X-ray determination of brushite (CaHPO4 · 2H2O) suspended in the water of the Neckar River,west Germany

The results reported in the present paper are a by-product of a detailed study of the heavy metals (Zn, Pb, Cu, Cd, Co, Ni, Cr, Fe, Mn) carried by the Upper Neckar River, Germany. The purpose was to determine the pollution by industrial waste of the river waters (Abadian 1976). In order to elucidate the various mechanisms of heavy-metal transport in the river, the clay of the bottom sediments and that carried in suspension was analysed for the metals at a number of locations and subjected to X-ray diffraction for the determination of the clay minerals present. The bottom sediments consist of kaolinite, illite, random interstratification (of mica and expandable layers) and quartz. In some samples chlorite and calcite were detected as well. The mineral content of the suspended load was collected by pressure filtration on porous ceramic plates. The clay minerals determined by subjecting the plates plus filtered residue to X-ray diffraction were the same as in the sediments. In addition to the clay-mineral reflections, three of the samples obtained from suspension (locations 2, 3, and 5 in the map, Fig. 1) showed the strongest diffraction line of the mineral brushite, CaHPO₄·2H₂O, at 7.6 Å. In one sample (location 2) three more lines of brushite were observed. The occurrence of brushite in the Neckar may be taken as a mineralogical indicator of the pollution of the river, because the following materials may be possible sources of the phosphate: artificial fertilizers, liquid manure, water softeners, detergents, and industrial waste waters.     

Die alpidischen Stockwerke der südlichen Ägäis

Zusammenfassung Im Bereich der südlichen Ägäis überlagern vier allochthone Stockwerke den autochthonen Plattenkalk (Perm-Oligozän). Die allochthonen Serien entstammen ursprünglich konzentrisch angeordneten mesozoisch-alttertiären Faziesräumen der zentralen Ägäis. Die tektonische Abfolge aus neritischen Karbonaten, pelagischen Karbonaten und einem vulkano-sedimentären Komplex, die durch inkompetente Zwischenmittel (Mélange) getrennt werden, besteht über den gesamten Bogen. Fazielle und stratigraphische Merkmale sowie die Art der Deformation ermöglichen die Korrelation der Teilprofile des südägäischen Deckenstapels und dessen Anknüpfung an die südwestliche Türkei. Die kinematische Analyse des Deckenbaus führt zu dem Bild eines sich ausbreitenden Mantel-Diapirs, an dessen geneigter Grenzfläche ein gravitativer Transport ausgelöst wurde.

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In the realm of the Southern Aegean Arc four allochthonous units are piled up above the autochthonous Cherty Limestone (Permian-Oligocene). The allochthonous units are derived from different Mesozoic to Paleogene facies zones which originally were arranged in concentric belts in the Central Aegean Sea. The nappe pile consists — from bottom to top — of neritic carbonates, pelagic carbonates and a volcano-sedimentary complex along the entire arc. These competent units are separated by incompetent members of mainly flyschoid sediments, acting as lubricants. The intercalated sediments were deformed to mélanges due to tectonic transport. Facies analysis, stratigraphy and the style of deformation lead to a correlation of type sections of the southern Aegean nappe pile and its relation to the southwestern part of Turkey. The nappe transport is caused by diapiric uplift and lateral shifting of a thermal dome. A radial gravity transport occurred on its inclined boundary plane.

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Résumé Dans la région de l'Egée méridionale le Calcaire en plaquettes, en position autochthone (Permian-Oligocène) repose sous quatre unités allochthones. Les séries allochthones proviennent de différentes zones de faciès mésozoique-paléogène qui à l'origine étaient disposées concentriquement dans l'Égée centrale. Les nappes sont constituées tout le long de l'arc entier pour des carbonates néritiques, des carbonates pélagiques et un complexe volcano-sédimentaire. Ces unités compétentes sont séparées par des formations incompétentes, notamment des sédiments flyschoides qui ont servi de lubrificant. Ces sédiments intercalés ont été déformés en mélanges par le transport tectonique. Des caractéristiques de faciès et d'ordre stratigraphique, et le style de la déformation rendent possible la corrélation entre les fractions des nappes sud-égéennes et leur rattachement au sud-ouest de la Turquie. Le transport des nappes est lié au déploiement latéral de l'enveloppe d'un dôme diapirique, qui a déclanché un transport radial, par gravité, le long de sa base inclinée.

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Diese Untersuchungen wurden im Rahmen des Schwerpunktprogrammes Geodynamik des mediterranen Raumes der Deutschen Forschungsgemeinschaft durchgeführt und gefördert. Ausgehend von einer Geländetätigkeit auf Kreta in den Jahren 1973–1975 erfolgten im Herbst 1975 Vergleichsbegehungen auf dem Peloponnes, auf Rhodos und den Kykladen. Von den Mitarbeitern des Institutes für Geologie und Paläontologie der TU Braunschweig übernahmen dankenswerterweise FrauBeddies und FrauBusch die Niederschrift des Manuskriptes sowie Übersetzungsarbeiten. HerrStosnach führte freundlicherweise die Reinzeichnung der Abbildungen und Fotoarbeiten aus.     

