Cloud Point Extraction for the Preconcentration of Silver and Palladium in Real Samples and Determination by Atomic Absorption Spectrometry

A cloud point extraction procedure is presented for the preconcentration and simultaneous determination of Ag⁺ and Pd²⁺ in various samples. After complexation with 2‐((2‐((1H‐benzo[d]imidazole‐2‐yl)methoxy)phenoxy)methyl)‐1H‐benzo[d]imidazol (BIMPI), which was used as a new chelating agent, analyte ions were quantitatively extracted to a phase rich in Triton X‐114 following centrifugation, and determination was carried out by flame atomic absorption spectrometry (FAAS). Under the optimum experimental conditions (i. e., pH = 7.0, 15.0·10^–5 mol/L BIMPI and 0.036% (w/v) Triton X‐114), calibration graphs were linear in the range of 28.0–430.0 μg/L and 57.0–720.0 μg/L with detection limits of 10.0 and 25.0 μg/L for Ag⁺ and Pd²⁺, respectively. The enrichment factors were 35.0 and 28.0 for Ag⁺ and Pd²⁺, respectively. The method has been successfully applied to evaluate these metals in some real samples, including waste water, soil and hydrogenation catalyst samples.     

Hydrological drought in the west of Iran and possible association with large‐scale atmospheric circulation patterns

Drought is a slow‐onset, creeping natural hazard which is an inevitable part of normal climate fluctuation especially in arid and semiarid regions, and its variability can be explained in terms of large‐scale atmospheric circulation patterns. Standardized streamflow index (SSFI) was utilized to characterize hydrological drought in the west of Iran for the hydrological years of 1969–1970 to 2008–2009. The linkage of atmospheric circulation patterns (ENSO, NAO) to hydrological drought was also used to reveal relations of climate variability affecting hydrological drought. River discharges exhibited negative anomalies during the warm phase of ENSO (El Niño) which caused the extreme and severe droughts in the study area, being strongest during the hydrological years of 2007–2008 and 2008–2009. The analysis also indicated the teleconnection impact of ENSO on the hydrological drought severity in the first half of the hydrological year especially between November and March. Moreover, the concurrent and lag correlations revealed a weak relationship between the SSFI drought severity and the NAO index. Copyright © 2012 John Wiley & Sons, Ltd.     

Comparison of linear and nonlinear forms of isotherm models for Zn(II) and Cu(II) sorption on a kaolinite

The most appropriate method in designing the adsorption systems and assessing the performance of the adsorption systems is to have an idea on adsorption isotherms. Comparison analysis of linear least square method and nonlinear method for estimating the isotherm parameters was made using the experimental equilibrium data of Zn(II) and Cu(II) onto kaolinite. Equilibrium data were fitted to Freundlich, Langmuir, and Redlich–Peterson isotherm equations. In order to confirm the best-fit isotherms for the adsorption system, the data set using the chi-square (χ ²), combined with the values of the determined coefficient (r ²) was analyzed. Nonlinear method was found to be a more appropriate method for estimating the isotherm parameters. The best fitting isotherm was the Langmuir and Redlich–Peterson isotherm. The Redlich–Peterson is a special case of Langmuir when the Redlich–Peterson isotherm constant g was unity. The sorption capacity of kaolinite to uptake metal ions in the increasing order was given by Cu (4.2721 mg/g)?<?Zn (4.6710 mg/g).     

Investigating the role of source mechanism,surface topography,and attenuation on the observed PGA pattern in May 28, 2004, Mw 6.2 Baladeh earthquake (Iran)

In this paper, we use seismic waveform simulation to investigate the influence of source mechanism complexity, surface topography, and quality factor on the observed peak ground motions in May 28, 2004, moment magnitude (Mw) 6.2 Baladeh earthquake. The observed peak ground acceleration (PGA) pattern in this event, which is the biggest earthquake to hit the Central Alborz Mountains of Iran in modern instrumental era, is irregular in some respects. First, the observed PGA contours are elongated toward north-west and, second, the maximum observed PGA value of 1049 cm/s² on the horizontal component of Hasan Keyf station 50 km away from the epicenter is quite high and irregular for an earthquake of this magnitude, at such long distance. In this study, we employ the spectral element method, implemented in SPECFEM3D software package to simulate the 3D wave propagation from several source models in the area. Our results suggest directivity effect is the main cause of the anomalous observations in this earthquake and could account for the elongation of PGA contours and also the anomalous maximum PGA value observed at Hasan Keyf strong motion station. We show that the surface topography has minor effect on the observed peak ground acceleration and the resulting PGA maps. Also by finding the bounds of seismic quality factor effect on the peak ground acceleration values, we show that this factor could not account for the elongation of iso-acceleration contours in the north-west direction.     

