锡同位素研究进展及其在矿床学中的应用展望

锡同位素是一种新兴的非传统稳定同位素,其在考古学及天体化学中的运用显示出非常大的示踪潜力和价值,然而目前其在地质学(尤其是矿床学)中的研究和应用前景缺乏系统介绍.本文总结分析了世界上目前所发表的主要天然及人工样品的锡同位素数据,发现天然样品中锡同位素组成有较大差异,其中玻璃陨石最富重锡(其δ122/118 Sn值可达2.53‰),而黝锡矿(黄锡矿)最富轻锡(其δ120/116Sn值可达-1.71‰).其中,含锡矿物(如锡石和黝锡矿)中的锡同位素组成变化范围要远远大于全岩样品.地幔及地壳来源的不同岩性或地质体的全岩锡同位素组成有明显差别;锡同位素在一定条件下可以发生分馏,且分馏程度可能远远大于锡同位素的初始值差异.锡石锡同位素对成矿环境非常敏感,其形成时的流体成分、化学反应速率以及物化条件(如温度、盐度、氧逸度、pH值等)等因素均能影响其锡同位素的组成.深部流体(如岩浆来源)结晶的锡石富重锡,而浅部流体(如地层流体)的加入将使锡石富轻锡,因此锡石的锡同位素具有判别不同矿床成因类型的潜力.展望未来,锡同位素的研究有望在以下三方面取得突破:①各地球圈层锡同位素储库数据的精确测定;②矿物原位微区锡同位素的准确快速分析;③热液矿床锡同位素分馏机制的建立.聚焦岩浆-热液演化过程中含锡矿物的锡同位素组成变化,有望揭示含锡流体性质及物化环境,从成矿流体来源、演化、沉淀等角度探讨成矿过程中锡同位素分馏的控制因素及其示踪机制,建立复杂锡成矿系统中的锡同位素演化模型.系统的锡同位素研究可为深入认识多类型锡矿化的"源"、"运""储"过程提供新的思路,为判别有争议锡矿床的成因类型及成矿物质来源提供关键的锡同位素证据,进而为研究大规模锡多金属成矿作用提供全新的视角,具有重要的理论价值及现实意义.     

武夷地块中南平-宁化构造带南华纪弧火山岩属性及其对华夏板块多微地体拼合的启示

武夷地块中各地体的活动解析是认识华夏板块构造活动演化的窗口.南平宁化构造带作为划分南武夷地体和北武夷地体的重要边界活动带,其构造属性对我们认识武夷地块中南、北武夷地体的构造演化具有重要意义.前人对南平-宁化构造带中变质火山岩类的研究和认识存在争议,限制了我们对南平-宁化构造带的构造属性的理解.因此,本文利用野外路线地质调查、年代学测定、同位素地球化学测试等手段,对该套变质火山岩做了重点研究,结合前人的研究成果,我们得到以下认识:南平-宁化构造带中的变质火山岩类主要形成于756～720 Ma,主要形成于活动大陆边缘或岛弧环境,表明南平-宁化构造带可能代表了南武夷地体和北武夷地体之间的一条南华纪的近东西向的岛弧火山活动带,结合带中构造变形反映的南北向对冲的汇聚极性,我们认为南武夷地体和北武夷地体之间在南华纪可能还存在洋-陆碰撞乃至陆-陆拼合过程,这也反映了多微地块、多期拼合过程可能更符合华夏板块大地构造演化的主旋律.     

豫西汝阳群、洛峪群碎屑锆石年代学特征及其地质意义

华北克拉通南缘"豫陕裂陷槽"发育大量中—新元古代地层,其中汝阳群和洛峪群分布于渑池—确山地层小区,其形成时代一直存有争议.本文针对汝阳群和洛峪群沉积岩进行了系统的碎屑锆石年代学研究工作,结合地层发育和岩石组合分析,为建立华北克拉通南缘中—新元古代地层框架提供依据.根据云梦山组下部碎屑锆石中获得年轻锆石年龄平均值1723.6 Ma,结合前人从洛峪群凝灰岩夹层中获得的年代学资料(1611±8 Ma、1640±16 Ma、1638±9 Ma、1634±10 Ma),将汝阳群-洛峪群的沉积时限限定在1720～1600 Ma之间.本文所采集的云梦山组、白草坪组和崔庄组样品中碎屑锆石207Pb/206Pb年龄分别在2657～1739 Ma、2712～1780 Ma和2654～1819 Ma之间,说明三个组沉积物质主要来源于古元古代地质体,部分为新太古代地质体.鲁山地区发育的新太古代—古元古代的太华杂岩,登封地区发育的新太古代登封群以及古元古代嵩山群和花岗质岩石等,均可为中—新元古代沉积岩提供物源.豫西地区汝阳群-洛峪群碎屑锆石中～2.7 Ga、～2.5 Ga、2.1～2.0 Ga和1.85～1.8 Ga的年龄谱峰值分别对应华北克拉通早前寒武纪发生地壳生长、克拉通化、裂谷和造山等重要地质事件.越来越多资料显示华北克拉通在2.2～2.0Ga时期存在强烈的岩浆活动,豫西地区～2.1 Ga的岩浆作用也逐渐被识别出来.     

