Three xenoliths erupted as ejecta during recent violent explosion of Stromboli volcano (Aeolian Islands) were investigated in this paper. They consist of high-temperature mineral association (cordierite, hercynite spinels, sillimanite, ±plagioclase, ±mullite, ±corundum) and abundant glass (10–70 vol.%), and may be classified as buchites. The peraluminous composition of the xenoliths, their trace element distribution and REE patterns support their origin from granulite- and amphibolite-facies metapelites of the Calabrian continental crust, which is considered the crystalline basement beneath Stromboli. Buchites have an isotopic composition comparable to that of Stromboli extrusives and significantly different from that of the Calabrian basement.
The glass is generally colourless and has a Si–Al–alkali-rich composition, except for one sample where a Fe–Mg–Ca-rich reddish-brown glass also occurs. These two kinds of glass show complicated textures where patches of reddish-brown glass are often surrounded by plagioclase and/or cordierite or forms streaks and swirls with the colourless glass. Cordierite, plagioclase and oxides have different compositions according to their position in the xenoliths. Ca-rich plagioclase (An72–95), Mg-poor cordierite (Mg-values 47–66) and Al-rich spinels are in the inner portions of the xenoliths and associated with colourless glass; on the contrary, close to the contact with the host lava or associated with coloured glass, cordierite shows higher Mg-values, Ti–Fe-bearing oxides occur and plagioclase is chemically similar to the basalt phenocrysts (An66–71).
The abundant and fresh glass and the idiomorphic shape of the high-temperature minerals suggest that the xenoliths were hold in the basaltic magma, before its extrusion, for a significant time to allow their partial or nearly complete melting and subsequent nucleation and growth of new phases. During this stage, the interaction between the anatectic liquid and the basaltic magma affected the original isotopic composition of the xenoliths and, in some cases, produced glass and mineral phases (cordierite, plagioclase and oxides) with different composition. 相似文献
General models of degradation suggest soil and nutrients are lost and conversion of rainfall into primary productivity is diminished when rangeland is degraded. These models are supported by studies on non-resilient landscapes, where loss of primary productivity also translated into loss of secondary productivity, but have not been tested on resilient landscapes. Elsewhere we showed that loss of chenopod shrubs from a landscape characterized as resilient was associated with declines in plant productivity and efficiency of conversion of rainfall into plant mass. To explore whether these differences in primary productivity translated into differences in secondary productivity, we grazed sheep at five rates of stocking for 10 years on 2000 ha of this landscape. The experiment was necessarily replicated in time not space (i.e. pseudo-replicated), which limits confident extrapolation of results to other landscapes.Productivity of sheep at all except highest rates of stocking varied little between sites where shrubs were abundant or scarce. From an animal production point of view, greater rates of stocking were unsustainable through dry years on the degraded site, but animal performance was generally unaffected on the non-degraded site, where shrubs were abundant. While these results provide evidence of economic penalties associated with degrading a resilient landscape, important ecological penalties were only partially explored. 相似文献
Summary From the early Tertiary K?lvegletscher ultramafic cumulate complex, emplaced into the Archaean basement on the west side
of the Kangerlussuaq Fjord, East Greenland, we present geochemical and isotopic data from an outcrop of finely layered dunitic
adcumulates. The dunites were deposited in a trough structure, interpreted to be a fossilized feeder channel to the K?lvegletscher
magma chamber. Detailed geochemical sampling of the trough reveals subtle cryptic compositional variations of olivines (Fo = 86.5–89.3;
Ni = 2000–2700 ppm) and chromites (Cr# = 66–80) in a stratigraphical profile perpendicular to the layering as well as relatively
large simultaneous variations of whole-rock 87Sr/86Sr ratios. The dunites are separable into sequences of normal and reverse cryptic zonations which are interpreted as resulting
from fractional crystallisation and magma chamber recharge, respectively. Up to 20% of magma chamber replenishment by high-Mg
melts is suggested. Sr-isotope compositions of the cumulates correlate with olivine compositions and suggest mixing of fractionated
and unfractionated parental melts assimilating up to 8% local basement. We propose the existence of a vigorous volcanic system
at the K?lvegletscher site in early Tertiary times, where plume-derived magmas incorporated minor amounts of local basement
and underwent fractionation and mixing in crustal chambers. Estimates of processed magma volumes during deposition of the
trough cumulates are in the range of 100–130 km3.
