Frequency analysis of nonstationary annual maximum flood series using the time‐varying two‐component mixture distributions

The most popular practice for analysing nonstationarity of flood series is to use a fixed single‐type probability distribution incorporated with the time‐varying moments. However, the type of probability distribution could be both complex because of distinct flood populations and time‐varying under changing environments. To allow the investigation of this complex nature, the time‐varying two‐component mixture distributions (TTMD) method is proposed in this study by considering the time variations of not only the moments of its component distributions but also the weighting coefficients. Having identified the existence of mixed flood populations based on circular statistics, the proposed TTMD was applied to model the annual maximum flood series of two stations in the Weihe River basin, with the model parameters calibrated by the meta‐heuristic maximum likelihood method. The performance of TTMD was evaluated by different diagnostic plots and indexes and compared with stationary single‐type distributions, stationary mixture distributions and time‐varying single‐type distributions. The results highlighted the advantages of TTMD with physically‐based covariates for both stations. Besides, the optimal TTMD models were considered to be capable of settling the issue of nonstationarity and capturing the mixed flood populations satisfactorily. Copyright © 2016 John Wiley & Sons, Ltd.     

Carboniferous eclogite and garnet–omphacite granulite from northeastern Hainan Island,South China: Implications for the evolution of the eastern Palaeo‐Tethys

High‐P (HP) eclogite and associated garnet–omphacite granulite have recently been discovered in the Mulantou area, northeastern Hainan Island, South China. These rocks consist mainly of garnet, omphacite, hornblende, quartz and rutile/ilmenite, with or without zoisite and plagioclase. Textural relationships, mineral compositions and thermobarometric calculations demonstrate that the eclogite and garnet–omphacite granulite share the same three‐stage metamorphic evolution, with prograde, peak and retrograde P?T conditions of 620–680°C and 8.7–11.1 kbar, 820–860°C and 17.0–18.2 kbar, and 700–730°C and 7.1–8.5 kbar respectively. Sensitive high‐resolution ion microprobe U–Pb zircon dating, coupled with the identification of mineral inclusions in zircon, reveals the formation of mafic protoliths before 355 Ma, prograde metamorphism at c. 340–330 Ma, peak to retrograde metamorphism at c. 310–300 Ma, and subsequent pegmatite intrusion at 295 Ma. Trace element geochemistry shows that most of the rocks have a MORB affinity, with initial ε_Nd values of +2.4 to +6.7. As with similar transitional eclogite–HP granulite facies rocks in the thickened root in the European Variscan orogen, the occurrence of relatively high P?T metamorphic rocks of oceanic origin in northeastern Hainan Island suggests Carboniferous oceanic subduction leading to collision of the Hainan continental block, or at least part of it, with the South China Block in the eastern Palaeo‐Tethyan tectonic domain.     

Precipitation variability assessment of northeast China: Songhua River basin

Variability in precipitation is critical for the management of water resources. In this study, the research entropy base concept was applied to investigate spatial and temporal variability of the precipitation during 1964–2013 in the Songhua River basin of Heilongjiang Province in China. Sample entropy was applied on precipitation data on a monthly, seasonally, annually, decade scale and the number of rainy days for each selected station. Intensity entropy and apportionment entropy were used to calculate the variability over individual year and decade, respectively. Subsequently, Spearman’s Rho and Mann–Kendall tests were applied to observe for trends in the precipitation time series. The statistics of sample disorder index showed that the precipitation during February (mean 1.09, max. 1.26 and min. 0.80), April (mean 1.12, max. 1.29 and min. 0.99) and July (mean 1.10, max. 1.20 and min. 0.98) contributed significantly higher than those of other months. Overall, the contribution of the winter season was considerably high with a standard deviation of 0.10. The precipitation variability on decade basis was observed to increase from decade 1964–1973 and 1994–2003 with a mean value of decadal apportionment disorder index 0.023 and 0.053, respectively. In addition, the Mann–Kendall test value (1.90) showed a significant positive trend only at the Shangzhi station.     

