云浮硫铁矿矿山地质环境问题及对策分析

云浮硫铁矿已开采多年,但开采中带来了一系列环境问题。本文通过对矿区进行的地质环境综合评价,查明了主要矿山地质环境存在的问题,并分析了其原因;利用敏感因子—综合分值评价法,对云浮硫铁矿矿山地质环境质量进行分区,提出了矿山地质环境恢复治理建议,最大程度的降低矿山开采对地质环境的不利影响,努力构建"和谐矿区,和谐社会",促进生态环境、经济和社会的协调可持续发展。     

陕北煤矿区地质环境保护与恢复治理措施——以神府矿区郭家湾煤矿为例

郭家湾煤矿地处神府矿区新民采区西北部,为生态环境脆弱区。井田七层煤三个煤组开采后引发地面塌陷、含水层疏干、土地结构变化等地质环境问题,严重制约了地方经济的发展。为了煤炭资源可持续发展,研究陕北煤矿区地质环境保护与恢复治理措施,以1∶10000野外详细调查为依据,首先进行现状评估,然后针对矿山工程建设可能遭受、加剧、引发的矿山地质环境问题进行预测评估,最后提出了以移民搬迁、回填裂缝、生态恢复、建立矿山地质环境监测体系等为主的防治措施,让煤矿开采与矿山地质环境问题恢复治理并行。旨为陕北地区乃至全国煤矿,在保护地质环境中开发利用矿产资源提供依据和示范。     

降雨入渗补给地下水数值模拟研究

针对在地下水资源评价中入渗补给量采用经验估算存在较大误差的问题,以神东矿区为例,在广泛调查矿区包气带岩性结构并结合野外取样、室内参数测定的基础上,采用数值模拟的方法建立包气带水分运移数值模拟模型,定量模拟矿区内不同地段降雨入渗强度,探讨影响降雨入渗强度的主要因素,计算得出研究区降雨入渗系数大致在0.18~0.27,分析认为影响降雨入渗强度的因素有降雨量、潜水埋深、包气带岩性等。其中在研究区广泛分布的风积沙对地下水资源起到了一定的保护作用。     

济阳坳陷桩海地区中生界同位素年代地层学研究

济阳坳陷中生界分布广泛,具有油气成藏的基本地质条件,并取得了一定的勘探发现,但其勘探程度和研究程度相对较低,包括地层划分、沉积体系、储层特征、控藏因素等。特别是地层时代、分层与分界等基本的地质问题尚存在不同的观点和认识。根据区内14口井的10个火山岩全岩样品和79个小于2μm的泥岩自生伊利石样品,开展K-Ar法同位素年代地层学测定,分别确定了中生界的坊子组、蒙阴组、三台组和西洼组的绝对年龄值,将坊子组划归下侏罗统,蒙阴组为中侏罗统,缺失上侏罗统,并明确了各组的接触关系。     

Predicting lake water quality responses to load reduction: a three-dimensional modeling approach for total maximum daily load

Water quality restoration efforts often suffer the risk of ineffectiveness and failure due to lack of quantitative decision supports. During the past two decades, the restoration of one of China’s most heavily polluted lakes, Lake Dianchi, has experienced costly decision ineffectiveness with no detectable water quality improvement. The governments are planning to invest tremendous amount of funds in the next 5 years to continue the lake restoration process; however, without a quantitative understanding between the load reduction and the response in lake water quality, it is highly possible that these planned efforts would suffer the similar ineffectiveness as before. To provide scientifically sound decision support for guiding future load reduction efforts in Lake Dianchi Watershed, a sophisticated quantitative cause-and-effect response system was developed using a three-dimensional modeling approach. It incorporates the complex three dimensional hydrodynamics, fate and transport of nutrients, as well as nutrient-algae interactions into one holistic framework. The model results show that the model performs well in reproducing the observed spatial pattern and temporal trends in water quality. The model was then applied to three total maximum daily load scenarios and two refined restoration scheme scenarios to quantify phytoplankton responses to various external load reduction intensities. The results show that the algal bloom in Lake Dianchi responds to load reduction in a complex and nonlinear way, therefore, it is necessary to apply the developed system for future load reduction and lake restoration schemes for more informed decision making and effective management.     

