Effects of key components of <Emphasis Type="Italic">S. triqueter</Emphasis> root exudates on fractions and bioavailability of pyrene–lead co-contaminated soils

The key components of S. triqueter root exudates involved 4-oxo-pentanoic acid, succinic acid, glutaric acid, phthalate acid, citric acid, vanillic acid, myristic acid, pentadecanoic acid, decanoic acid, 14-methyl-pentadecanoic acid, hexadecanoic acid, octadecanoic acid and oleic acid, and the content of the water-soluble organic acids (citric acid, succinic acid and glutaric acid) significantly increased in pyrene and lead co-contaminated rhizosphere soil. These three water-soluble organic acids including citric acid, succinic acid and glutaric acid were detected as the specific root exudates of S. triqueter under stress of pollutants for pyrene and lead, so they were chosen as the research objects, and they were added into the bioremediation systems of pyrene and lead co-contaminated wetland soils. Compared with the control, the treatments added the three organic acids always improved the quantity of the bioavailable fraction of pyrene and lead in wetland soils and greatly influenced other chemical states of pyrene and lead fractions in the test concentration range. Under the 50 g kg^?1 of organic acids concentration, the amount of the bioavailable fraction of pyrene and lead increased 41.0 and 872.7 % by citric acid, respectively. The enhancement of bioavailability of pyrene and lead in the wetland soil by adding organic acids generally decreased in the following order: citric acid > succinic acid > glutaric acid. Enhancing effects of organic acids on the bioavailability improvement of pyrene and lead is remarkable.     

Exploring the effects of data quality,data worth,and redundancy of CO2 gas pressure and saturation data on reservoir characterization through PEST inversion

This study examined the impacts of reservoir properties on carbon dioxide (CO₂) migration after subsurface injection and evaluated the possibility of characterizing reservoir properties using CO₂ monitoring data such as spatial–temporal distributions of gas pressure, which can be reasonably monitored in practice. The injection reservoir was assumed to be located 1,400–1,500 m below the ground surface such that CO₂ remained in the supercritical state. The reservoir was assumed to contain layers with alternating conductive and resistive properties, which is analogous to actual geological formations such as the Mount Simon Sandstone unit. The CO₂ injection simulation used a cylindrical grid setting in which the injection well was situated at the center of the domain, which extended out 8,000 m from the injection well. The CO₂ migration was simulated using the latest version of the simulator, subsurface transport over multiple phases (the water–salt–CO₂–energy module), developed by Pacific Northwest National Laboratory. A nonlinear parameter estimation and optimization modeling software package, Parameter ESTimation (PEST), is adopted for automated reservoir parameter estimation. The effects of data quality, data worth, and data redundancy were explored regarding the detectability of reservoir parameters using gas pressure monitoring data, by comparing PEST inversion results using data with different levels of noises, various numbers of monitoring wells and locations, and different data collection spacing and temporal sampling intervals. This study yielded insight into the use of CO₂ monitoring data for reservoir characterization and how to design the monitoring system to optimize data worth and reduce data redundancy. The feasibility of using CO₂ saturation data for improving reservoir characterization was also discussed.     

Evaluating the impact of caprock and reservoir properties on potential risk of CO2 leakage after injection

Numerical models are essential tools in fully understanding the fate of injected CO₂ for commercial-scale sequestration projects and should be included in the life cycle of a project. Common practice involves modeling the behavior of CO₂ during and after injection using site-specific reservoir and caprock properties. Little has been done to systematically evaluate and compare the effects of a broad but realistic range of reservoir and caprock properties on potential CO₂ leakage through caprocks. This effort requires sampling the physically measurable range of caprock and reservoir properties, and performing numerical simulations of CO₂ migration and leakage. In this study, factors affecting CO₂ leakage through intact caprocks are identified. Their physical ranges are determined from the literature from various field sites. A quasi-Monte Carlo sampling approach is used such that the full range of caprock and reservoir properties can be evaluated without bias and redundant simulations. For each set of sampled properties, the migration of injected CO₂ is simulated for up to 200 years using the water–salt–CO₂ operational mode of the STOMP simulator. Preliminary results show that critical factors determining CO₂ leakage rate through caprocks are, in decreasing order of significance, the caprock thickness, caprock permeability, reservoir permeability, caprock porosity, and reservoir porosity. This study provides a function for prediction of potential CO₂ leakage risk due to permeation of intact caprock and identifies a range of acceptable seal thicknesses and permeability for sequestration projects. The study includes an evaluation of the dependence of CO₂ injectivity on reservoir properties.     