固体聚合膜电解浓集法测量天然水中低含量氚的化学淬灭效应研究

固体聚合膜电解浓集法是浓缩氚含量较低(1 Bq/m~3)的天然水样的常用方法,但因水样自身含有杂质离子或电解装置聚合膜带入杂质进入浓集液,使浓集液偏酸性,在测量过程中易产生化学淬灭效应,导致氚的测量值偏低。本文研究了水样自身存在的杂质离子和聚合膜上残留的杂质离子、样品溶液的pH值及其电导率所产生的化学淬灭效应的影响,实验表明,为减少化学淬灭效应,提高测量低含量氚的准确性,需保证水样溶液呈中性,电导率≤1μS/cm,同时避免杂质沉积在聚合膜上。如果水样溶液的pH值偏酸性、电导率大于1μS/cm,可采用酸碱混合型离子交换树脂去除水样中自身的杂质;对于聚合膜引入的杂质,可在电解后的水样中加入微量氨水将其pH值调节至中性。     

Characteristics of the two active stages of lightning activity in two hailstorms

Two hailstorms that occurred in Beijing and Tianjin, respectively, are investigated, based mainly on the total lightning data observed by the System d’Alerte Fondre par Interferometric Radioelecctrique (SAFIR3000), the cloud-to-ground (CG) lightning data of a CG lightning location system, and the echo data of a Doppler radar. Both hailstorms exhibited two lightning frequency peaks: the first was before the hailfall and the second was after the hailfall, with the second peak greater than the first. The dominant polarity of the CG lightning was positive in the stage around the first frequency peak, but changed to negative in the stage around the second frequency peak. The evolution of radar echoes and the height distribution of lightning radiation sources are explored, revealing that both hailstorms had stronger convection and the main positive charge occurred at mid levels during the stage around the first frequency peak. However, whilst the Beijing hailstorm experienced the enhancement of convection, with the main positive charge at upper levels around the second frequency peak, the Tianjin hailstorm generated its second frequency peak during the period when the convection kept weakening and the main positive charge dropped to mid–lower levels. Through evaluation of the radar parameters, we investigate the mechanisms responsible for the second stage of active lightning discharge. Furthermore, the lightning activity exhibited a close relationship with radar echo parameters and hailfall. Lightning jump signals were found before the hailfall and were associated with the change ratio of the 40-dBZ echo volume above the ?15°C level, which demonstrates the application value of lightning data in severe weather warning.     

北京和广州地区云闪初始击穿电场变化特征

对比分析了北京和广州地区各100例云闪初始阶段前30 ms快电场变化波形上初始击穿脉冲的特征。依据脉冲的结构特征,两地区的云闪初始击穿脉冲可分为单极性单峰型、单极性多峰型、双极性单峰型和双极性多峰型脉冲,两地区均以单极性和单峰型脉冲为主。对脉冲参量特征的统计发现,脉冲的10%-90%上升时间、半峰值宽度地区差异性小于脉冲类型差异性;双极性单峰型脉冲的半峰值宽是单极性单峰型的1.2倍。不同类型脉冲过零时间的中值、平均值在10μs左右量级,且广州地区较北京地区的大;云闪初始击穿脉冲宽度平均值显著小于相同地区正地闪的,而脉冲间隔显著大于正地闪的。初始击穿脉冲最为集中的出现在云闪最初的1~2 ms,其比例随时间以显著的负指数分布下降。研究发现,双极性脉冲的过零时间与脉冲宽度之间、起始半周期峰值幅度与过冲幅度之间均存在较好的线性关系。     

