Geochemical processes controlling arsenic mobility in groundwater: A case study of arsenic mobilization and natural attenuation

The behavior of As in the subsurface environment was examined along a transect of groundwater monitoring wells at a Superfund site, where enhanced reductive dechlorination (ERD) is being used for the remediation of groundwater contaminated with chlorinated solvents. The transect was installed parallel to the groundwater flow direction through the treatment area. The ERD technology involves the injection of organic C (OC) to stimulate in situ microbial dechlorination processes. A secondary effect of the ERD treatment at this site, however, is the mobilization of As, as well as Fe and Mn. The concentrations of these elements are low in groundwater collected upgradient of the ERD treatment area, indicating that, in the absence of the injected OC, the As that occurs naturally in the sediment is relatively immobile. Batch experiments conducted using sediments from the site inoculated with an Fe(III)- and As(V)-reducing bacterium and amended with lactate resulted in mobilization of As, Fe and Mn, suggesting that As mobilization in the field is due to microbial processes.     

Holocene environmental dynamics of south-eastern Brazil recorded in laminated sediments of Lago Aleixo

Environmental changes of the last 9,300 years were reconstructed by geochemical and pollen analyses of a 14-m-long, laminated sediment core from Lago Aleixo, south-eastern Brazil. Fossil pollen assemblages indicate open savannah vegetation (campo cerrado) and gallery forests until approximately 6,900 cal. BP. During that time, siderite laminae were deposited under anoxic conditions at the lake bottom. Then, increased rainfall and a shorter annual dry period allowed gallery forests and semi-deciduous forests to expand, leading to more closed cerrado vegetation. High-intensity rainfall events during this period are recorded as peaks in K and Ti concentrations. The sediment facies during this period consists of alternating layers of diatoms and minerogenic matter. C/N ratios imply that algae and perhaps soils, too, were the main contributors to sediment organic matter. Biogenic silica and δ¹³C_org variations indicate increasing primary productivity, which was related to higher nutrient flux from intensified leaching of soils, as shown by rising K/Al ratios. Around 800 cal. BP, a closed, semi-deciduous forest developed under present-day climate conditions. Slope stabilization diminished erosion processes in the catchment and caused reduced input of minerogenic matter into the basin. Human impact is evident in the topmost homogeneous sediments, as removal of the stabilizing forest cover amplified soil erosion. The continuous trend to more humid conditions during the Holocene probably reflects increased influence of the Amazon Basin as a moisture source. We conclude that the Lago Aleixo sediment archive was a sensitive recorder of environmental dynamics in tropical South America, which were mainly controlled by changes in precipitation patterns.     

Kleintektonik im Gebiet der Glarner überschiebung

Ohne Zusammenfassung     

Preface: Workshop on matter,astrophysics, gravitation,ions and cosmology—MAGIC23

We outline our experience in organizing the first edition of the Workshop on Matter, Astrophysics, Gravitation, Ions and Cosmology, held in virtual and in-person format, denominated MAGIC23, held from 6 to 10 March, 2023, in Praia do Rosa, Santa Catarina, Brazil. The event aimed to bring together leading academic scientists, professors, students, and research scholars for exchanging experiences and discuss the most recent innovations, trends, practical challenges, and experimental and theoretical solutions adopted in the investigation fields within the scope of the meeting. The workshop offered to the participants a platform for scientific and academic projects, partnerships, and presentation of high-quality research contributions describing original and unpublished results on topics related to matter, astrophysics, gravitation, ions, and cosmology.     

Stratigraphische Untersuchungen im Unterrotliegenden des Pfälzer Sattels

Ohne Zusammenfassung