Vibration screening by trench barriers,a review

This paper provides a review of various investigations concerned with vibration isolation using trench barriers and factors affecting their performance, also extracts design recommendations, because there is no exact conclusion of researches in this field. Vibrations induced by different sources can be seriously harmful to structures and occupants. Geometrical parameters, soil characteristics, and filling material properties can affect a barrier’s performance. Investigators have applied analytical approach, finite element, boundary element, experimental, and field studies to identify relevant factors. Various geometrical parameters affecting trench’s isolation level were examined, among which depth of trench was found to be the most important, but in most cases, the width of the trench and source-barrier distance have a low effect. Shear-wave velocity ratio of filling material and surrounding soil has the most significant role of all material properties. Using high-energy-absorbing materials can lead to better isolation. The majority of studies consider soil and filling material’s behavior to be elastic, so changes in loading amplitude have no effect on vibration reduction. Finally, among special cases in vibration isolation by trenches, non-rectangular and multiple ones found to be economically satisfying and well-isolating barriers.     

Iranian earthquakes, a uniform catalog with moment magnitudes

A uniform earthquake catalog is an essential tool in any seismic hazard analysis. In this study, an earthquake catalog of Iran and adjacent areas was compiled, using international and national databanks. The following priorities were applied in selecting magnitude and earthquake location: (a) local catalogs were given higher priority for establishing the location of an earthquake and (b) global catalogs were preferred for determining earthquake magnitudes. Earthquakes that have occurred within the bounds between 23–42° N and 42–65° E, with a magnitude range of M _W 3.5–7.9, from the third millennium BC until April 2010 were included. In an effort to avoid the “boundary effect,” since the newly compiled catalog will be mainly used for seismic hazard assessment, the study area includes the areas adjacent to Iran. The standardization of the catalog in terms of magnitude was achieved by the conversion of all types of magnitude into moment magnitude, M _W, by using the orthogonal regression technique. In the newly compiled catalog, all aftershocks were detected, based on the procedure described by Gardner and Knopoff (Bull Seismol Soc Am 64:1363–1367, 1974). The seismicity parameters were calculated for the six main tectonic seismic zones of Iran, i.e., the Zagros Mountain Range, the Alborz Mountain Range, Central Iran, Kope Dagh, Azerbaijan, and Makran.     

Application of the Christensen Failure Criterion to Intact Rock

The Christensen criterion, originally introduced in materials science, has a simple mathematical form and uniaxial tensile and compressive strength as the only parameters, making it an attractive candidate for rock engineering purposes. In this study, the applicability of the criterion to rock materials is examined. Explicit equations for application of the criterion under biaxial, triaxial compression, triaxial extension, and polyaxial states of stresses are derived. A comprehensive strength data set including the results of tests on synthetic rock, chert dyke, Carrara marble and Westerly granite is utilized to examine the accuracy of the Christensen criterion to the failure of rock material. The two surprising findings about the Christensen criterion are the zero values of tensile strength and the very low slopes of the failure envelope obtained from fitting analyses for chert dyke and Westerly granite. It is shown that the two problems are interrelated and the values of tensile strength tend to zero to produce higher slopes. It is then mathematically proven that the maximum initial slope of the Christensen failure envelope is limited to 4 in triaxial compression and 2.5 in triaxial extension which is considerably lower than the slope of experimental data. The accuracy of the Christensen criterion was found to be significantly lower than the well-established Hoek–Brown criterion. The circular π-plane representations and brittle-to-ductile transition limits from the Christensen criterion are also inconsistent with the observed behavior of rocks.     

A new rating system approach for risk analysis of rock slopes

In this paper, an approach is presented to analyze the stability risk of rock slopes based on a new rating system. Three factors are used to estimate the risk level of rock slopes: (1) failure probability, (2) element at risk rating, and (3) vulnerability rating. Element at risk and vulnerability ratings are both given a range from 0 to 10, and the probability of failure is varied between 0 and 1, so the risk rating ranges between 0 and 100. This risk rating can be used to determine both the quantitative and qualitative risk levels of slopes at the same time. The method is tested on the western sector of the slopes facing Songun copper plant phase III, Iran, to clarify its procedures and assess its validity. Deterministic kinematic analyses showed that the slope has a potential for circular failure. Risk assessments revealed that the risk levels of the slope in both static and pseudo-static conditions are “very low” and “high,” respectively.