南秦岭柞水—山阳矿集区金铜矿床成矿规律与找矿方向

南秦岭柞水—山阳矿集区地质构造和岩浆活动强烈,矿床(点)成群成带分布,成矿条件良好。在长期找矿实践、成矿地质背景分析和典型矿床解剖的基础上,综合研究认为,区内金矿主要受EW向断裂或EW向韧-脆性剪切带与NE向张扭性叠加构造控制,寒武系水沟口组、泥盆系星红铺组与大枫沟组是金的赋矿地层。金矿体呈近EW向大致等间距展布,单个矿体在延伸方向呈透镜状、哑铃状、囊状等,具尖灭再现特征,构造叠加部位矿体厚大、品位较高。区内金矿床类型多为中-低温热液型、远成低温热液型,成矿时代为印支—燕山期。夏家店等已知金矿床深部及外围、区域断裂旁侧次级近EW向与NNE向断裂交汇部位、构造转折端、构造虚脱部位等是寻找金矿的有利靶区。铜矿分布于山阳—凤镇大断裂两侧,成矿类型以斑岩型-矽卡岩型为主,构造热液改造型、隐爆角砾岩型次之。斑岩型-矽卡岩型铜(钼)矿受燕山期构造-岩浆活动控制,赋存于燕山期斑岩体与围岩接触带内;矿体产状多受岩体与围岩接触面控制,呈似层状、透镜状产出。燕山期中酸性小岩体及其与围岩的接触部位、东西向三级断裂带附近是寻找铜(钼)矿的首选靶区。本次研究建立了柞水—山阳矿集区金铜矿床区域成矿模式,总结了找矿标志,通过成矿规律、成矿作用及物探、化探、遥感异常特征系统分析,认为区内找矿潜力巨大,并提出了3片金铜(钼)成矿远景区,指出下一步的找矿方向。     

喀斯特露石生境下构树和桑树的光合特征

以喀斯特适生植物构树（Broussonetia papyrifera）为研究对象,非喀斯特适生植物桑树（Morus alba）为对照,比较了不同的植物光合作用对露石生境的响应。与无露石生境相比,多露石生境土壤具有较高的水分含量和较多的有机质。分析植物光合作用的光响应曲线和二氧化碳响应曲线、叶绿素荧光参数以及叶片水势（LWP）和碳稳定同位素值（δ13C）的结果表明:不同生境下,两种植物的LWP及δ13C无显著变化;除了初始荧光参数外,同种植物的叶绿素荧光参数差异不显著;不同生境下,构树的呼吸速率和羧化效率无显著变化,而多露石生境土壤生长的桑树的呼吸速率和羧化效率明显要大于无露石生境土壤生长的;在水分亏缺下,构树以牺牲体内碳的方式来维持稳定的羧化效率,进而保持稳定的光合能力;构树比桑树对喀斯特环境有着较强的适应性。      

基于地理探测器的喀斯特不同地貌形态类型区土壤侵蚀定量归因（英文）

The formation mechanism and influencing factors identification of soil erosion are the core and frontier issues of current research. However, studies on the multi-factor synthesis are still relatively lacked. In this study, the simulation of soil erosion and its quantitative attribution analysis have been conducted in different geomorphological types in a typical karst basin based on the RUSLE model and the geodetector method. The influencing factors, such as land use type, slope, rainfall, elevation, lithology and vegetation cover, have been taken into consideration. Results show that the strength of association between the six influencing factors and soil erosion was notably different in diverse geomorphological types. Land use type and slope were the dominant factors of soil erosion in the Sancha River Basin, especially for land use type whose power of determinant(q value) for soil erosion was much higher than other factors. The q value of slope declined with the increase of relief in mountainous areas, namely it was ranked as follows: middle elevation hill> small relief mountain> middle relief mountain. Multi-factors interactions were proven to significantly strengthen soil erosion, particularly for the combination of land use type with slope, which can explain 70% of soil erosion distribution. It can be found that soil erosion in the same land use type with different slopes(such as dry land with slopes of 5° and above 25°) or in the diverse land use types with the same slope(such as dry land and forest with a slope of 5°), varied much. These indicate that prohibiting steep slope cultivation and Grain for Green Project are reasonable measures to control soil erosion in karst areas. Based on statistics of soil erosion difference between diverse stratifications of each influencing factor, results of risk detector suggest that the amount of stratification combinations with significant difference accounted for 55% at least in small relief mountain and middle relief mountainous areas. Therefore, the spatial heterogeneity of soil erosion and its influencing factors in different geomorphological types should be investigated to control karst soil loss more effectively.     

