Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

福建紫金山铜金矿床成矿流体演化数值模拟——混合和沸腾过程研究

利用ＣＨＩＬＬＥＲ软件模拟了紫金山铜金矿床主矿化阶段成矿流体的混合和局部减压等焓沸腾过程，模拟结果显示矿化具有低的ＨＳ＾－和Ｃａ＾２＋浓度，高的Ａｓ含量。在混全和沸腾过程中，随着温度和压力的降低，ｐＨ值和ｆＯ２逐渐降低，这是些金山铜金矿成矿流体的重要特征。     

CA-FCM方案与其它几种人工增雨评估方案的比较

对河南省12次飞机增雨作业,分别采用作业区域趋势对比双比分析评估方案、区域趋势相关回归分析方案、区域趋势协变量多元回归分析方案、浮动对比区历史回归分析方案(FCM)、以降水量为协变量的CA-FCM(Cluster-Analysis-based Floating Contro historical regression Method)方案和以降水量和整层大气可降水量为协变量的CA-FCM方案进行效果评估,均得到大于15%的相对增雨量.对结果比较分析表明:协变量由降水量和整层大气降水量两个组成的CA-FCM方案,由于采用了聚类分析提高了对比区和影响区相关系数和引入了整层大气可降水量作为协变量提高了作业区自然降水量估计值的准确性,从而比其它评估方案效果更好.     

长江下游仪征河段汊道分流属性及航道滩槽演变机制

长江下游仪征河段处于枯季潮流界的上边界,揭示其汊道分流属性及滩槽联动演变机制,对河势控制工程及深水航道工程实践具有重要意义.本研究收集了1955—2021年水文泥沙及地形等资料,在汊道分流关系及调整成因上:世业洲右汊的分流属性为枯水倾向型汊道,即低流量时期分流比大于高流量时期;1959—2021年期间,世业洲右汊分流比经历了“稳定-下降-上升”的调整过程,上游河段滩槽格局调整及流域来沙减少引起的汊道间不均衡冲刷是分流关系调整的主因;流域流量过程调整、河道崩岸等综合影响引起1959—2017年期间世业洲右汊分流比为减小态势,航道工程实施起到了调控汊道关系的功能,世业洲右汊分流比为增加态势.在滩槽联动演变关系上:仪征河段进口段以展宽为主,世业洲左汊展宽程度大于右汊,左汊河床形态变化与进口段滩槽形态的一致性关系优于右汊,即上游进口段滩槽演变、流域来沙量减少等综合作用会加速了左汊发展;2015年南京以下12.5 m深水航道二期工程建设以来,工程区域淤积且洲体完整性增强,且深槽冲刷及河槽容积增大,表明航道工程已实现汊道分流关系及滩槽调控的功能.     

内蒙古典型草原和草甸草原相对花粉产量重估

相对花粉产量（RPP）是利用地层花粉数据定量重建古植被的重要参数,但目前估算的不同地区同一植物类型的RPP多存在差异。为了解植被盖度计算方法对花粉产量的影响,本项研究利用卫星影像数字化重新计算了内蒙古锡林郭勒典型草原和乌拉盖草甸草原采样点周边100 m以外的植被数据,利用ERV模型重新估算了主要花粉类型的RPP,并运用景观重建算法（LRA）进行了检验。锡林郭勒典型草原ERV模型分析显示,ERV子模型1结合1/d距离加权法与植被-花粉数据拟合度最高,得到的相关花粉源范围（RSAP）为1470 m;以蒿属为参照种（RPP=1±0）,各科属RPP依次为藜科（0.53±0.03）、十字花科（0.17±0.01）、唐松草属（0.14±0.02）、菊科（0.09±0.01）、莎草科（0.08±0.006）、委陵菜属（0.07±0.01）、禾本科（0.050±0.003）。乌拉盖草甸草原ERV模型分析显示,ERV子模型1结合Prentice距离加权法与植被-花粉数据拟合度最高,得到的RSAP为770 m;以蒿属为参照种（RPP=1±0）,各科属RPP依次为藜科（5.85±0.58）、蓼科（5.27±0.37）、石竹科（5.15±0.47）、莎草科（4.16±0.13）、菊科（1.63±0.09）、百合科（0.49±0.08）、唇形科（0.38±0.06）、禾本科（0.200±0.004）。重估的RSAP和RPP均与首次估算时存在差异,表明植被盖度计算方法确实会影响RSAP和RPP。景观重建算法对RPP检验结果表明,卫星影像数字化估算的RPP重建的植被盖度与实际植被的相关性更高。

