and Valle Millecampi; (iii) peroxynitrite at Valle Millecampi.

Inhibition in CAT activity, observed in all the monitored sites, confirms the presence of an oxidative pressure in transplanted mussels.

In addition, Pearson correlation analysis was performed in order to observe possible links between the various parameters. The PCA was a powerful tool to discriminate impacted sites, suggesting that the mussels transplanted throughout the Venice lagoon were subjected to different levels of oxidative pressure. Furthermore, it provided an easy and useful tool to summarize the obtained results.     

Stability of lysosomal and cell membranes in haemocytes of the common mussel (Mytilus edulis): effect of low temperatures.

Expanding industrial activities in the Arctic require an urgent assessment of the toxicity of chemicals at low temperatures. Organisms acclimatized to low temperature exhibit specific adaptations. For example, the amount of unsaturated lipids is increased to maintain the fluidity of the cell membranes. It has been hypothesized that such temperature-induced alterations in membrane lipid composition may affect the stability of lysosomal and cell membranes in the common mussel, Mytilus edulis, an organism exposed to seasonal temperature extremes. As mussels may be exposed to petroleum compounds along industrialized coastlines, we tested the combined effects of exposure to low temperature and the petroleum compound, phenanthrene, on haemocyte membrane stability. Test animals, acclimated to either 0 or 10 degrees C, were exposed to phenanthrene (0 = control or 500 micrograms l-1) and haemocytes were examined using the neutral red retention assay (lysosomal stability) and a fluorescence assay (cell membrane stability). At 0 degree C, lysosomal and cell membranes from uncontaminated mussels were destabilized compared with 10 degrees C (P = 0.0005). No significant effects (P > 0.05) of phenanthrene were detected at either temperature. Possible mechanisms underlying membrane destabilization include a weaker physical resistance of the membrane due to a higher amount of unsaturated lipids, a potentially higher level of reactive oxygen radicals at low temperature and the higher susceptibility of unsaturated lipids to oxidative stress. More work is required to better understand the consequences of this membrane destabilization at low temperature on the susceptibility of the organism to pollutants.     

Ecohydrological modelling with EcH2O‐iso to quantify forest and grassland effects on water partitioning and flux ages

We used the new process‐based, tracer‐aided ecohydrological model EcH₂O‐iso to assess the effects of vegetation cover on water balance partitioning and associated flux ages under temperate deciduous beech forest (F) and grassland (G) at an intensively monitored site in Northern Germany. Unique, multicriteria calibration, based on measured components of energy balance, hydrological function and biomass accumulation, resulted in good simulations reproducing measured soil surface temperatures, soil water content, transpiration, and biomass production. Model results showed the forest “used” more water than the grassland; of 620 mm average annual precipitation, losses were higher through interception (29% under F, 16% for G) and combined soil evaporation and transpiration (59% F, 47% G). Consequently, groundwater (GW) recharge was enhanced under grassland at 37% (~225 mm) of precipitation compared with 12% (~73 mm) for forest. The model tracked the ages of water in different storage compartments and associated fluxes. In shallow soil horizons, the average ages of soil water fluxes and evaporation were similar in both plots (~1.5 months), though transpiration and GW recharge were older under forest (~6 months compared with ~3 months for transpiration, and ~12 months compared with ~10 months for GW). Flux tracking using measured chloride data as a conservative tracer provided independent support for the modelling results, though highlighted effects of uncertainties in forest partitioning of evaporation and transpiration. By tracking storage—flux—age interactions under different land covers, EcH₂O‐iso could quantify the effects of vegetation on water partitioning and age distributions. Given the likelihood of drier, warmer summers, such models can help assess the implications of land use for water resource availability to inform debates over building landscape resilience to climate change. Better conceptualization of soil water mixing processes and improved calibration data on leaf area index and root distribution appear obvious respective modelling and data needs for improved simulations.     

The effect of forcing and landscape distribution on performance and consistency of model structures

It is often challenging to determine the appropriate level of spatial model forcing and model distribution in conceptual rainfall‐runoff modelling. This paper compares the value of incorporating both spatially distributed forcing data and spatially distributed model conceptualisations based on landscape heterogeneity, applied to the Ourthe catchment in Belgium. Distributed forcing data were used to create a spatial distribution of model states. Eight different configurations were tested: a lumped and distributed model structure, each with four levels of model state distribution. The results show that in the study catchment the distributed model structure can in general better reproduce the dynamics of the hydrograph, and furthermore, that the differences in performance and consistency between calibration and validation are smallest for the distributed model structure with distributed model states. For the Ourthe catchment, it can be concluded that the positive effect of incorporating a distributed model structure is larger than that of incorporating distributed model states. Distribution of model structure increases both model performance and consistency. Copyright © 2015 John Wiley & Sons, Ltd.     

Sulfur-rich monazite with high common Pb in ore-bearing schists from the Schellgaden mining district (Tauern Window, Eastern Alps)

The compositional variation of accessory monazite in ore bearing micaschists from the Schellgaden mining district, Tauern Window, Eastern Alps, was studied by means of the electron microprobe. In ore-rich domains monazite yields unusually high sulfur contents (up to 2.5?wt.% SO₃), which enter the monazite structure together with Ca and Sr as ??anhydrite-celestine?? component replacing P and REEs. The exchange reaction is S⁶⁺+ (Ca, Sr)²⁺ = REE³⁺+ P⁵⁺. Sulfur-rich monazite is intergrown with anglesite, pyromorphite or galena and shows oscillatory zoning indicating growth from S-bearing fluids. This type of S-enriched monazite yields very high common lead contents (up to 0.5?wt.% PbO) and unrealistic high apparent Th-U-total Pb single dates (> 1?Ga). However, S-enriched monazite grains provide a flat trendline in the Th* vs. Pb isochron diagram similar to the trendline defined through low-S, and low-Pb monazite crystals (0.1?C1?wt.% SO₃, < 0.05?wt.% PbO), which were observed in ore-poor parts of micaschists. Results from this study imply an Alpine rather than a pre-Alpine formation age for monazite and a strong S-rich fluid activity during the Alpine orogeny. Apart from this geological aspect, the current study also shows that the detection of sulfur in monazite may serve as a warning for a possible presence of common Pb.