Exploring the database of a soil environmental survey using a geo-self-organizing map: A pilot study

A model integrating geo-information and self-organizing map (SOM) for exploring the database of soil environmental surveys was established. The dataset of 5 heavy metals (As, Cd, Cr, Hg, and Pb) was built by the regular grid sampling in Hechi, Guangxi Zhuang Autonomous Region in southern China. Auxiliary datasets were collected throughout the study area to help interpret the potential causes of pollution. The main findings are as follows: (1) Soil samples of 5 elements exhibited strong variation and high skewness. High pollution risk existed in the case study area, especially Hg and Cd. (2) As and Pb had a similar topo-logical distribution pattern, meaning they behaved similarly in the soil environment. Cr had behaviours in soil different from those of the other 4 elements. (3) From the U-matrix of SOM networks, 3 levels of SEQ were identified, and 11 high risk areas of soil heavy metal-contaminated were found throughout the study area, which were basically near rivers, factories, and ore zones. (4) The variations of contamination index (CI) followed the trend of construction land (1.353) > forestland (1.267) > cropland (1.175) > grassland (1.056), which suggest that decision makers should focus more on the problem of soil pollution surrounding industrial and mining enterprises and farmland.

     

南海东北部陆架边缘第四纪高分辨率层序地层和沉积体系演化及其控制因素

The northeastern shelf margin of the South China Sea(SCS) is characterized by the development of large scale foresets complexes since Quaternary. Based on integral analysis of the seismic, well logging and paleontological data, successions since ～3.0 Ma can be defined as one composite sequence, consist of a set of regional transgressive to regressive sequences. They can be further divided into six 3 rd order sequences(SQ0–SQ5) based on the Exxon sequence stratigraphic model. Since ～1.6 Ma, five sets of deltaic systems characterized by development of wedge-shaped foresets complexes or clinoforms had been identified. High-resolution seismic data and the thick foresets allowed further divided of sub-depositional sequences(4 th order) of regression to transgression, which is basically consistent with published stacked benthic foram O-isotope records. Depositional systems identified in the study area include deltaic deposits(inner-shelf deltas and shelf-edge deltas), incised valleys, and slope slumping massive deposits. Since ～1.6 Ma, clinoforms prograded from the southern Panyu Lower Uplift toward the northern Baiyun Depression, shelf slope break migrated seaward, whereas the shelf edge of SQ0 migrated landward. The development of incised valleys in the continental shelf increased upward,especially intensive on the SB3 and SB2. The slumping massive deposits increased abruptly since SB2, which corresponds to the development of incised valleys. The evolution of depositional systems of continental slope mainly controlled by the combined influence of sea level changes, tectonic movements, sediment supply and climate changes. Since ～3.0 Ma, relative sea level of the northern SCS had been experienced transgression(～3.0 Ma BP) to regression(～1.6 Ma BP). The regional regression and maximum transgressions of the composite sequences were apparently enhanced by uplift or subsidence related to tectono-thermal events. In addition,climatic variations including monsoon intensification and the mid-Pleistocene transition may have enhanced sediment supply by increasing erosion rate and have an indispensable influence on the development of the incised valleys and 5 sets of deltaic systems since ～1.6 Ma.     

苯并（a）芘诱导下岩虫CYP基因的表达特征

Rapid amplification of cDNA ends(RACE) and real-time polymerase chain reaction(RT-PCR) were carried out to analyze the CYP4 gene expression in polychaete Marphysa sanguinea exposed to benzo[a]pyrene(BaP) in this study. The full length of MsCYP4 cDNA was 2 470 bp, and it encoded 512 amino acids. The deduced amino acid sequence showed 47% identity with CYP4 F from frog Xenopus tropicalis and shared high homology with other known CYP4 sequences. To analyse the role of CYP4 in protecting M. sanguinea from BaP exposure, three BaP groups were established: 0.5, 5 and 50 μg/L. Polychaetes were sampled after 3, 7 and 12 d. At 0.5 μg/L, the effect of BaP on MsCYP4 gene expression increased with time prolonged. MsCYP4 gene expression curve showed Ushaped trend with time in 5 and 50 μg/L BaP groups. Therefore, MsCYP4 gene may play an important role in maintaining the balance of cellular metabolism and protecting M. sanguinea from BaP toxicity.     

大气折光系数测定及在悬索桥基准索股线形测量中的应用

大跨度悬索桥基准索股跨中位置处于百米高空,如何测得精确的垂度值,对主缆线形进行控制至关重要。本文分析了影响悬索桥基准索股垂度测量精度的主要因素,提出了基于实时大气折光系数改正的单向三角高程的跨中垂度测量新方法。在桥址区建立高精度的高差基准,通过对桥址区的大气折光系数的测定及改正试验,证明该测量方法切实可行。基准索股跨中垂度采用双测站进行测量,当双测站所测同一点绝对垂度互差小于10 mm时,取双测站所测垂度均值作为该点的垂度值。该方法的测量结果达到设计精度要求,对同类工程测量项目有借鉴意义。