Evidence for the occurrence of hydrogeochemical processes in the groundwater of Khoy plain,northwestern Iran,using ionic ratios and geochemical modeling

Rapid population growth, industrialization, and agricultural expansion in the Khoy area (northwestern Iran) have led to its dependence on groundwater and degradation of groundwater quality. This study attempts to decipher the major processes and factors that degrade the groundwater quality of the Khoy plain. For this purpose, 54 groundwater samples from unconfined and confined aquifers of the plain were collected in July 2017 and analyzed for major cations and anions (Na, K, Ca, Mg, HCO₃, SO_4, and Cl), minor ions (NO₃ and F), and Al. Magnesium and bicarbonate were identified as the dominant cation and anion, respectively. Several ionic ratios and geochemical modeling using PHREEQC indicated that the most important hydrogeochemical processes to affect groundwater quality in the plain were weathering and dissolution of evaporitic and silicate minerals, mixing, and ion exchange. There were smaller effects from evaporation and anthropogenic factors (e.g., industries). Results showed that the high salinity of the groundwater in the northeast area of the plain was due to the high solubility of the evaporitic minerals, e.g., halite and gypsum. Reverse ion exchange and the contribution of mineral dissolution were more significant than ion exchange in the northeastern part of the plain. Elevated salinity of the groundwater in the southeast was attributed mostly to reverse ion exchange and somewhat to evaporation.     

Geochemistry of Ground and Groundwater Pertinent to Chemical Attacks Mitigation on Concrete Foundations; A Case Study of the City of Rasht,Northern Iran

Presence of aggressive chemicals in ground and groundwater can deteriorate concrete foundations or its reinforcements. Concrete codes require preventive measures to assure durability of concrete foundations which is based on geochemistry information of the site. Construction in the city of Rasht, in the Iranian Caspian coast, is fast growing often without sufficient geochemistry data for residential buildings. The later may pose risk of chemical attacks on concrete foundations. To resolve this shortcoming, this study aimed at investigating geochemistry of ground and groundwater from the upper 10 m which can serve as a preliminary guideline for shallow foundation constructions in the city. The database for this study included previous geochemical investigations from 50 boreholes in the city as well as boring eleven test pits at various locations along with soil and groundwater geochemistry tests. The geochemistry experiments included measurement of sulfate, chloride, organic matter, as well as pH in soil and groundwater. Geochemistry of ground and groundwater in the city mostly fell within permissible limits set by a local concrete code. Based on current study, service environment for shallow concrete foundations in the city was categorized in a moderate class; hence, durability requirements from the same local concrete code were emphasized.     

Analysis of pervasive precipitation in similar gradient areas of Iran

Precipitation is a major climatic element with high spatial variations. Temporal and spatial variations may differ in large and small scales. It is, therefore, of utmost importance to study areas with similar gradients in terms of precipitation patterns in order to shed light on the complexities of precipitation variations. In the present study, attempts were made to identify areas with similar gradients experiencing the same precipitation pattern over a 50-year period (1964–2013). To this end, data were collected from synoptic stations in Iran in two phases (i.e., 1434 stations in the first phase and 673 stations in the second one). Alexanderson’s technique was adopted to examine sudden changes in precipitation patterns. The results showed that five regions with similar gradients could be identified in terms of precipitation patterns: negative and high variations, negative and moderate variations, positive and high variations, positive and moderate variations, and little or no variations. The distribution of such regions indicated that the regions with positive trends experienced more annual variations and had further spatial distribution. Furthermore, the findings revealed that the regions with negative precipitation patterns experienced more sudden changes in comparison with those with positive precipitation patterns. Additionally, more variations were observed in the precipitation patterns in recent years.     

