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931.
为了解江苏某材料厂金属冶炼活动引发的重金属污染风险,采集周围农田土壤、小麦和水稻籽实样品,确定Mo含量及其在土壤中的形态,采用地质累积指数和富集因子指标评价土壤中钼的污染风险,采用健康风险指数评价小麦、稻米中Mo的健康风险。结果表明,农田土壤中Mo含量在0.50~63.2 mg/kg之间,其平均值5.70 mg/kg远高于全省平均值0.65 mg/kg,表层土壤出现了中度—高度富集,近70%的样点受到不同程度的钼污染,污染范围距该厂300 m,污染深度>1.5 m。土壤中的Mo具有较高的生物有效性,在小麦、水稻籽实中显著富集,主要与土壤具有较高的全Mo含量以及土壤呈碱性有关。基于EPA的健康风险评估方法,食用当地稻米、小麦会产生较大的健康风险。 相似文献
932.
Xinmiao Zhao Hongfu Zhang Xiangkun Zhu Suohan Tang Yanjie Tang 《Contributions to Mineralogy and Petrology》2010,160(1):15-14
Iron isotopes, together with mineral elemental compositions of spinel peridotite xenoliths and clinopyroxenites from Hannuoba
and Hebi Cenozoic alkaline basalts, were analyzed to investigate iron isotopic features of the lithospheric mantle beneath
the North China Craton. The results show that the Hannuoba spinel peridotite xenoliths have small but distinguishable Fe isotopic
variations. Overall variations in δ57Fe are in a range of −0.25 to 0.14‰ for olivine, −0.17 to 0.17‰ for orthopyroxene, −0.21 to 0.27‰ for clinopyroxene, and −0.16
to 0.26‰ for spinel, respectively. Clinopyroxene has the heaviest iron isotopic ratio and olivine the lightest within individual
sample. No clear linear relationships between the mineral pairs on “δ-δ” plot suggest that iron isotopes of mineral separates
analyzed have been affected largely by some open system processes. The broadly negative correlations between mineral iron
isotopes and metasomatic indexes such as spinel Cr#, (La/Yb)N ratios of clinopyroxenes suggest that iron isotopic variations in different minerals and peridotites were probably produced
by mantle metasomatism. The Hebi phlogopite-bearing lherzolite, which is significantly modified by metasomatic events, appears
to be much heavier isotopically than clinopyroxene-poor lherzolite. This study further confirms previous conclusions that
the lithospheric mantle has distinguishable and heterogeneous iron isotopic variations at the xenoliths scale. Mantle metasomatism
is the most likely cause for the iron isotope variations in mantle peridotites. 相似文献
933.
Huang Bolin Chen Lide Peng Xuanming Liu Guanning Chen Xiaoting Dong Haogang Lei Tianci 《Landslides》2010,7(1):1-11
In 2007 and 2008, six big damaging rockfalls occurred at four sites in Wu Gorge, the second gorge of the Three Gorges, China.
Detailed surveys and aerial-photographic interpretation identified 104 potentially dangerous rock masses. This paper reviews
previous rock-mass risk ratings, examines dangerous rock-mass structure and presents a new assessment system for rockfall
risk (ASRFR) in the Wu Gorge area. The ASRFR considers 15 factors: seven factors for hazard and eight factors for consequence.
Relative importance weights for these factors are ascertained using an analytic hierarchy process. Using an equation to calculate
the risk, the 104 dangerous rock masses were divided into three risk groups: high risk (33 sites), medium risk (33 sites)
and low risk (38 sites). The ASRFR analysis can be used to divide the shipping route through the Wu Gorge into seven courses
each of one of three classes: safe-route regions, yellow-alarm regions and red-alarm regions. The system provides geological
information and a rockfall-risk management tool for local government and the shipment-route department. 相似文献
934.
Ling-zhi Huang Guang-ming Zeng Dan-lian Huang Li-feng Li Chun-yan Du Ling Zhang 《Environmental Earth Sciences》2010,60(8):1683-1691
Biosorption is an effective method to remove heavy metals from wastewater. In this work, the biosorption of Cd(II) onto Hydrilla verticillata was examined in aqueous solution with parameters of initial pH, adsorbent dosage, contact time, initial Cd(II) concentration,
temperature, and co-existing ion. Linear Langmuir and Freundlich models were applied to describe the equilibrium isotherms,
and both of the two models were fitted well. The monolayer adsorption capacity of Cd(II) was found to be 50 mg/g at pH 6 and
20°C. Dubinin–Radushkevich isotherm model was also applied to the equilibrium data. The mean free energy of adsorption (11.18 kJ/mol)
indicated that the adsorption of Cd(II) onto H. verticillata might be carried out via chemical ion-exchange mechanism. Thermodynamic parameters, including free energy (∆G
0), enthalpy (∆H
0), and entropy (∆S
0) of adsorption, were also calculated. These results showed that the biosorption of Cd(II) onto H. verticillata was a feasible, spontaneous, and exothermic process in nature. Desorption experiments indicated that 0.01 mol/L EDTA and
HNO3 were efficient desorbents for the recovery of Cd(II) from biomass. IR spectrum analysis suggested that amido, hydroxyl, C=O
and C–O could combine strongly with Cd(II). EDX spectrum analysis suggested that an ion exchange mechanism might be involved. 相似文献
935.