Spatial heterogeneity of cyanobacteria-inoculated sand dunes significantly influences artificial biological soil crusts in the Hopq Desert (China)

Artificial biological soil crusts (ABSCs), formed by inoculating Microcoleus vaginatus Gom. and Scytonema javanicum Born. et Flah. onto the topsoil of desert dunes, proved to be effective tools for the stabilization of moving dunes and promotion of soil fertility. As dominant driving forces in arid habitats, the abiotic environmental conditions of undulating dunes produce a gradient of abiotic stresses on cyanobacteria. Cyanobacteria are considered pioneering phototrophs in early soil crust communities in deserts. In this study, the development of ABSCs under various environmental site conditions was investigated using 16S rRNA-based polymerase chain reaction, denaturing gradient gel electrophoresis (DGGE), and soil property measurements. After inoculation in 2002 and long-term development, patchy moss crusts were observed on the dunes. All of the available sequenced bands in the DGGE gels belonged to Oscillatoriales and Nostocales. The dominant Nostocales genus in the ABSCs was still Scytonema; however, more Oscillatoriales genera were identified, which belonged to Microcoleus and Phormidium. The cyanobacterial compositions of different slope types were significantly distinct (p < 0.05), particularly those from windward slopes. The crusts of the top-dune slopes were more heterogeneous. In addition, the soil physicochemical properties and richness indices of the windward slopes were significantly lower than those of the leeward and interdune slopes (p < 0.05). Compared with uninoculated control dunes, all of the inoculated dunes had far higher biodiversities.     

A method for mineral prospectivity mapping integrating C4.5 decision tree,weights-of-evidence and m-branch smoothing techniques: a case study in the eastern Kunlun Mountains,China

In this study, a novel method that integrates C4.5 decision tree, weights-of-evidence and m-branch smoothing techniques was proposed for mineral prospectivity mapping. First, a weights-of-evidence model was used to rank the importance of each evidential map and determine the optimal buffer distance. Second, a classification technique that uses a C4.5 decision tree in data mining was used to construct a decision tree classifier for the grid dataset. Finally, an m-branch smoothing technique was used as a predictor, which transformed the decision tree into a probability evaluation tree. The method makes no conditional independence assumption and can be applied for class imbalanced datasets like those collected during mineral exploration for prospectivity mapping of an area. The traits of comprehensibility, accuracy and efficiency were derived from the C4.5 decision tree. In addition, a case study for iron prospectivity mapping was performed in the eastern Kunlun Mountains, China. Sixty-two Skarn iron deposits and eight evidential maps related to iron mineralization were studied. On the final map, areas of low, moderate and high potential for iron deposit occurrence covered areas of 71,491, 14,298, and 9,532 km², respectively. For the goodness-of-fit test, 91.94 % of the total 62 iron deposits were within a high-potential area, 8.06 % were within a moderate-potential area and 0 % were within a low-potential area. For ten-fold cross-validation, 82.26 % were within a high-potential area, 14.52 % were within a moderate-potential area and 3.22 % were within a low-potential area. To evaluate the predictive accuracy, Receiver Operating Characteristic (ROC) curves and Area Under ROC Curve (AUC) were employed. The accuracy of the goodness-of-fit test reached 97.07 %, and the accuracy of the ten-fold cross-validation was 95.10 %. The majority of the iron deposits were within high-potential and moderate-potential areas, which covered a small proportion of the study area.     

