Oxygen isotope salt effects at high pressure and high temperature and the calibration of oxygen isotope geothermometers

The influence of NaCl, CaCl₂, and dissolved minerals on the oxygen isotope fractionation in mineral-water systems at high pressure and high temperature was studied experimentally. The salt effects of NaCl (up to 37 molal) and 5-molal CaCl₂ on the oxygen isotope fractionation between quartz and water and between calcite and water were measured at 5 and 15 kbar at temperatures from 300 to 750°C. CaCl₂ has a larger influence than NaCl on the isotopic fractionation between quartz and water. Although NaCl systematically changes the isotopic fractionation between quartz and water, it has no influence on the isotopic fractionation between calcite and water. This difference in the apparent oxygen isotope salt effects of NaCl must relate to the use of different minerals as reference phases. The term oxygen isotope salt effect is expanded here to encompass the effects of dissolved minerals on the fractionations between minerals and aqueous fluids. The oxygen isotope salt effects of dissolved quartz, calcite, and phlogopite at 15 kbar and 750°C were measured in the three-phase systems quartz-calcite-water and phlogopite-calcite-water. Under these conditions, the oxygen isotope salt effects of the three dissolved minerals range from ∼0.7 to 2.1‰. In both three-phase hydrothermal systems, the equilibrium fractionation factors between the pairs of minerals are the same as those obtained by anhydrous direct exchange between each pair of minerals, proving that the use of carbonate as exchange medium provides correct isotopic fractionations for a mineral pair.When the oxygen isotope salt effects of two minerals are different, the use of water as an indirect exchange medium will give erroneous fractionations between the two minerals. The isotope salt effect of a dissolved mineral is also the main reason for the observation that the experimentally calibrated oxygen isotope fractionations between a mineral and water are systematically 1.5 to 2‰ more positive than the results of theoretical calculations. Dissolved minerals greatly affect the isotopic fractionation in mineral-water systems at high pressure and high temperature. If the presence of a solute changes the solubility of a mineral, the real oxygen isotope salt effect of the solute at high pressure and high temperature cannot be correctly derived by using the mineral as reference phase.     

淄博市区大气颗粒物重金属元素分布特征及其来源分析

为科学认识淄博市区大气颗粒物污染状况,探讨颗粒物的污染水平和元素在颗粒物中的分布与分配特征,对颗粒物中元素的来源进行分析。于2015年冬季和夏季期间分别布设45个和16个采样点采集悬浮颗粒物（TSP）、PM₁₀及PM_2.5样品,分析了颗粒物和18种元素（或化合物）的质量浓度。结果表明：1）大气颗粒物中冬季TSP、PM₁₀及PM_2.5的质量浓度均值高于夏季;PM₁₀和PM_2.5质量浓度均超过国家标准,其中冬季PM_2.5质量浓度是标准限值的1.96倍。2）不同粒径的颗粒物中元素质量分数差别显著,As、Cd、Cr、Cu、Ni、Pb、Zn等多数重金属元素主要富集在PM_2.5中,且PM_2.5约占PM₁₀的65%（冬季）和73%（夏季）。3）颗粒物PM_2.5中Al₂O₃、CaO、Fe₂O₃、K₂O、MgO等氧化物主要受土壤扬尘控制;As、Cd、Hg、Pb、Se、Zn等元素主要源于人为污染;Se的富集因子最高,反映了PM_2.5污染主要来源于燃煤;Co、Cu、Ni、Na₂O受土壤扬尘和人类活动的共同作用,而Cr具有混合污染的特点。     

Risk assessment of land subsidence at Tianjin coastal area in China

Risk assessment and zoning are very important to risk management. In this study, a land subsidence risk assessment index was proposed based on the Disaster Risk Index. The cumulative subsidence volume, the land subsidence velocity, and the groundwater exploitation intensity were collected, analyzed, and put together to create a land subsidence hazard evaluation map in Tianjin coastal area. The population density, Gross Domestic Product per square kilometer, and construction land proportion were adopted as indexes to create the vulnerability map. In addition, the capability of land subsidence prevention and reduction was also assessed. Finally, the land subsidence risk map was created by combing the hazard, vulnerability, and the capability of land subsidence prevention and reduction map. Specifically, the land subsidence risk was classified into five levels, i.e., very high, high, medium, low, and very low. The result of this research could provide a solid basis for the sustainable development as well as disaster prevention policy-making of Tianjin city.     

超临界流体热力学函数的理论计算

Ｄｕａｎ等（１９９２。１９９６）基于分子间相互作用势能模型,建立了一个适合于超临界流体的状态方程,此方程能反演出世界上几十个实验室测定的成千上万个纯组分及混合物的ＰＶＴ（压力、体积、温度）数据（温压范围：Ｐ〈２ＧＰａ,Ｔｃ〈Ｔ〈２０００Ｋ）。最近的研究发现,此方程能准确预测Ｈ２Ｏ、ＣＯ２、ＣＨ４、Ｎ２及它们的混合物在Ｔ＝１．３Ｔｃ,Ｐ＝０到Ｔ＝２０００Ｋ,Ｐ＝１０ＧＰａ这一温压范围内的压力、体积、     

