Does chlorophyllidea reduce reliability of chlorophylla measurements in marine coastal sediments?

Pigment concentrations (chlorophylla, chlorophyllidea and pheopigmentsa) were measured by HPLC and spectrophotometry with acidification on 57 samples collected in different marine coastal sediments, containing autochthonous microphytes, and with various organic matter contents (plant detritus, biodeposits or hydrocarbons). Statistical analysis shows that the spectrophotometry with acidification, as compared to HPLC, gives reliable values for chlorophylla. Chlorophyllidea concentrations may be considered as negligible. Though spectrophotometric methods are sometimes questioned when applied to sediments they appear to give easy, quick and good estimates of Chla contents in benthic microphytes for hydrobiological studies in coastal areas.     

Présence de Paléocène marin dans les Grands Causses (France)

In the Grands Causses, incised valleys, lapies, fissures and sinkholes inherited from successive polyphase karstifications were filled by Palaeocene marine sediments overall assigned to the P1c–P3 interval (Upper Danian–Lower Selandian). These sediments are distributed into three detritic facies, generated by extensional tectonics controlling karstic and erosional processes. Upper Cretaceous marine fossils known within these facies are interpreted as reworked from hypothetically pellicular deposits. The probable palaeogeographic connection with the Pyrenean Palaeocene ‘Breccia trough’ supposes the presence of a SE–NW ‘ria’ running across the continental areas of Lower Languedoc and draining towards the northwest the marine waters of the Palaeocene transgression as far as the Rodez region. To cite this article: B. Peybernès et al., C. R. Geoscience 335 (2003).     

Density and magnetic field fluctuations observed by ISEE 1–2 in the quiet magnetosheath

We analyse the fluctuations of the electron density and of the magnetic field in the Earth’s magnetosheath to identify the waves observed below the proton gyrofrequency. We consider two quiet magnetosheath crossings i.e. 2 days characterized by small-amplitude waves, for which the solar wind dynamic pressure was low. On 2 August 1978 the spacecraft were in the outer magnetosheath. We compare the properties of the observed narrow-band waves with those of the unstable linear wave modes calculated for an homogeneous plasma with Maxwellian electron and bi-Maxwellian (anisotropic) proton and alpha particle distributions. The Alfvén ion cyclotron (AIC) mode appears to be dominant in the data, but there are also density fluctuations nearly in phase with the magnetic fluctuations parallel to the magnetic field. Such a phase relation can be explained neither by the presence of a proton or helium AIC mode nor by the presence of a fast mode in a bi-Maxwellian plasma. We invoke the presence of the helium cut-off mode which is marginally stable in a bi-Maxwellian plasma with <alpha> particles: the observed phase relation could be due to a hybrid mode (proton AIC + helium cut-off) generated by a non-Maxwellian or a non-gyrotropic part of the ion distribution functions in the upstream magnetosheath. On 2 September 1981 the properties of the fluctuations observed in the middle of the magnetosheath can be explained by pure AIC waves generated by protons which have reached a bi-Maxwellian equilibrium. For a given wave mode, the phase difference between B _\Vert and the density is sensitive to the shape of the ion and electron distribution functions: it can be a diagnosis tool for natural and simulated plasmas.     

Progressive change of tidal wave characteristics from the eastern Yellow Sea to the Asan Bay,a strongly convergent bay in the west coast of Korea

Although there have been studies on the tide in convergent bay (or estuary), the tide change in terms of phase speed, amplitude, and phase difference between elevation and tidal current from a coastal ocean to a convergent bay has not been clearly shown so far. This study systematically examines the change of tidal wave characteristics from the eastern Yellow Sea to the Asan Bay, a strongly convergent bay on the west coast of Korea, using observations and an analytical model. As the tidal wave propagates from the eastern Yellow Sea into the Asan Bay, the phase speed, amplitude, and phase difference between elevation and tidal current increase along the channel. Such a phenomenon represents a unique example of tide change from a coastal ocean to a convergent bay, indicating dominance of convergence over friction in the Asan Bay. Both analytically computed tidal amplitude and travelling time compare well with observations. In the Asan Bay, the influence of the reflected wave is only felt in the upper one fifth of the bay and is almost unperceivable in the rest of the bay. The analytical analyses presented in this paper are particularly useful for understanding the relative importance of channel convergence, bottom friction, and reflected wave on the tidal characteristics change along the channel and the proposed method could be applicable to other estuaries.     

