Adsorption of Thallium(I) Ions Using Eucalyptus Leaves Powder

Using batch method, the adsorption of thallium(I) ions from aqueous solutions on eucalyptus leaves powder, as a low cost adsorbent, was studied. The effect of various modification of considered adsorbent on the adsorption percentage of Tl(I) is an important feature of this study. The results showed that the unmodified and acidic modified adsorbent are the poor adsorbents for the Tl(I) ions while basic modified adsorbent is a suitable adsorbent. Also, the effect of some experimental conditions such as solution initial pH, agitation speed, contact time, sorbent dosage, temperature, particle size, and thallium initial concentration was studied. The results showed that the adsorption percentage depends on the conditions and the process is strongly pH‐dependent. The satisfactory adsorption percentage of Tl(I) ions, 81.5%, obtained at 25 ± 1°C. The equilibrium data agreed fairly better with Langmuir isotherm than Freundlich and Temkin models. The value of q_m that was obtained by extrapolation method is 80.65 mg g^?1. Separation factor values, R_L, showed that eucalyptus leaves powder is favorable for the sorption of Tl(I). The negative values of ΔH⁰ and ΔS⁰ showed that the Tl(I) sorption is an exothermic process and along with decrease of randomness at the solid–solution interface during sorption, respectively.     

Hazards of mechanized tunnel excavation in H<Subscript>2</Subscript>S bearing ground in Aspar tunnel,Iran

Occurrence of hydrogen sulfide gas (H₂S) is one of the most important engineering geological hazards during tunneling. Its hazards and consequent challenges are very difficult and costly to solve. During site investigation, one of the tasks for engineering geologists is prediction and evaluation of the risk of H₂S gas in the underground spaces. In this study, water conveyance tunnel of Aspar, which was excavated in H₂S-bearing environments, is discussed. The tunnel is excavated in the hydrocarbon formations. Applied experiments suggest that geological formations pertaining to hydrocarbon resources are crucial in formation and reservation of H₂S gas. This paper briefly discusses hazards and geological sources of H₂S, as well as remedial measures for decreasing the risks and problems in excavation of the tunnel. To predict the risk of H₂S gas in the underground spaces, it is possible to use some precursors such as: sulfur springs, organic traces, organic argillaceous rocks, exposure of H₂S odor from fresh surface of rock and smell of H₂S during boreholes drilling. Controlling the inflow of groundwater into the excavation, diluting the concentration of H₂S, training the personnel and utilization of some proper safety equipment have been used to mitigate risks and problems in tunnel excavation.     

Coupled and splitting bedload sediment transport models based on a modified flux-wave approach

Numerical modeling of free-surface flow over a mobile bed with predominantly bedload sediment transport can be done by solving the shallow water and Exner equations using coupled and splitting approaches.The coupled method uses a coupling of the governing equations at the same time step leading to a non-conservative solution.The splitting method solves the Exner and the shallow water equations in a separate manner,and is only capable of modeling weak free-surface and bedload interactions.In the current study,an extended version of a Godunov-type wave propagation algorithm is presented for modeling of morphodynamic systems using both coupled and splitting approaches.In the introduced coupled method the entire morphodynamic system is solved in the form of a conservation law.For the splitting technique,a new wave Riemann decomposition is defined which enables the scheme to be utilized for mild and strong interactions.To consider the bedload sediment discharge within the Exner equation,the Smart and Meyer-Peter&Müller formulae are used.It was found that the coupled solution gives accurate predictions for all investigated flow regimes including propagation over a dry-state using a Courant-Friedrichs-Lewy(CFL)number equal to 0.6.Furthermore,the splitting method was able to model all flow regimes with a lower CFL number of 0.3.     

Patterns of Chemical Changes During Environmental Alteration of Hydrocarbon Fuels

This paper discusses major environmental alteration processes and describes a set of chemical tests that have been developed to monitor compositional changes in hydrocarbon fuels released into the environment. The methods examine various homologous series of hydrocarbons including straight chain (paraffins or n-alkanes), branched chain (isoparaffins or isoprenoids), alicyclic (naphthenes or alkylated cyclohexanes), polycyclic (steranes and terpanes), and aromatic structures (benzene, toluene, ethylbenzene. xylenes, alkylated benzenes, polycyclic aromatic hydrocarbons, and aromatic steranes). Each one of these groups of hydrocarbons has a different tolerance to environmental alteration by evaporation, dissolution (water washing), and biodegradation. When used as an analytical system on environmental samples, the data obtained provide information on fuel type recognition patterns and on degradation levels of the various fuels, allowing for an estimate of residence time.     

Hydromechanical behaviour of an expansive bentonite/silt mixture in cyclic suction-controlled drying and wetting tests

To further our knowledge of coupling between the hydraulic cycles and mechanical behaviour of the swelling soils, this paper presents an experimental study on a bentonite/silt mixture using an odometer with suction controlled by the osmotic technique. A loading/unloading cycle was applied to each of the samples at different constant suctions (0, 2, 3 and 8 MPa). Moreover, successive wetting and drying cycles were applied under constant vertical stress at a suction range of 0 to 8 MPa, followed by a loading/unloading cycle at similar suctions (0, 2, 3 and 8 MPa). Finally, the compression curves of the aforementioned suctions with and without the application of suction cycles were compared, so as to analyse the influence of hydraulic cycles on the soil fabric and the mechanical parameters. It is observed that the wetting and drying cycles applied to both the micro- and macrostructure significantly influenced the virgin compression index λ(s), the apparent preconsolidation stress p₀(s) and the elastic compression index values κ. However, the hydraulic cycles imposed only on the micro- or macrostructure induce negligible changes in the mechanical parameters of the soil.     

Transient Scattering of Elastic Waves by Dipping Layers of Arbitrary Shape Part 1: Antiplane Strain Model

Scattering of elastic waves by two dimensional multilayered dipping sediments of arbitrary shape embedded in an elastic half-sapce is investigated by using a bondary method. The displancement field is evaluated throughout the elastic media for both steady state and transient incident SH waves. The unknown scattered field is expressed in terms of wave functions which satisfy the equation of motion, traction-free boundary condition and appropariate radiation conditions. The transient response is constructed from the steady state solution by using the fast Fourier transform technique. The numerical results presented demonstrate that scattering of waves by subsurface irregularities may cause locally very large amplification of surface ground motion. The motion can be affected greatly by the scattered surface waves in the sediments. The results clearly indicate that the surface ground motion depends upon a number of parameters present in the problem, such as frequency and the angle of incidence of the incoming wave, impedance contrast between the layers and location of the observation point.