Pretreatment of high strength waste emulsions by combined vibratory shear enhanced process with Fenton oxidation

Pretreatment of waste emulsions with high organic content by a combined process of vibratory shear enhanced process and Fenton’s oxidation prior to biological treatment was investigated. Vibrating membrane had shown good performance in chemical oxygen demand and oil removals and the mitigation of concentration polarization. However, the permeate after filtration processing still contained high content of organics. Thus, additional Fenton oxidation was applied to reduce the organic loading, and improve the biodegradability of the wastewater. The optimal molar ratio of ferrous iron to hydrogen peroxide was 0.05 obtained from the jar-test experiments. Removal of organics was enhanced by increasing hydrogen peroxide dosage, while efficiency of hydrogen peroxide reached maximum of 1.11(w/w) at the hydrogen peroxide dosage of 6.8 g/L. Furthermore, the biological experiments indicated that the high concentration of organics could inhibit microbial activity, which decreased the chemical oxygen demand degradation rates. The adaptive period of the microbe was greatly shortened using Fenton’s reagent at the low dosages. The improvement of the biodegradability could be explained by partial mineralization and chemical transformation of parent organic compounds after Fenton oxidation.     

南秦岭东江口、柞水岩体岩石谱系单位划分及演化

南秦岭东江口、柞水岩体位于南丹断裂带南侧,为华力西期岩基。通过1：5万地质填图,将东江口老体划分为5个岩石谱系单位,柞水岩体划分为3个岩石话系单位,共圈定出36个侵入体。分别建立了东江口超单元和排水超单元。依据接触关系,结构构造,包体特征确定了其侵入序次,构成了两个完整的“S”型岩浆演化序列,在岩石矿物组成、岩石化学成分、微量元素及稀土元素组成上,各具有明显的独特岩浆演化特征,分别形成于南秦岭晚古生代被动陆线构造环境。     

岩浆-流体过渡和阿尔泰三号伟晶岩脉之成因

本文对新疆阿尔泰可可托海的三号伟晶岩形成的物理化学条件、特别是流体-熔融包裹体进行了研究，证明岩浆的确可以分出热液，对于三号伟晶岩脉来说，这种热液组分主要是NaCl－CO2－H2O流体。     

浙江花岗岩类地球化学与地壳演化——Ⅱ.元古宙花岗岩类

浙江元古宙花岗岩类包括神功期（1．8－1．9Ga）和晋宁晚期（0．6—0．9Ga）。研究了浙江元古宙花岗岩类的主元素、微量元素、稀土元素和Rb、Sr同位素组成特征及岩石成因，探讨了浙江地壳的演化。浙江地壳形成于太古亩和元古宙，地壳增生的时期为2．6－2．7、0．8-1．1和0.1－0.12Ga。随时间演化浙江地壳组成有变化，但分异演化不明显。沿江-绍断裂分布的晋宁晚期慢源和壳幔混合中酸性岩是普宁期俯冲碰撞的证据。加里乐和印支期是两次规模不大的构造运动。     

VBA在桩基检测数据批量处理中的应用

工程上有时需将Excel中的数据批量处理成Word文档,以充分利用Excel强大的数据处理和计算分析功能与Word较强的文字处理和排版能力。当工程数据信息较多时,采用传统手工编辑的方法,其工作量非常大,重复性工作多,既费时又很容易出错。结合大型桩基工程,利用Microsoft Office软件中的VBA编程方法实现了桩基检测信息的自动批量生成,为桩基检测提供了及时准确的数据,大大提高了工作效率,具有重要的应用价值。     

青海省都兰县果洛龙洼金矿成矿流体

果洛龙洼金矿是青海东昆仑地区最典型、最具规模的金矿床之一。在前人资料基础上,将果洛龙洼金矿热液成矿期划分为4个成矿阶段：贫矿化石英阶段、石英-多金属硫化物阶段（主要成矿阶段）、石英-贫硫化物阶段（次要成矿阶段）和石英-碳酸盐阶段。随后对主要和次要成矿阶段石英脉开展流体包裹体显微测温和H-O同位素研究。结果表明：原生流体包裹体主要包括气液两相、富CO₂三相、纯CO₂两相共3类;成矿流体总体以CO₂-NaCl-H₂O体系为主,均一温度为130.0~357.3 ℃,盐度（w(NaCl)）为1.83%~20.11%。石英-多金属硫化物阶段石英δ¹⁸O_V-SMOW值为14.8‰~17.2‰,据此计算流体的δ¹⁸O_H2O值为5.5‰~8.5‰,流体的δD_V-SMOW值为-61‰~-96‰;而石英-贫硫化物阶段石英δ¹⁸O_V-SMOW值为15.7‰~16.9‰,据此计算流体的δ¹⁸O_H2O值为4.1‰~5.3‰,流体的δD_V-SMOW值为-84‰~-101‰。由此认为：主要成矿阶段成矿流体可能为高温低盐度富CO₂变质热液和低温中高盐度岩浆热液两个端元组成的混合流体;次要成矿阶段成矿流体主要为混合后更均匀的中低温中低盐度热液,但后期明显有大气降水混入。总之,成矿流体的来源、性质及其演化等方面的研究结果进一步证明果洛龙洼金矿为造山型金矿。     

Calcified roasting-acid leaching process of vanadium from low-grade vanadium-containing stone coal

The low-grade vanadium-containing stone coal used in this experiment was collected from Wuxi Coun- try, Chongqing City, China. The experiment focused on the vanadium recovery from roasted residue through opti- mizing the process conditions of an effective and environmentally-friendly technology, named calcified roast- ing-sulfuric acid leaching technology. By single-factor experiments and orthogonal experiments, the effects of roast- ing temperature, roasting time, sulfuric acid concentration and leaching time on the leaching ratio of vanadium were analyzed. The results showed that the leaching ratio of vanadium reached 85.5% under the proper technological con- ditions of roasting temperature=950℃, roasting time=4 h, 40% concentration of sulfuric acid and leaching time=6 h.     

麦饭石对腐殖酸及重金属离子的吸附作用

研究了麦饭石对腐殖酸和重金属离子（Ｈｇ２＋,Ｐｂ２＋,Ｃｕ２＋,Ｚｎ２＋,Ｃｄ２＋）的吸附作用,实验结果表明麦饭石对腐殖酸和重金属离子都具有较好的吸附性能,且腐殖酸的存在有利于麦饭石对重金属离子的吸附。ｐＨ值是影响吸附的重要因素,当ｐＨ值为５．０～６．０时,麦饭石同时吸附腐殖酸和重金属离子的效果最好,麦饭石在吸附腐殖酸和重金属离子的同时能溶出微量元素硒,这对于大骨节病的防治有重要意义。     

川滇地区某纯橄榄岩地质特征

本文对川滇地区某纯橄榄岩体的地质特征进行了初步研究。该岩体的岩石新鲜，几乎没有蛇纹石化。岩体具层状构造，岩石中发育扭折带、巨晶、碎斑、等粒镶嵌结构、板块镶嵌结构等特殊的地幔岩结构构造。此外，岩石化学及地球化学特征了都表明该纯橄榄岩体属于蛇绿岩层序中堆积的一个组成部分。