Simulating flow in karst aquifers at laboratory and sub-regional scales using MODFLOW-CFP

Groundwater flow in a well-developed karst aquifer dominantly occurs through bedding planes, fractures, conduits, and caves created by and/or enlarged by dissolution. Conventional groundwater modeling methods assume that groundwater flow is described by Darcian principles where primary porosity (i.e. matrix porosity) and laminar flow are dominant. However, in well-developed karst aquifers, the assumption of Darcian flow can be questionable. While Darcian flow generally occurs in the matrix portion of the karst aquifer, flow through conduits can be non-laminar where the relation between specific discharge and hydraulic gradient is non-linear. MODFLOW-CFP is a relatively new modeling program that accounts for non-laminar and laminar flow in pipes, like karst caves, within an aquifer. In this study, results from MODFLOW-CFP are compared to those from MODFLOW-2000/2005, a numerical code based on Darcy’s law, to evaluate the accuracy that CFP can achieve when modeling flows in karst aquifers at laboratory and sub-regional (Woodville Karst Plain, Florida, USA) scales. In comparison with laboratory experiments, simulation results by MODFLOW-CFP are more accurate than MODFLOW 2005. At the sub-regional scale, MODFLOW-CFP was more accurate than MODFLOW-2000 for simulating field measurements of peak flow at one spring and total discharges at two springs for an observed storm event.     

内蒙古东乌旗地区中下泥盆统泥鳅河组沉积相研究

发育于内蒙古东乌旗地区的泥鳅河组,属于早中泥盆世沉积,厚度约1000m,主要发育泥岩、粉砂岩和灰岩沉积,粉砂岩中常常发育大量腕足类和珊瑚生物化石。首次在本区发现风暴沉积和Beaconites遗迹化石:风暴沉积由下至上包括粒序层理段、平行层理段、丘状交错层理段和浪成波纹层理段4个层段;Beaconites遗迹化石具管壁和内部水平“V”字型的回填纹构造。通过对岩相、生物化石、风暴沉积和Beaconites遗迹化石的研究显示,东乌旗地区泥鳅河组为浅海相沉积。     

退火对B掺杂纳米金刚石薄膜微结构和电化学性能的影响

采用热丝化学气相沉积法制备B掺杂纳米金刚石薄膜,并对薄膜进行真空退火处理,系统研究了不同退火温度对B掺杂纳米金刚石薄膜的微结构和电化学性能的影响.结果表明,当退火温度升高到800 ℃后,薄膜的Raman谱图中由未退火时在1157,1346,1470,1555 cm^-1处的4个峰转变为只有D峰和G峰,说明晶界上的氢大量解吸附量减少;并且D峰和G峰的积分强度比I_D/I_G值变为最小,即sp²相团簇     

成烃贡献值及其在烃源岩评价中的应用

烃源岩评价是油气勘探的关键工作之一。为了更加合理、直观和有效地评价烃源岩,以辽东湾地区为例,通过对烃源岩常规评价参数的分析,提出了考虑有机质丰度、类型和热演化程度的综合指标——成烃贡献值,并利用该指标对辽东湾地区烃源岩进行了评价。从个体评价和整体评价两方面,与常规评价方法的结论进行对比研究。结果表明,辽东湾地区辽中凹陷沙河街组烃源岩对成烃的贡献比东营组大,中洼烃源岩比北洼好。由此可见,用成烃贡献值评价烃源岩,不仅可以达到常规评价的要求,而且比常规方法更加合理和直观。     

深部气层和干层测井模糊综合评判

深部气层和干层的区分是常规测井解释的难题。认识始于实践。本文依据东濮凹陷深层试采资料,建立了两个模式各四个参数的隶属度曲线,进行气层和干层模糊综合评判研究,并用该地区深层试井资料作了检验,效果颇佳。证明模糊综合评判是区分深部气层和干层的一种行之有效的方法。     

The Paleoceanography during the Time with High δ13C of Phanerozoic marine carbonates