Geochemical processes controlling arsenic mobility in groundwater: A case study of arsenic mobilization and natural attenuation

The behavior of As in the subsurface environment was examined along a transect of groundwater monitoring wells at a Superfund site, where enhanced reductive dechlorination (ERD) is being used for the remediation of groundwater contaminated with chlorinated solvents. The transect was installed parallel to the groundwater flow direction through the treatment area. The ERD technology involves the injection of organic C (OC) to stimulate in situ microbial dechlorination processes. A secondary effect of the ERD treatment at this site, however, is the mobilization of As, as well as Fe and Mn. The concentrations of these elements are low in groundwater collected upgradient of the ERD treatment area, indicating that, in the absence of the injected OC, the As that occurs naturally in the sediment is relatively immobile. Batch experiments conducted using sediments from the site inoculated with an Fe(III)- and As(V)-reducing bacterium and amended with lactate resulted in mobilization of As, Fe and Mn, suggesting that As mobilization in the field is due to microbial processes.     

A roadmap for a dedicated Earth Science Grid platform

Due to its intensive data processing and highly distributed organization, the multidisciplinary Earth Science applications community is uniquely positioned for the uptake and exploitation of Grid technologies. Currently Enabling Grids for E-sciencE, and other large Grid infrastructures are already deployed and capable of operational services. So far however, the adoption and exploitation of Grid technology throughout the Earth Science community has been slower than expected. The Dissemination and Exploitation of GRids in Earth sciencE project, proposed by the European Commission to assist and accelerate this process in a number of different ways, had between its main goals the creation of a roadmap towards Earth Science Grid platform. This paper presents the resulting roadmap.     

Groundwater geochemistry of the Chihuahua City region in the Rio Conchos Basin (northern Mexico) and implications for water resources management

The Chihuahua City region, located in the semiarid-arid northern highlands of Mexico, has experienced intensive groundwater abstraction during the last 40 years to meet water demands in the region. A geochemical survey was carried out to investigate the evolution from baseline to modern conditions of a 130-km flow path including the El Sauz–Chihuahua–Aldama–San Diego de Alcalá regions. The research approach included the use of major chemical elements, chlorofluorocarbons and environmental isotope (¹⁸O, ²H, ¹³C and ¹⁴C) tracers. Stable isotopes indicate that groundwater evolves from the evaporation of local rainfall and surface water. Groundwater located at the lower end of the flow section is up to 6000 years old and older groundwater in the order of 9000 years BP was found in a deep well located in the upper part of the flow system, implying contribution from a neighbour basin. The background groundwater chemistry upstream of Chihuahua City results from feldspar weathering. Beyond Chihuahua City the chemical conditions are strongly modified owing to disposal of sewage from public and industrial water supplies into the Rio Chuviscar, subsequent allocation of this water to agricultural irrigation areas and direct infiltration under the river bed. As a consequence, anions like chloride and sulphate are mainly related to surface sources. Nitrate is controlled in part by sewage from public supply and industry and in part by agricultural practices. Arsenic and fluoride are related to weathering of rock formations of local mineralized ranges and subsequent enrichment of the basin-fill by magmatic processes. The results of this study have implications for groundwater management in an arid region that depends entirely on groundwater for domestic, industrial and agricultural water consumption. Copyright © 2008 John Wiley & Sons, Ltd.     

Theory of the collapsed zone at the front of a coal seam and its effect on translatory rock bursting

If the slope of the uniaxial stress–strain diagram in the post-failure regime is steep enough, it is shown, using a simplified (‘elementary’) theory, that the frontal zone of a coal seam close to a cavity may suddenly collapse. This collapse, well known from in situ, evidence, is also shown to reduce in most cases the danger of initiation or the strength of a subsequent coal mine bump.     

Die Unterschiede in den Sedimentationsvorgängen zwischen dem Autunien und Saxonien von Mittel- und Westeuropa

After a comment on the stratigraphical classification and the subdivision of Permian strata, a review on their occurrences in Central and Western Europe including the Alps is given. Within this area, the strata can be summarized to a northern, a central, and a “Verrucano” province. The Autunian (Lower Rotliegend) has been typically developed in the central province where it is best preserved. It is characterized by many different sedimentation processes the most important of which are described. They lead to the conclusion that the sediment deposition mainly took place in fresh water lakes and through fluviatile transport. On the other hand, the deposition of the Saxonian (Upper Rotliegend) took place in a much drier climate. Finally, the differences between the two types of climate are described.