Flat rare earth element patterns as an indicator of cumulate processes in the Lesser Qinling carbonatites, China 总被引:1,自引:0,他引:1
Cheng Xu Ian H. Campbell Charlotte M. Allen Zhilong Huang Liang Qi Huan Zhang Guishan Zhang 《Lithos》2007,95(3-4):267-278
The Lesser Qinling carbonatite dykes are mainly composed of calcites. They are characterized by unusually high heavy rare earth element concentrations (HREE; e.g. Yb > 30 ppm) and flat to weakly light rare earth element (LREE) enriched chondrite-normalized patterns (La/Ybn = 1.0–5.5), which is in marked contrast with all other published carbonatite data. The trace element contents of calcite crystals were measured in situ by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). Some crystals show reduced LREE from core to rim, whereas their HREE compositions are relatively constant. The total REE contents and chondrite-normalized REE patterns from the cores of carbonate crystals are similar to those of the whole rock. The carbon and oxygen isotopic compositions of calcites fall within the range of primary, mantle-derived carbonatites. The initial Sr isotopic compositions (0.70480–0.70557) of calcites are consistent with an EM1 source or mixing between HIMU and EM1 mantle sources. However these sources cannot produce carbonatite parental magmas with a flat or slightly LREE enrichment pattern by low degrees of partial melting. Analyses of carbonates from other carbonatites show that carbonates have nearly flat REE pattern if they crystallize from a LREE enriched carbonatite melt. This implies that when carbonates crystallize from a carbonatite melt the calcite/melt partition coefficients (D) for HREE are much greater than the D for the LREE. The nearly flat REE patterns of the Lesser Qinling carbonatites can be explained if they are carbonate cumulates that contain little trapped carbonatite melt. Strong enrichment of HREE in the carbonatites may require their derivation by small degrees of melting from a garnet-poor source. 相似文献
936.
is paper is concerned with the geochemical features of major elements,transition metal elements,large ion lithophile elements,rare-earth elements and Sr isotopes in alkaline-ul-trabasic rocks in the Jijie complex of Lufeng,Yunnan Province,which is located in southern Sichuan-Yunnan rift zone,one of Luoci alkaline-ultrabasic complexes in central Ynnnan,Moreover,its origin pertaining primary magma,magma soure region,fractional crystallization,etc.are also discussed in the present paper. 相似文献
937.
云南老王寨金矿区煌斑岩的成因:稀土元素研究 总被引:6,自引:0,他引:6
云南老王寨金矿区煌斑岩与金矿化在时间上、空间上密切共生。主要元素分析表明,本区煌斑岩属钾质-富钾质钙碱性煌斑岩;与原始地幔和大洋中脊玄武岩相比,岩石相对富集稀土元素;模拟计算表明,岩石来源于稀土元素相对富集的交代富集地幔;地质发展史、不相容元素分配型式、Sr、Nd同位素组成及有关模拟计算表明,俯冲进入地幔楔的地壳物质脱水 流体是引起该区地幔交代作用的主要因素。 相似文献
938.
下扬子区二叠系层序地层的地球化学特征 总被引:4,自引:1,他引:4
本文以安徽巢县平顶山、鬼门关剖面为例,阐述了二叠系沉岩的主要岩石类型,即灰岩、硅质岩和泥质岩的岩石学特征及稀土元素组成特点;划分出七种沉积相类型,即局限台地相、开阔台地相、斜坡相、盆地相、三角洲相、汪 相和陆缘泻湖相;识别出七个Ⅲ级层序,其中四个为Ⅰ型层,三个为Ⅱ型层序。对栖霞组灰岩的地球化学测试数据进行了统计分析,总结了海侵体系域,高水位体系域的氧碳同位素、稀土元素和微量元素组成的差异,并认为造 相似文献
939.
曲边冰洲石的发现及其矿床成因的探讨 总被引:2,自引:0,他引:2
在各类型冰洲石矿床中发现了大量的冰洲石弯晶,通过冰洲石矿床野外考察的归纳总结,联系到晶体生长和材料力学的有关知识,提出冰州石矿床的成因极可能是原矿床中方解石受到的构造运动强烈影响后,在长期的水淋滤改造作用下发生冰洲石化,并由此而形成冰洲石矿床。 相似文献
940.