APG:A novel python-based ArcGIS toolbox to generate absence-datasets for geospatial studies

One important step in binary modeling of environmental problems is the generation of absence-datasets that are traditionally generated by random sampling and can undermine the quality of outputs.To solve this problem,this study develops the Absence Point Generation(APG)toolbox which is a Python-based ArcGIS toolbox for automated construction of absence-datasets for geospatial studies.The APG employs a frequency ratio analysis of four commonly used and important driving factors such as altitude,slope degree,topographic wetness index,and distance from rivers,and considers the presence locations buffer and density layers to define the low potential or susceptibility zones where absence-datasets are gener-ated.To test the APG toolbox,we applied two benchmark algorithms of random forest(RF)and boosted regression trees(BRT)in a case study to investigate groundwater potential using three absence datasets i.e.,the APG,random,and selection of absence samples(SAS)toolbox.The BRT-APG and RF-APG had the area under receiver operating curve(AUC)values of 0.947 and 0.942,while BRT and RF had weaker per-formances with the SAS and Random datasets.This effect resulted in AUC improvements for BRT and RF by 7.2,and 9.7％from the Random dataset,and AUC improvements for BRT and RF by 6.1,and 5.4％from the SAS dataset,respectively.The APG also impacted the importance of the input factors and the pattern of the groundwater potential maps,which proves the importance of absence points in environmental bin-ary issues.The proposed APG toolbox could be easily applied in other environmental hazards such as landslides,floods,and gully erosion,and land subsidence.     

Biostratigraphy and Sequence Stratigraphy of the Tarbur Formation (Maastrichtian) from Iranian Zagros Foreland Basin, Southwest of Iran

Shallow carbonate deposits(Tarbur Formation)were formed in the Zagros foreland basin with dynamic tectonics during the Maastrichtian age.From the viewpoint of reconstruction of depositional conditions in these deposits,studies of biostratigraphy,microfacies,microtaphofacies,and sequence stratigraphy were performed in a single area at Tang-e Shabi Khoon,northwest of Zagros.Based on the identification of two assemblage zones consisting of benthic foraminifera in these strata,the formation was deposited during the middle to late Maastrichtian.The number of cycles in test size and type of coiling in Loftusia decreased from the study area toward the northwest of the Neotethys basin.The input of clastic sediments affected the distribution of Loftusia and rudists in the study area.Nine microfacies,six microtaphofacies,and one terrigenous facies(shale)were identified based on the sedimentary features.These deposits of the middle-late Maastrichtian were deposited on a homoclinal carbonate ramp.The platform can be divided into restricted and semi-restricted lagoon,shoal,and open marine environments.In the study area,the deposits of the Tarbur Formation were deposited during four third-order depositional sequences.Local fault activities affected the formation of depositional sequences in the study area.     

Artificial recharge efficiency assessment by soil water balance and modelling approaches in a multi-layered vadose zone in a dry region

To assess recharge through floodwater spreading, three wells, approx. 30 m deep, were dug in a 35-year-old basin in southern Iran. Hydraulic parameters of the layers were measured. One well was equipped with pre-calibrated time domain reflectometry (TDR) sensors. The soil moisture was measured continuously before and after events. Rainfall, ponding depth and the duration of the flooding events were also measured. Recharge was assessed by the soil water balance method, and by calibrated (inverse solution) HYDRUS-1D. The results show that the 15 wetting front was interrupted at a layer with fine soil accumulation over a coarse layer at the depth of approx. 4 m. This seemed to occur due to fingering flow. Estimation of recharge by the soil water balance and modelling approaches showed a downward water flux of 55 and 57% of impounded floodwater, respectively.     

Evaluation of public participation in reconstruction of Bam,Iran, after the 2003 earthquake

In the midst of the ever-increasing natural and human-induced disasters, where many of the preparedness and mitigation measures show inefficiencies, there is narrow margin for decision-makers to make mistakes by misallocating budgets, designing infeasible reconstruction plans, and in other terms, making decisions not in line with the public preferences. In particular, public participation in post-disaster measures seems undoubtedly necessary to reduce the possible economic, social, political, and cultural conflicts around the stressful community after a major disaster. This paper aims at evaluating the role of public participation in increasing the reconstruction phase efficiency through a case study of the reconstruction process in Bam, a southeastern Iranian city, after the 2003 earthquake. It is attempted to identify the major motivators of the public participation through a combination of quantitative and qualitative studies. Statistical data are generated through a set of questionnaires being filled by a number of 200 randomly selected survivors. The numerical results were then discussed through the Focus Group technique sessions to determine the main contributors to the public participation. It is later found that the answers are found among the performance of the reconstruction authorities, financial policies, emotional resiliency of the survivors, public information mechanisms, public satisfaction, the pace of reconstruction, and temporary housing policies.     