     

面向智慧城市的GIS框架

现有轨迹匹配方法具有一定局限性,其匹配精度无法满足车辆导航定位的需求。针对拓扑匹配方法对于起始匹配位置的依赖性,提出了顾及速度与航向信息的轨迹匹配方法。该方法综合利用速度、距离和航向约束改进起始匹配路段和起始位置的判定,并通过后续时刻车辆的正确匹配位置修正起始位置,避免了传统拓扑匹配方法中起始位置匹配错误导致的误差传递累积,提高匹配路段的准确性。同时以起始位置为基础,速度与时间信息为约束确定匹配点。为验证所提方法的有效性,选取多条复杂程度各异的路线进行实验,并与现有的几何匹配方法和拓扑匹配方法进行比较。实验结果表明,该方法在不同复杂程度的城市路网下具有良好的匹配效果,准确率可达93.53%。在匹配准确率方面优于现有的两种方法,在匹配效率方面能满足定位导航的需求。     

Effects of Enclosure on Plant and Soil Nutrients in Different Types of Alpine Grassland

Enclosure is one of the most widely used management tools for degraded alpine grassland on the northern Tibetan Plateau, but the responses of different types of grassland to enclosure may vary, and research on these responses can provide a scientific basis for improving ecological conservation. This study took one site for each of three grassland types (alpine meadow, alpine steppe and alpine desert) on the northern Tibetan Plateau as examples, and explored the effects of enclosure on plant and soil nutrients by comparing differences in plant community biomass, leaf-soil nutrient content and their stoichiometry between samples from inside and outside the fence. The results showed that enclosure can significantly increase all aboveground biomass in these three grassland types, but it only increased the 10-20 cm underground biomass in the alpine desert. Enclosure also significantly increased the leaf nutrient content of the dominant plants and contents of total nitrogen (N), total potassium (K), and organic carbon (C) in 10-20 cm soil in alpine desert, thus changing the stoichiometry between C, N and P (phosphorus). However, enclosure significantly increased only the N content of dominant plant leaves in alpine steppe, while other nutrients and stoichiometries of both plant leaves and soil did not show significant differences in alpine meadow and alpine steppe. These results suggested that enclosure has differential effects on these three types of alpine grasslands on the northern Tibetan Plateau, and the alpine desert showed the most active ecological conservation in the responses of its soil and plant nutrients.     

顾及形态特征和语义信息的双线道路识别方法

双线道路识别与提取是城市路网综合的关键。提出了一种城市双线道路提取的方法。在构建好的道路网眼的基础上,综合考虑双线道路网眼形态特征以及构成网眼路段之间的语义相似度,设计了识别双线道路网眼的综合指标。通过判断网眼综合指标确定最终的双线道路网眼,最后根据识别出的双线道路网眼提取出双线道路。实验表明,该方法能有效提取出城市道路数据中的双线道路。     

断层EDF技术在复杂断块构造研究中的应用

复杂断块构造具有断层复杂,小断层广泛发育,断层识别难度大,储层分布及连通性复杂,地震成像不清、资料品质较差等特征。对于此类问题,常规地震资料无法满足断层解释精度要求。提出了一种新的断层EDF解释性处理技术,将地震资料处理与解释融为一体,以提高资料的信噪比和断层的识别能力。断层EDF解释性处理技术是利用扩散滤波和中值倾角滤波相结合的断层增强滤波方法来提高资料的信噪比,突出断层和地层的接触关系,再在滤波后的地震资料数据体上进行分频处理,选择最佳成像频带,突出识别不同规模的断层。通过在涠洲A油田的应用,取得了良好的效果。