内蒙古贺斯格乌拉牧场白音高老组火山岩U-Pb年龄及地球化学特征

白音高老组火山岩在大兴安岭地区广泛分布,本文对大兴安岭中南部贺斯格乌拉牧场白音高老组酸性火山岩进行了锆石U-Pb年代学、岩石地球化学和Sr-Nd同位素分析,探讨其岩石成因及构造背景。位于大兴安岭中南段东乌旗地区的白音高老组火山岩,主要岩性为流纹岩、流纹质凝灰岩等,LA-ICP-MS锆石U-Pb年龄分别为129. 8±0. 8 Ma、128. 2±2. 8 Ma,属早白垩世早期;从岩石地球化学特征上看,其主量元素SiO_2含量68. 76%～76. 18%、Al_2O_3含量11. 84%～13. 38%,属高钾钙碱性岩石;稀土总量较高,(La/Yb)N 6,(La/Sm)_N 3,显示为轻稀土富集型,δEu显示负铕异常(0. 4～0. 6),微量元素以富集大离子亲石元素K、Rb、Ba,贫高场强元素Nb、P、Ti为特征; Sr-Nd同位素组成上具有低I_(Sr)、高ε_(Nd)(t)和低t_(DM)的特征(I_(Sr)=0. 7039～0. 7045,ε_(Nd)(t)=2. 65～4. 39)。火山岩浆来源于下地壳基性物质的部分熔融,综合研究并结合前人资料认为,白音高老组流纹岩形成于滨太平洋板块俯冲后伸展及蒙古-鄂霍次克洋闭合后的综合效应下。     

The Application of Elastic Wave Measurement to the Deep Holes in the Bedrock of a Nuclear Power Station

In this paper we present the principle and technique for measuring velocity of elastic waves in the bedrock with deep holes, and the effective watertight and pressure-proof measures taken. Using this method, the measurement in the bedrock of the reactor of a nuclear power station with holes (120m in depth) are completed with the anticipated results. The data, processed and analysed, have been provided for the construction of the above-mentioned nuclear power station.     

华南沿海老红砂的成因与红化作用

根据野外调查和室内实验分析，以及测年数据，本文讨论了华南沿海老红砂的成因、年龄与形成环境。认为老红砂是晚更新世末次冰期海岸风沙堆积，红色特征与亚间冰期的温暖古气候有关。在湿热气候下，古风成砂中含铁硅酸盐矿物氧化生成赤铁矿，而使无色石英沙粒染成红色，是其红化的主要机制。风成砂形成红色的时间不超过１万年。     

Formation of saddle dolomites in Upper Cambrian carbonates, western Tarim Basin (northwest China): Implications for fault-related fluid flow

The saddle dolomites occur more intensely in cores closely to fault than that in cores far away from the fault in Upper Cambrian carbonate of western Tarim basin, suggesting that formation of the saddle dolomites is likely related to fault-controlled fluid flow. They partially fill in fractures and vugs of replacement dolomite. The saddle dolomites exhibit complex internal textures, commonly consisting of core and cortex. In comparison with the matrix dolomites, the saddle dolomites show lower Sr-content and ⁸⁷Sr/⁸⁶Sr ratios, higher Fe- and Mn-content, and more negative δ¹⁸O values. Combined with high Th (100–130 °C) of primary fluid inclusions, it is suggested that the saddle dolomites precipitated from hydrothermal fluid derived from the deep evaporite-bearing Middle Cambrian strata, and the magnesium source may be due to dissolution of host dolomite during hydrothermal fluid migration. Fault activity resulted in petrographic and geochemical difference of the core and cortex of the saddle dolomites. The cores precipitated from the formation water mixed by deep brines at the early stage of fault activity, and the cortexes precipitated from the deep fluid with higher temperatures through the Middle Cambrian later. In summary, the formation of the saddle dolomites implies a hydrothermal fluid event related to fault activity, which also resulted in high porosity in Upper Cambrian carbonate in western Tarim Basin.     

一种污水排海的近远区计算与控制方法──以大亚湾水容量计算及污水排海为例

针对点容量计算中混合区限制的要求，采用了动量积分法、经验公式法和有限差分法，分别对污水排放后可能引起的近区、过渡区和远区的污水浓度变化进行了模拟预测，并就一定的限制性条件对容量点近区、高浓度混合区及容量点远区影响范围进行了分析。在大亚湾水容量计算及污水排海规划中的应用表明，该法具有计算机时较省、精度相对较高等优点。     

初至层析静校正在复杂山地三维地震勘探中的应用

随着地形高差增大、地貌单元多变、近地表模型复杂,目前被广泛应用的初至折射静校正的精度已无法满足精细勘探的要求。初至层析静校正技术,由给定的初始模型进行正演,用射线追踪方法得到初始模型的初至波,利用该初至波和实际拾取的初至波进行比较,计算地表模型的修正量,反复迭代求得准确的地表模型。山西省国阳新能股份有限公司二矿390水平九采扩区地表标高940～1100m,地貌单元复杂,在对该区资料处理时,利用初至层析折射静校正,经9次迭代计算后,真实地刻划出近地表模型。在二种静校正技术对比中,初至折射静校正不但近地表模型精度低于层析折射静校正,而且其叠加剖面精细程度也远低于层析静校正,如在初至折射静校正叠加剖面同相轴上呈现的凹凸形态,在层析静校正叠加剖面并无显示,且后者剖面的信噪比也比前者明显提高。