Interaction of bentonite colloids with Cs, Eu, Th and U in presence of humic acid: A flow field-flow fractionation study

The interaction of Cs(I), Eu(III), Th(IV) and U(VI) with montmorillonite colloids was investigated in natural Grimsel Test Site groundwater over a 3 years period. The asymmetric flow field-flow fractionation combined with various detectors was applied to study size variations of colloids and to monitor colloid association of trace metals. The colloids suspended directly in the low ionic strength (I), slightly alkaline granitic groundwater (I = 10⁻³ mol/L, pH 9.6) showed a gradual agglomeration with a size distribution shift from initially 10-200 nm to 50-400 nm within over 3 years. The Ca²⁺ concentration of 2.1 × 10⁻⁴ mol/L in the ground water is believed to be responsible for the slow agglomeration due to Ca²⁺ ion exchange against Li⁺ and Na⁺ at the permanently charged basal clay planes. Furthermore, the Ca²⁺ concentration lies close to the critical coagulation concentration (CCC) of 10⁻³ mol L⁻¹ for clay colloids. Slow destabilization may delimit clay colloid migration in this specific groundwater over long time scales. Eu(III) and Th(IV) are found predominantly bound to clay colloids, while U(VI) prevails as the UO₂(OH)₃⁻ complex and Cs(I) remains mainly as aquo ion under our experimental conditions. Speciation calculations qualitatively represent the experimental data. A focus was set on the reversibility of metal ion-colloid binding. Addition of humic acid as a competing ligand induces rapid metal ion dissociation from clay colloids in the case of Eu(III) even after previous aging for about 3 years. Interestingly only partial dissociation occurs in the case of Th(IV). Experiments and calculations prove that the humate complexes dominate the speciation of all metal ions under given conditions. The partial irreversibility of clay bound Th(IV) is presently not understood but might play an important role for the colloid-mediated transport of polyvalent actinides over wide distances in natural groundwater.     

Quiet-time periods observed by EPHIN/SOHO during the minimum of the 22nd solar cycle

An analysis of the hydrogen and helium isotopic composition from EPHIN data, during the quiet-time period from January 1 to June 1, 1996, is presented. An isotopic discrimination and background rejection have been applied and relationships between the abundances of ²H/¹H, ³He/⁴He, and ⁴He/¹H have been calculated. The energy spectra in the 4–50 MeV nucl^–1 range have been obtained and the contribution of the different spectral components have been analysed in this energy range. We conclude that the main contribution to the ⁴He spectrum is of anomalous origin, while the proton and ³He spectra have contributions mainly from particles of solar origin at low energies and from the galactic cosmic radiation modulated by the heliosphere at high energies. The deuterium spectrum is mainly of galactic origin.     

Geomagnetische Induktionspfeile in der ČSSR,Hervorgerufen durch Grossräumige Elektrische Leitfähigkeitsstrukturen

Резюме Значительные раэности электропроводности в горизонтальном направлении заставляют индуцируемые ионосферными временными вариациями электрические токи в подстиляющих слоях протекать по преимущественным направлениям. В статье представляются вызванные этим вариации вертикальной и горизонтальной составляющих для периодов 19–40 мун в 20 пунктах в ЧССР, где регистрировались магнитные вариации при помощи полевых регистрирующих станций.

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Mitteilung Nr. 194 des Geomagnetischen Instituts Potsdam.     

Nachweis von Industriechemikalien (HPS,BPS und SPS) im Oberflächenwasser

Occurrence of Industrial Chemicals (HPS, BPS, and SPS) in Surface Water The paper gives the results of water examinations for different phenylsulfonamides. Random samples taken every month between May 1999 and August 2000 from surface water out of the river Rhine (kilometer 838), the river Ruhr (Mülheim Styrum) and the river Emscher (Oberhausen center) were tested for the corrosion inhibiting agent 6‐[methyl(phenylsulfonyl)amino]‐hexanoic acid (HPS) as well as its metabolites 4‐[methyl‐(phenylsulfonyl)amino]‐butanoic acid (BPS) and sarkosin‐N‐(phenylsulfonyl) (SPS). Furthermore, the sewage plant effluents of two municipal wastewater treatment plants from the rural area were also included in the monitoring program. The analytical method includes solid‐phase extraction (SPE), a derivatization step as well as gas chromatography mass spectrometry (GC‐MS). SPS is regularly found in all investigated surface waters, but only occasionally in the effluents of the two rural sewage plants. The median values for SPS amount to 0.09 μg/L in the river Rhine, 0.60 μg/L in the river Ruhr, and 0.70 μg/L in the river Emscher. BPS can only be found in the river Ruhr (median value: 0.08 μg/L) and in the river Emscher (median value: 0.41 μg/L). HPS was regularly found in a surface water for the first time. This substance can be detected in the Emscher through the whole measurement period. The median value for HPS amounts to 1.78 μg/L. Aditionally, the validation characteristics of an alternative analytical method including solid‐phase microextraction (SPME) is worked out. The fully automated process includes an on‐fiber methylation step and the GC‐MS. The repeatability standard deviation of the process amounts to RSD < 12%. Detection limits between 0.07 and 0.70 μg/L are achieved.     