Defining physico-chemical variables, chlorophyll-a and Secchi depth reference conditions in northeast eco-region lakes, China

Establishing reference conditions for regional lakes is necessary to assess human impact on aquatic ecosystems, protect water quality and biotic integrity. The northeast eco-region lakes often present a marked seasonal variability in hydrological, biological and geochemical processes, which could affect physico-chemical variables, chlorophyll-a and Secchi depth reference conditions. Reference conditions were calculated using two different methods: lake population distribution method and trisection method. General physico-chemical reference conditions (pH, conductivity, BOD and nutrients) and chlorophyll-a, and Secchi depth reference conditions were established using the two approaches combined with the analysis of seasonal variability for each parameter for shallow and deep lake types in the northeast eco-region lakes. The results indicated that depth was an important factor affecting physico-chemical variables, chlorophyll-a and Secchi depth reference values. Moreover, the seasonal differences in parameters were also assessed using a non-parametric repeated measure ANOVA (Friedman test) in the shallow and deep lakes. Some parameters showed a seasonal variability for shallow and deep lakes. The least restrictive reference values of the four seasons were proposed to simplify the water quality assessment for regional lake management goals. These results indicated that the 50th percentile (median) value from the best one-third of the nutrient-concentration data distributions is more appropriate for the northeast eco-region lakes.     

Controlling factors of the δ 11B-pH proxy and its research direction

Significant boron isotope fractionation occurs in nature (?70 ‰ to +75 ‰) due to the high geochemical reactivity of boron and the large relative mass difference between ¹⁰B and ¹¹B. Since the 1990s, reconstruction of ancient seawater pH using the isotopic composition of boron in bio-carbonates (δ ¹¹B_carb), and then calculation of the past pCO₂ have become important issues for the international isotope geochemistry community, and are called the δ ¹¹B-pH proxy. Although many achievements have been made by this proxy, various aspects of boron systematics require rigorous evaluation. Based on the previous researches, mechanism of boron isotope fractionation, variation of boron isotope (δ ¹¹B) in nature (especially in bio-carbonates) and controlling factors of the δ ¹¹B-pH proxy, such as the dissociation constant of B(OH)₃ in seawater (pK_a), the δ ¹¹B of seawater (δ ¹¹B_SW), the boron isotopic fractionation factor between B(OH) ₄ ^? and B(OH)₃ (α _4–3), and the incorporated species of boron into bio-carbonates, are reviewed in detail and the research directions of this proxy are proposed. Generally, the controversy about pK_a, δ ¹¹B_sw, and α _4–3 is relatively less, but whether boron incorporated into bio-carbonates only in the form of B(OH) ₄ ^? remains doubtful. In the future, it is required that the physicochemical processes that control boron incorporation into carbonates be rigorously characterized and that the related chemical and isotopic fractionation be quantified. It is also necessary and important to establish a “best-fit empirically equation” between δ ¹¹B_carb and pH of seawater based on the precipitation experiments of inorganic or culture experiments of corals or foraminifera. In addition, extended application of the δ ¹¹B-pH proxy to the earlier part of the Phanerozoic relying on the Brachiopods is worthy of studying. Like other geochemical indicators, there are limiting factors of δ ¹¹B; however, it remains a very powerful tool in the reconstruction of past seawater pH at present.     

Antimony adsorption on kaolinite in the presence of competitive anions

Antimony (Sb) emissions to the environment are increasing, and there is a dearth of knowledge regarding Sb fate and behavior in natural systems. In natural systems, the presence of competitive anions may compete with Sb for adsorption sites on mineral surfaces, hence increasing its potential bioavailability. Accordingly, the adsorption of Sb(III) on kaolinite was investigated in the presence of competitive anions. Kinetic studies suggest that adsorption reaction of Sb(III) on kaolinite is rapid initially and becoming slow after 12 h both in binary Sb(III)–kaolinite system and in ternary Sb(III)-competitive anion–kaolinite system. The presence of PO₄ ^3? has a much stronger and more obvious promotive effect on the adsorption of Sb(III) on kaolinite compared with the other two anions. The adsorption data of Sb(III) on kaolinite in the absence and presence of competitive anions at three temperatures were successfully modeled using Langmuir (r ² > 0.95) and Freundlich (r ² > 0.95) isotherms. Accompanied the adsorption of Sb(III) on kaolinite, significant oxidation of Sb(III) to Sb(V) had occurred under the experimental conditions used in this study. The presence of kaolinite which has a larger specific surface area could increase the contact area between the adsorbed Sb(III) and oxygen in the bulk solution, which promoted the oxidation rate of Sb(III) to Sb(V).