Elucidating microbial processes in nitrate- and sulfate-reducing systems using sulfur and oxygen isotope ratios: The example of oil reservoir souring control

Sulfate-reducing bacteria (SRB) are ubiquitous in anoxic environments where they couple the oxidation of organic compounds to the production of hydrogen sulfide. This can be problematic for various industries including oil production where reservoir “souring” (the generation of H₂S) requires corrective actions. Nitrate or nitrite injection into sour oil fields can promote SRB control by stimulating organotrophic nitrate- or nitrite-reducing bacteria (O-NRB) that out-compete SRB for electron donors (biocompetitive exclusion), and/or by lithotrophic nitrate- or nitrite-reducing sulfide oxidizing bacteria (NR-SOB) that remove H₂S directly. Sulfur and oxygen isotope ratios of sulfide and sulfate were monitored in batch cultures and sulfidic bioreactors to evaluate mitigation of SRB activities by nitrate or nitrite injection. Sulfate reduction in batch cultures of Desulfovibrio sp. strain Lac15 indicated typical Rayleigh-type fractionation of sulfur isotopes during bacterial sulfate reduction (BSR) with lactate, whereas oxygen isotope ratios in unreacted sulfate remained constant. Sulfur isotope fractionation in batch cultures of the NR-SOB Thiomicrospira sp. strain CVO was minimal during the oxidation of sulfide to sulfate, which had δ¹⁸O_SO4 values similar to that of the water-oxygen. Treating an up-flow bioreactor with increasing doses of nitrate to eliminate sulfide resulted in changes in sulfur isotope ratios of sulfate and sulfide but very little variation in oxygen isotope ratios of sulfate. These observations were similar to results obtained from SRB-only, but different from those of NR-SOB-only pure culture control experiments. This suggests that biocompetitive exclusion of SRB took place in the nitrate-injected bioreactor. In two replicate bioreactors treated with nitrite, less pronounced sulfur isotope fractionation and a slight decrease in δ¹⁸O_SO4 were observed. This indicated that NR-SOB played a minor role during dosing with low nitrite and that biocompetitive exclusion was the major process. The results demonstrate that stable isotope data can contribute unique information for understanding complex microbial processes in nitrate- and sulfate-reducing systems, and offer important information for the management of H₂S problems in oil reservoirs and elsewhere.     

Evidence for pre-orogenic,Early Devonian rifting in the Variscan belt: stratigraphy and structure of the Palaeozoic cover of the Mauges Unit (Upper Allochthon,Armorican massif,France)

The Palaeozoic sediments from the Mauges Unit (Armorican Massif, France) are the best-preserved pre-orogenic sequences belonging to the Upper Allochthon. Two coherent sequences are identified. The southern unit (Chateaupanne Unit) represents the cover of the Proterozoic basement and consists of Ordovician sediments unconformably overlain by Emsian carbonates followed by Emsian to earliest Eifelian immature sandstones. The northern unit (Tombeau Leclerc Unit) consists of an Hirnantian to Emsian condensed sequence, in reverse position, that has been thrust over the southern unit. The Devonian unconformity is interpreted as evidence for an Early Devonian extension, recorded by normal faults affecting both the Early Devonian limestones and the underlying Ordovician series. This crustal extension, recorded here for the first time, is possibly related to the opening of a back-arc basin (Saint-Georges-sur-Loire) associated with the subduction of an ocean located further south (Galicia-Brittany-Massif Central Ocean).     