Carbon isotopic composition of marine carbonates is a record for various important geological events in the process of earth development and evolution. The carbonates of Carboniferous, Permian and Triassic, as the transition from Paleozoic to Mesozoic-Cenozoic have very high ¹³C value. Taking this as the main point, and combined with the oxygen, strontium isotopic composition in carbonates, distribution of carbonate basin area through geologic time, the correlation of carbon isotopic composition of marine carbonates to sea level change, organic carbon burial flux, exchange of CO₂ content in atmosphere and ocean, and long cycle evolution of the earth ecosystems were approached. The results are shown as follows: ①The interval of ¹³C >3‰ during Phanerozoic was concentrated in Carboniferous, Permian and the beginning of Triassic, but the beginning of Triassic was characterized by higher frequency and larger fluctuations in ¹³C value during a short time, whereas the Carboniferous-Permian presented a continuously stable high ¹³C value, indicating a larger amount of organic carbon accumulation in this time interval. Relatively high ¹⁸O values during this time was also observed, showing a long time of glaciations and cold climate, which suggest a connection among rapid organic carbon burial, cold climate, as well as pCO₂ and pO₂ states of atmosphere. ②The over consumption of atmosphere CO₂ by green plants during the time with high ¹³C of seawater forced CO₂ being transferred from ocean to atmosphere for the balance, but the decrease in the seawater amount and water column pressure caused by the global cooling could weaken dissolution capacity of CO₂ in seawater and carbon storage of marine carbonates, and also reduce the carbonate sedimentary rate and decrease the carbonate basin area globally from Devonian to Carboniferous and Permian. During the middle-late Permian carbonate was widely replaced by siliceous sediments even though in shallow carbonate platform, which resulted in the decrease of marine invertebrates, suggesting the Permian chert event should be global. ③The Phanerozoic ⁸⁷Sr/⁸⁶Sr trend of seawater showed a sharp fall in Permian and drop to a minimum at the end of the Permian, indicting input of strontium from the submarine hydrothermal systems (mantle flux). Such process should accompany with a supplement of CO₂ from deep earth to atmosphere and ocean system, but the process associated with widespread volcanism and rises of earth’s surface temperature pricked up the mass extinction during the time of end Permian. ④Cold climate and increase of continental icecap volume, the amalgamation of northern Africa and Laurentia continentals were the main reasons responsible for the sea level drop, but the water consumption result from the significantly increased accumulation of organic carbon should also be one of the reasons for the sea level drop on the order of tens of meters. ⑤The mass extinction at the end Permian was an inevitable event in the process of earth system adjustment. It was difficult for marine invertebrates to survive because of the continuously rapid burial of organic carbon, and of the decrease of sea water amount and its dissolution ability to CO₂. At last, at the end of Paleozoic, the supplement of CO₂ to atmosphere and ocean by widely magma activities resulted in a high temperature of earth surface and intensified mass extinction.     

贵州烂泥沟金矿床中辉锑矿的构造成因矿物学初析

本文通过对贵州烂泥微细浸染型金矿床中辉锑矿显微形貌和超微结构观察，发现辉矿晶体中出现显微波纹扭裂纹，沿扭裂纹部位被辰砂充填交代和辉锑矿晶体中存在大量变形双晶、层错、位错壁、亚晶粒等变形超微结构，从而为成矿过程中锑、汞矿化之间这段区间发生构造应力作用了微观的成因信息。     

长江口海水的密度

为了核对1980年国际海水状态方程应用于中国近岸海水的可靠性,高精度的磁力浮沉子密度计在15—25℃,盐度5—35,一个大气压条件下,测量了长江口附近海水及其人工稀释海水的相对密度。结果表明,海水密度直接测量值系统地偏高于状态方程计算值,二者之间的偏差随水样盐度值降低而增大,且与海水[Ca~(2+))/s比值成明显正相关关系。经计算机拟合,导出了长江口附近海水及其稀释海水的状态方程,该方程计算值与实验值的平均标准偏差为±3.9×10~(-3)kg/m~3。     

Single electron loss in the collisions of C3 + and atomic hydrogen

This paper studies the projectile electron loss cross sections of C^{3 +} colliding with atomic hydrogen in the frame work of extended over-barrier model at intermediate velocities (25 keV/u--600 keV/u). The electron loss is calculated in terms of the interaction between the screened target nucleus and the active projectile electron and of the interaction between projectile electron and target electron. Compared with the convergent close-coupling calculations, screening and anti-screening calculations, this model satisfactorily reproduces the experimentally obtained energy dependence of the electron-impact ionisation cross sections and the single electron loss cross sections over the energy range investigated here.     

河南焦作地区下二叠统太原组遗迹化石及其沉积环境

河南省焦作地区下二叠统太原组发育一套陆表海碳酸盐岩以及海湾-潟湖、潮坪-沼泽和障壁岛 （砂质滩、坝） 相碎屑岩和煤层,其中保存有大量完好的遗迹化石,已识别出的有10个遗迹属11个遗迹种,包 括Zoohycos brianes,Zoohycos villae,Teichichnus rectus,Nereies isp．,Chondries isp.,Rhizocorallium isp.,Thalassinoides suevivus,Ophiomorpha nodosa,Gordiamaina,Taenidium satanassi和Planolites isp.等。这些遗迹化石多为 全浮痕保存,少数为半浮痕表迹保存,其丰度较高。根据遗迹化石的组成与产状特征及其围岩的沉积特征,可 识别出３种遗迹化石组合：(1) Zoohycos－Nereites遗迹组合,出现在水体相对较深、浪基面之下且沉积底层内 氧气贫乏的远岸浅海沉积环境;(2) Zoohycos－Taenidium遗迹组合,产生于水体相对较浅的浪基面之上的近岸 浅海沉积环境;(3)Ophiomorpha－Thalassinoides遗迹组合,发育于海岸带潮坪或海湾、湖沉积环境,遗迹化石 往往保存在泥质灰岩或钙质粉砂岩和薄层细砂岩中。基于遗迹化石组合的分布特点,提出了焦作地区太原组遗 迹化石的沉积环境模式。