Methane emission measurements in urban areas in Eastern Germany

We have investigated methane emissions from urban sources in the former East Germany using innovative measurement techniques including a mobile real-time methane instrument and tracer release experiments. Anthropogenic and biogenic sources were studied with the emphasis on methane emissions from gas system sources, including urban distribution facilities and a production plant. Methane fluxes from pressure regulating stations ranged from 0.006 to 24. l/min. Emissions from diffuse sources in urban areas were also measured with concentration maps and whole city flux experiments. The area fluxes of the two towns studied were 0.37 and 1.9 g/m²/s. The emissions from individual gas system stations and total town emissions of this study are comparable to results of similar sites examined in the United States.     

Methods for biological assessment of salt-loaded running waters - fundamentals, current positions and perspectives

Salinisation of running waters is a severe problem in many parts of the world. Monitoring and management of such waters require ecological methods which consider the hydrochemical effects of salinisation on the aquatic communities in order to set targets to protect habitats and biodiversity. Several bioassays have been developed for this purpose and are surveyed here. They are based on the salt sensitivity of the following groups of organisms: diatoms, ciliates and macroinvertebrates. In this paper experiences gained so far are also considered as well as practical applications originating from this research.     

Observations of Comet 9P/Tempel 1 around the Deep Impact event by the OSIRIS cameras onboard Rosetta

The OSIRIS cameras on the Rosetta spacecraft observed Comet 9P/Tempel 1 from 5 days before to 10 days after it was hit by the Deep Impact projectile. The Narrow Angle Camera (NAC) monitored the cometary dust in 5 different filters. The Wide Angle Camera (WAC) observed through filters sensitive to emissions from OH, CN, Na, and OI together with the associated continuum. Before and after the impact the comet showed regular variations in intensity. The period of the brightness changes is consistent with the rotation period of Tempel 1. The overall brightness of Tempel 1 decreased by about 10% during the OSIRIS observations. The analysis of the impact ejecta shows that no new permanent coma structures were created by the impact. Most of the material moved with . Much of it left the comet in the form of icy grains which sublimated and fragmented within the first hour after the impact. The light curve of the comet after the impact and the amount of material leaving the comet ( of water ice and a presumably larger amount of dust) suggest that the impact ejecta were quickly accelerated by collisions with gas molecules. Therefore, the motion of the bulk of the ejecta cannot be described by ballistic trajectories, and the validity of determinations of the density and tensile strength of the nucleus of Tempel 1 with models using ballistic ejection of particles is uncertain.     

A spherical model for computing polarized radiation in Titan's atmosphere

The Huygens descent through Titan's atmosphere in January 2005 will provide invaluable information about Titan's atmospheric composition and aerosol properties. The Descent Imager/Spectral Radiometer (DISR) will perform upward and downward looking radiation observations at various spectral ranges and spatial resolutions. To prepare the DISR data interpretation we have developed a new model for radiation transfer in Titan's atmosphere. The model solves for the full three-dimensional polarized radiation field in spherical geometry. However, the atmosphere itself is assumed to be spherically symmetric. The model is initialized with a fast-to-compute plane–parallel solution based on the doubling and adding algorithm that incorporates a spherical correction for the incoming direct solar beam. The full three-dimensional problem is then solved using the characteristics method combined with the Picard iterative approximation as described in Rozanov et al. (J. Quant. Spectrosc. Radiat. Transfer 69 (2001) 491). Aerosol scattering properties are calculated with a new microphysical model. In this formulation, aerosols are assumed to be fractal aggregates and include methane gas absorption embedded into the extinction coefficient. The resulting radiance of the model atmosphere's internal field is presented for two prescribed DISR wavelengths.     

Observations of atmospheric water vapor above the Tharsis volcanoes on Mars with the OMEGA/MEx imaging spectrometer

The OMEGA imaging spectrometer onboard the Mars Express spacecraft is particularly well suited to study in detail specific regions of Mars, thanks to its high spatial resolution and its high signal-to-noise ratio. We investigate the behavior of atmospheric water vapor over the four big volcanoes located on the Tharsis plateau (Olympus, Ascraeus, Pavonis and Arsia Mons) using the 2.6 μm band, which is the strongest and most sensitive H₂O band in the OMEGA spectral range. Our data sample covers the end of MY26 and the whole MY27, with gaps only in the late northern spring and in northern autumn. The most striking result of our retrievals is the increase of water vapor mixing ratio from the valley to the summit of volcanoes. Corresponding column density is often almost constant, despite a factor of ∼5 decrease in air mass from the bottom to the top. This peculiar water enrichment on the volcanoes is present in 75% of the orbits in our sample. The seasonal distribution of such enrichment hints at a seasonal dependence, with a minimum during the northern summer and a maximum around the northern spring equinox. The enrichment possibly also has a diurnal trend, being the orbits with a high degree of enrichment concentrated in the early morning. However, the season and the solar time of the observations, due to the motion of the spacecraft, are correlated, then the two dependences cannot be clearly disentangled. Several orbits exhibit also spatially localized enrichment structures, usually ring- or crescent-shaped. We retrieve also the height of the saturation level over the volcanoes. The results show a strong minimum around the aphelion season, due to the low temperatures, while it raises quickly before and after this period. The enrichment is possibly generated by the local circulation characteristic of the volcano region, which can transport upslope significant quantities of water vapor. The low altitude of the saturation level during the early summer can then hinder the transport of water during this season. The influence of the coupling between atmosphere and surface, due mainly to the action of the regoliths, can also contribute partially to the observed phenomenon.