He,Pb, Sr and Nd isotope constraints on magma genesis and mantle heterogeneity beneath young Pacific seamounts

Pb, Sr and Nd isotope variations are correlated in diverse lavas erupted at small seamounts near the East Pacific Rise. Tholeiites are isotopically indistinguishable from MORB (²⁰⁶Pb/²⁰⁴Pb=18.1–18.5; ⁸⁷Sr/⁸⁶Sr=0.7023–0.7028; ¹⁴³Nd/¹⁴⁴Nd=0.51326-0.51308); associated alkali basalts always show more radiogenic Pb and Sr signatures (²⁰⁶Pb/²⁰⁴Pb=18.8–19.2; ⁸⁷Sr/⁸⁶Sr=0.7029–0.7031) and less radiogenic Nd (¹⁴³Nd/¹⁴⁴Nd=0.51289–0.51301). The isotopic variability covers 80% of the variability for Pacific MORB, due to the presence of small-scale heterogeneity in the underlying mantle. Isotope compositions also correlate with trace element ratios such as La/Sm. Tholeiites at these seamounts have ³He/⁴He between 7.8–8.7 R _A(R _A= atmospheric ratio), also indistinguishable from MORB. He trapped in vesicles of alkali basalts, released by crushing in vacuo, has low ³He/⁴He (1.2–2.6 R)_Ain conjunction with low helium concentrations ([He]<5×10^–8 ccSTP/g). In many cases post-eruptive radiogenic ingrowth has produced He isotope disequilibrium between vesicles and glass in the alkali basalts; subatmospheric ³He/⁴He ratios characterize the He dissolved in the glass which is released by melting the crushed powders. The narrow range of ³He/⁴He in the vesicles of the alkali basalts suggests that low ³He/⁴He is a source characteristic, but given their low [He] and high (U + Th), pre-eruptive radiogenic ingrowth cannot be excluded as a cause for low inherited ³He/⁴He ratios. Pb, Sr and Nd isotope compositions in lavas erupted at Shimada Seamount, an isolated volcano on 20 m.y. old seafloor at 17°N, are distinctly different from other seamounts in the East Pacific (²⁰⁶Pb/²⁰⁴Pb=18.8–19.0, ⁸⁷Sr/ ⁸⁶Sr0.7048 and ¹⁴³Nd/¹⁴⁴Nd0.51266). Relatively high ²⁰⁷Pb/²⁰⁴Pb (15.6–15.7) indicates ancient (>2 Ga) isolation of the source from the depleted upper mantle, similar to Dupal components which are more prevalent in the southern hemisphere mantle. ³He/⁴He at Shimada Seamount is between 3.9–4.8 R _A. Because the helium concentrations range up to 1.5×10^–6, the low ³He/⁴He can not be due to radiogenic accumulation of ⁴He in the magma for reasonable volcanic evolution times. The low ³He/⁴He may be due to the presence of enriched domains within the lithosphere with high (U + Th)/He ratios, possibly formed during its accretion near the ridge. Alternatively, the low ³He/⁴He may be an inherent characteristic of an enriched component in the mantle beneath the East Pacific. Collectively, the He-Pb-Sr-Nd isotope systematics at East Pacific seamounts suggest that the range of isotope compositions present in the mantle is more readily sampled by seamount and island volcanism than by axial volcanism. Beneath thicker lithosphere away from the ridge axis, smaller degrees of melting in the source regions are less efficient in averaging the chemical characteristics of small-scale heterogeneities.     

Recent transfer of coastal sediments to the Laurentian Channel,Lower St. Lawrence Estuary (Eastern Canada), through submarine canyon and fan systems

Multibeam sonar data, acoustic sub-bottom profiles and box cores were used to study the activity of submarine canyons and fans near the city of Les Escoumins, on the North Shore of the Lower St. Lawrence Estuary (Eastern Canada). The multibeam data were used to generate a high-resolution digital terrain model that reveals the presence of a large number of canyons and fans along the northern slopes of the Laurentian Channel. This paper focuses on two of the larger canyons, and their associated submarine fans. The sub-bottom profiles on the fans reveal high-amplitude reflections at the sediment/water interface and near the seafloor surface, indicating the occurrence of layers of coarse material. A turbidite was observed in a box core sampled in one of the fans, confirming the nature of the coarse layer. Geophysical and sedimentological data indicate that the canyons and fans play an important role in transferring coastal sandy sediments to the deeper marine environments by longshore drift-initiated turbidity flows, and thereby contribute to the negative sediment budget along the coast. The morphology of the canyons indicates that they were produced by a combination of erosive turbidity flows and retrogressive failures. The two box cores sampled on the fans reveal a recent (~last 60 years) quasi-exponential increase in sand content near the surface of the cores, possibly reflecting recent deforestation and/or increased coastal erosion.