Received January 18, 2000;/revised version accepted December 19, 2000 相似文献
In the West Sudetes, northeastern Bohemia Massif, geochronometry provides evidence for repeated episodes of rapid cooling that contrasts sharply with an absence of structural evidence for significant tectonic exhumation by crustal extension. Instead, high-grade assemblages of the Orlica–Snieznik Complex have a regional sub-horizontal foliation and sub-horizontal lineations that trend parallel to narrow sub-vertical shear zones containing exhumed high-pressure assemblages. Mesoscopic petrofabrics combined with anisotropy of magnetic susceptibility (AMS) data from amphibolite facies to migmatitic meta-sedimentary and meta-igneous rocks reveal remarkably consistent average lineations that plunge shallowly to the SSW on both steep and sub-horizontal NNE-trending planar fabrics. The dominant SSW–NNE fabric orientation is parallel to the Bohemia–Brunia suture, which marks a major boundary along the eastern margin of the massif. The shape of the AMS ellipsoid is predominantly oblate, revealing flattened fabrics, with only local prolate ellipsoids. We envisage that the continental Brunian indentor operated as a rigid backstop and allowed the migmatized lower crustal orogenic root to be exhumed along the Bohemian margin shortly following terminal arc collision. Sub-vertical extrusion of the orogenic root was arrested in the mid-crust, where the lower ductile crust was laterally overturned at the base of rigid upper crustal blocks. Upon reaching the crustal high-strength lid the exhumed ductile mass of continental material laterally spread sub-parallel to the margin, underwent subsequent supra-Barrovian metamorphism, and quickly cooled. The application of AMS techniques to high-grade metamorphic rocks in concert with macroscopic structural observations is a powerful approach for resolving the deformation history of a terrane where visible rock fabrics can be tenuous. 相似文献
We investigated the effect of high power ultrasound, at a frequency of 19 kHz, on the survival of bacteria, phytoplankton and zooplankton, in order to obtain estimates of effective exposure times and energy densities that could be applied to design of ultrasonic treatment systems for ballast water. Efficacy of ultrasonic treatment varied with the size of the test organism. Zooplankton required only 3-9s of exposure time and 6-19 J/mL of ultrasonic energy to realize a 90% reduction in survival. In contrast, decimal reduction times for bacteria and phytoplankton ranged from 1 to 22 min, and decimal reduction energy densities from 31 to 1240 J/mL. Our results suggest that stand-alone ultrasonic treatment systems for ballast water, operating at 19-20 kHz, may be effective for planktonic organisms >100 microm in size, but smaller planktonic organisms such as phytoplankton and bacteria will require treatment by an additional or alternative system. 相似文献
Particulate matter emissions generated by agricultural field preparation and harvesting operations were measured remotely
via aerosol lidar and sampled simultaneously with a variety of aerosol point samplers in order to quantify dust plume space
and time dynamics and particulate mass and number concentrations. Data for two cotton operations (disking, harvesting) in
a flood-irrigated field in New Mexico are presented. Dust plume dynamics varied with boundary layer meteorological conditions,
especially atmospheric stability, with plume maximum height significantly lower under stable conditions. Plume tracking indicated
little change in plume area with height under unstable conditions and plume movement depended on wind speed and direction.
Particle mass distributions indicate approximately 50% of the measured PM10 mass was PM2.5, significantly higher than previously reported values, possibly due to the near-source nature of the samples collected here.
Variability in plume movement matched the variability in short-term wind fluctuations and this variability helps explain why
models that utilize long-term averages perform poorly when trying to capture plume dynamics for nonsteady sources such as
tractor operations. 相似文献
High-precision Pb isotope data and Sr–Nd–Hf isotope data are presented together with major and trace element data for samples spanning the 4.6 Ma history of volcanism at Santiago, in the southern Cape Verde islands. Pb isotope data confirm the positive Δ8/4 signature of the southern islands indicating that the north–south compositional heterogeneity in the Cape Verde archipelago has persisted for at least 4.6 Ma. The Santiago volcanics show distinct compositional differences between the old, intermediate and young volcanics, and suggest greater involvement of an enriched mantle (EM1)-like source over time. Isotopic variations in the Santiago volcanics indicate convergence towards a homogeneous EM1-like end-member and distinct temporal variations in the FOZO-like end-member. Santiago and Santo Antão (a northern island, Holm et al. 2006), show a simultaneous decrease in 208Pb/204Pb of the high 206Pb/204Pb FOZO-like source with time. Such systematic archipelago-wide variations in the FOZO-like component suggest that this component is more likely to be present as a coherent package of recycled ocean crust rather than as multiple small heterogeneities dispersed in the upwelling mantle. The temporal variations in 208Pb/204Pb reflect minor lateral variations in Th/U of this recycled ocean crust package entering the melting zone beneath the islands. The location of the EM1-like component is more equivocal. A shallow lithospheric location is possible, but this would require a coincidence between spatial compositional variations in the lithosphere (EM1 is spatially restricted to the southern islands) and flow lines in the upwelling mantle revealed by seismic anisotropy. Therefore, we favour a deeper asthenospheric mantle source for the EM1-like source. 相似文献
Chromite is a mineral with low solubility and is thus resistant to dissolution. The exception is when manganese oxides are available, since they are the only known naturally occurring oxidants for chromite. In the presence of Mn(IV) oxides, Cr(III) will oxidise to Cr(VI), which is more soluble than Cr(III), and thus easier to be removed. Here we report of chromite phenocrysts that are replaced by rhodochrosite (Mn(II) carbonate) in subseafloor basalts from the Koko Seamount, Pacific Ocean, that were drilled and collected during the Ocean Drilling Program (ODP) Leg 197. The mineral succession chromite-rhodochrosite-saponite in the phenocrysts is interpreted as the result of chromite oxidation by manganese oxides. Putative fossilized microorganisms are abundant in the rhodochrosite and we suggest that the oxidation of chromite has been mediated by microbial activity. It has previously been shown in soils and in laboratory experiments that chromium oxidation is indirectly mediated by microbial formation of manganese oxides. Here we suggest a similar process in subseafloor basalts. 相似文献