贵州西北部基性侵入岩锆石U-Pb年代学、岩石地球化学特征 及其与铅锌成矿关系初探

贵州西北部发育多处基性侵入岩,总体规模较小(约0.25 Km2),多沿深大断裂侵位,出露于铅锌矿点外围,本文对猫猫厂、凉山两处矿点附近的儿马冲和白岩庆两地小型基性侵入岩进行了重点研究。侵入岩主要岩性为细粒辉长岩,造岩矿物主要为拉长石、普通辉石。SiO2范围为49.60-51.09 wt%,MgO从3.88-4.27 wt %,TiO2为3.69-3.85 wt %。LA-ICP-MS锆石U-Pb定年结果为268.3±7.4 Ma,显示岩浆侵位于二叠纪。基性侵入岩的微量元素蛛网图呈OIB型特征,富集大离子亲石元素（LILE）、轻稀土元素（LREE）,亏损重稀土元素（HFEE）,相对亏损高场强元素（Nb,Ta）,有Sr、Y亏损,Pb富集。(87Sr/86Sr)i范围0.706749～0.707069,(143Nd/144Nd)i范围0.512313～0.512363,εNd(t)范围0.2～1.2;源区熔融深度处于石榴石橄榄岩相深度,可能经历了1-3 %的部分熔融,处于亏损石榴石二辉橄榄岩相向原始石榴石二辉橄榄岩相的过渡区。成岩过程中发生了单斜辉石、斜长石等矿物分离结晶,受到了有限的地壳混染作用,未经历明显的AFC过程。地壳物质在地幔源区中的加入可能是造成地幔富集的主要原因。侵入岩与成矿作用之间的关系,主要通过两方面所表现。一方面是二者间构造活动上的耦合性。另一方面是基性岩在成矿过程中可能发挥了重要的化学屏障层作用。     

鄂尔多斯盆地纳岭沟铀矿床绿泥石特征及地质意义

纳岭沟铀矿床位于鄂尔多斯盆地北部,具有明显的后期热液作用的特征,矿体空间展布主要受控于绿色-灰色砂岩的过渡界面,与绿泥石化的蚀变砂岩关系密切。通过对纳岭沟铀矿床不同颜色砂岩中的绿泥石进行详细的岩相学研究和电子探针化学成分分析,依据绿泥石的成因与共生矿物的关系,识别出绿泥石主要的3种类型:填隙物型绿泥石,片状与黄铁矿共生型绿泥石以及黑云母蚀变型绿泥石;同时通过绿泥石的Fe-Si图解确定了纳岭沟铀矿床不同颜色砂岩中的绿泥石主要为铁镁绿泥石和密绿泥石。根据Al/(Fe+Mg+Al)-Mg/(Fe+Mg)的关系图解确定出不同颜色砂岩中的绿泥石具有铁镁质流体和泥质两种来源,通过绿泥石中主要阳离子与镁的关系图解和计算得出的绿泥石形成温度共同确定出绿泥石是多期次的中低温热液流体作用的产物。综合研究表明,纳岭沟铀矿床的绿泥石形成至少经历了温度稍高的还原性流体和温度稍低的氧化性流体等两个期次的流体作用,稍高温的还原性流体与成矿关系更为重要。与绿泥石形成有关的热液流体作用不仅带入了部分铀,还促进了铀的活化和运移。     

Research on comprehensive carrying capacity of Beijing–Tianjin–Hebei region based on state-space method

Based on state-space method and component analysis, this paper builds a comprehensive evaluation system of carrying capacity for the Beijing–Tianjin–Hebei region from four aspects, namely economy, environment, ecology and energy. The results show that the comprehensive carrying capacity in this region gradually rises in recent years and the economic carrying capacity plays an important role in this situation. Ecological and environmental carrying capacity are gradually enhanced but still affected by water shortages. The energy carrying capacity of this region is low, which is the major factor restricting its sustainable development. Based on the empirical results, following policy suggestions should be adopted: Firstly, local government should accelerate technological progress, promoting the optimization and upgrading of industrial structure; Secondly, the contradiction between supply and demand of water resource should be solved gradually; thirdly, government should develop recycling economy, realizing the coordinated development of economy and environment; last but not least, saving energy and improving energy efficiency.