Forecasting monthly inflow with extreme seasonal variation using the hybrid SARIMA-ANN model

The optimal operation of dam reservoirs can be programmed and managed by predicting the inflow to these structures more accurately. To this end, there are various linear and nonlinear models. However, some hydrological problems like inflow with extreme seasonal variation are not purely linear or nonlinear. To improve the forecasting accuracy of this phenomenon, a linear Seasonal Auto Regressive Integrated Moving Average (SARIMA) model is combined with a nonlinear Artificial Neural Network (ANN) model. This new model is used to predict the monthly inflow to the Jamishan dam reservoir in West Iran. A comparison of the SARIMA and ANN models with the proposed hybrid model’s results is provided accordingly. More specifically, the models’ performance in forecasting base and flood flows is evaluated. The effect of changing the forecasting period length on the models’ accuracy is studied. The results of increasing the number of SARIMA model parameters up to five are investigated to achieve more accurate forecasting. The hybrid model predicts peak flood flows much better than the individual models, but SARIMA outperforms the other models in predicting base flow. The obtained results indicate that the hybrid model reduces the overall forecast error more than the ANN and SARIMA models. The coefficient of determination of the hybrid, ANN and SARIMA models were 0.72, 0.64 and 0.58, and the root mean squared error values were 1.02, 1.16 and 1.27 respectively, during the forecast period. Changing the forecasting length also indicated that these models can be used in the long term without increasing the forecast error.     

Assessment of geomorphological bank evolution of the alluvial threshold rivers based on entropy concept parameters

The complex stream bank profiles in alluvial channels and rivers that are formed after reaching equilibrium has been a popular topic of research for many geomorphologists and river engineers. The entropy theory has recently been successfully applied to this problem. However, the existing methods restrict the further application of the entropy parameter to determine the cross-section slope of the river banks. To solve this limitation, we introduce a novel approach in the extraction of the equation based on the calculation of the entropy parameter (λ) and the transverse slope of the bank profile at threshold channel conditions. The effects of different hydraulic and geometric parameters are evaluated on a variation of the entropy parameter. Sensitivity analysis on the parameters affecting the entropy parameter shows that the most effective parameter on the λ-slope multiplier is the maximum slope of the bank profile and the dimensionless lateral distance of the river banks.     

The effect of different meteorological parameters on the temporal variations of reference evapotranspiration

Temporal changes of meteorological variables can affect reference evapotranspiration (ET₀). The goal of the present research is to analyze the changes of ET₀ and identify the impact of effective meteorological parameters to the changes of ET₀. For this purpose, daily meteorological data recorded in 30 synoptic stations of Iran during 1960–2014 were used. The annual and seasonal values of ET₀ were calculated by the recorded data. To calculate ET₀, FAO56 Penman–Monteith method (standard method) was used. The annual and seasonal trends of ET₀ and its eight effective parameters were analyzed. Then the contributions of effective parameters changes on ET₀ were determined. To analyze ET₀ trend at annual and seasonal scales, two common methods, Spearman’s Rho and Mann–Kendall tests, were used. The R ² = 0.99 showed that the results of the mentioned methods were similar and on the basis of T-statistic <0.057, their difference was not significant (95% confidence level). Therefore, only one method’s results (Spearman’s Rho) were reported. On the basis of Spearman’s Rho results, the annual and seasonal values of ET₀ had negative trend in most of arid and semi-arid stations while the trend of this parameter was positive in humid and very humid stations. At annual and seasonal scales, decreasing in wind speed (W), temperature (T), sunshine hours (n), minimum temperature (TN), dew point temperature (TD), maximum temperature (TX), saturation vapor pressure deficit (SVPD) and solar radiation (RS) was observed in 58, 54, 39, 43, 56, 65, 65 and 37% studied stations, respectively. In many scales, the results showed that TX and W were the most effective meteorological variables on ET₀ changes and then SVPD was located in second step in arid and semi-arid stations. In humid and very humid stations, W was the first effective parameter at all scales, except autumn.