白云岩体表生成岩裸露期古风化壳岩溶的规模

白云岩体表生成岩裸露期古风化壳岩溶对白云岩体古岩溶储渗体的形成至关重要。表生成岩裸露期古风化壳岩溶可形成地表残积层和表层之下大小不等的溶蚀空间。地表残积层与上覆盖层间可成为油气的储渗空间和通道,表层之下大小不等的溶蚀空间则可被塌积岩、冲积岩、填积岩和淀积岩充填,但其内常可保存部分孔隙,并为后来的埋藏溶解提供流体扩溶的初始空间和流体流动的通道。野外露头和井下岩心中的大量现象和事实说明,白云岩体表生成岩裸露期古风化壳的规模远小于石灰岩体。最主要原因是白云岩(石)可溶性远较石灰岩(方解石)小,同样组构的白云岩的物理力学强度亦较石灰岩小。白云岩体本身的岩性和组构、层理类型、泥质含量、构造裂隙的发育程度等都会影响裸露期古风化壳的规模。     

基于孔压静力触探的岩土参数正态性检验方法对比

岩土参数的正态分布是岩土工程可靠分析的基本假定之一。目前,岩土工程参数的正态性检验以KS （Kolmogorov-Smirnov）检验为主,然而诸多研究表明,对于小样本数据,KS检验的正态性检验结果并不可靠。本文以废黄河泛滥沉积相粉土中的孔压静力触探（CPTU）锥尖阻力q_t数据为研究对象,首先采用ANOVA （方差分析）检验,从CPTU测试资料中进行总体的样本筛选,然后应用SW （Shapiro-Wilk）检验、KS检验、LF （Lilliefors）检验和AD （Anderson-Darling）检验等4种正态性检验方法,在不同样本容量条件下,对测试数据进行正态性检验评价。当测试数据的样本容量充足时,分析结果表明：SW检验结果最为严格,KS检验结果最不保守,而LF检验和AD检验的严格性介于两者之间;对于常规岩土工程设计,采用KS检验结果即可满足稳定性分析要求,对于复杂岩土工程设计,采用SW检验对设计参数进行正态性检验,可降低设计的不确定性。     

Study on Monitoring Technology of Surrounding Rock in Deep Layered Roadway Based on Constant Resistance and Large Deformation Bolt

Geotechnical and Geological Engineering - The stability monitoring of surrounding rock in layered roadway is an important method to ensure the safety of deep mining coal mine. In view of the actual...     

渤海—鲁西地区白垩-早第三纪裂谷活动——火山岩的地球化学证据

渤海—鲁西地区的白垩早第三纪火山岩在渤海东部主要沿郯庐断裂带呈北北东向分布,在渤海西部和鲁西地区主要沿北西向断裂带分布。白垩纪火山岩以安山岩类为主,早第三纪以玄武岩类为主,玄武岩浆源于富集型地幔,即富集轻稀土和大离子亲石元素,但明显亏损Yb、Ni和Cr等元素。火山岩的Sr和Nd同位素初始比值结果表明白垩纪的火山岩来源于Ⅱ型富集地幔,而早第三纪火山岩来源于接近原始地幔的略富集型地幔。这可能由于早第三纪岩石圈大规模伸展减薄,致使上地幔深部的亏损型物质上涌参与岩浆活动,与富集型地幔混染的结果。     

吉林六批叶沟金矿床绢云母40Ar-39Ar 快中子活化法定年研究

在六批叶沟金矿石中,精选出与金矿物同期生成的绢云母作为样品,采用40Ar-39Ar快中子活化法测年,获得8个一致相连的平坦型绢云母年龄谱,tp=(190.28±0.30) Ma,氩同位素计算得等时线年龄为(189.98±0.58) Ma,两者完全吻合.等时线截距为(296.9±10.0) Ma,与大气氩的该值(295.5 Ma)相比较,两者完全吻合,表明该样品出自未受明显后期热力作用影响的非扰动体系.锁定六批叶沟金矿床主要成矿年龄为190 Ma左右,属早侏罗世的燕山早期.     

辽宁刘屯金矿床地质特征及成因

刘屯金矿床为含金硫化物石英脉型,矿体直接围岩为晚太古代混合花岗岩。区域上建平群大营子组为金的矿源层,金成矿与中生代构造岩浆活动密切相关。含金石英脉(矿脉)严格地受近东西向断裂构造控制。据硫同位素组成证明矿石、围岩、中生代侵入岩具有同一性,为幔源硫。氢氧同位素组成则显示了成矿溶液的多成因特征。矿石中铅同位素为古老的铅体系,与中生代岩体的长石铅属同一源地。通过时矿床成因的探讨,认为是"岩浆热源-混合热液"型复成因金矿床,成矿时代为燕山期。