Dissolved oxygen dynamics in a eutrophic estuary,Upper Newport Bay,California

Eutrophication often causes hypoxia in estuarine and coastal systems, but the mechanisms that control hypoxic events vary among estuaries and are often difficult to discern. We monitored surface and bottom dissolved oxygen (DO) in the Upper Newport Bay (UNB), a tidally mixed estuary in southern California subject to anthropogenic nutrient loading, eutrophication and hypoxia. Our goal was to identify the environmental factors regulating DO dynamics. Six hypoxic events occurred between June and November and were associated with a combination of low solar radiation, increased freshwater discharge following precipitation, and enhanced haline stratification during reduced tidal range periods. At the head of the estuary, high macroalgal biomass and pronounced haline stratification resulted in high DO in the surface layer and low DO in the bottom layer. Oxygen-rich and oxygen-poor waters were transported down-estuary by ebb tides, resulting in DO heterogeneity throughout the UNB. Cross-wavelet analysis illustrated the down-estuary propagation of high/low DO signal correlated with the phases of diurnal photosynthetic and semi-diurnal tidal cycles.     

Clay minerals as an indicator of the accumulation of the Upper Quaternary deposits in the St. Anna Trough (Kara Sea)

This paper is devoted to the studies of clay minerals from two cores collected in the northern and central regions of the St. Anna Trough, the largest trough of the Kara Sea. The Upper Quaternary glacial, glaciomarine, and marine deposits are characterized by various contents of kaolinite, chlorite, illite, and smectite. It is established that, from older to younger deposits, the amounts of kaolinite and chlorite generally decrease, while those of illite and smectite, on the contrary, increase. A joint analysis of the distributions of clay and heavy minerals over the section allowed us to refine the position of the sources for the terrigenous matter and their temporal variability. It is shown the changes in the sources of supply were directly related to the climate changes that occurred when passing from the glacial to marine sedimentation environments.     

The coupled oceanographic–tomographic analysis and prediction system: A practical means for utilizing high frequency tomography in the world's oceans

Details are presented of a methodology that utilizes acoustic travel time information in an ocean circulation model. Recent developments of this model-oriented tomography are discussed, representing some significant improvements over earlier formulations. More accurate means of determining the arrival times of specific ray paths are detailed, along with a means of estimating possible errors in the calculated travel times. The assimilation of the observed arrival time information into an ocean model is achieved using a Kalman gain, and more advanced expressions for calculating the Kalman gain are presented. A formulation to account for errors in the stated positions of a source and receiver is also presented. It is shown that the methodology performs fairly well in reproducing observed travel time anomalies. However, the model-predicted anomalies along a specific ray path may not always track the observed anomalies for that path when assimilating multiple ray path data. Results indicate that additional work is required to determine a means of handling observed arrival time data without having prior knowledge of the magnitude of errors in the observations. Results from simulation experiments provide estimates of: (1) potential errors when the travel times for ray paths are only sampled at discreet intervals as opposed to continuously and (2) to what degree acoustic data can be expected to “correct” model-predicted fields.     

Predictive land value modelling in Guatemala City using a geostatistical approach and Space Syntax

ABSTRACT

Spatial information of land values is fundamental for planners and policy makers. Individual appraisals are costly, explaining the need for predictive modelling. Recent work has investigated using Space Syntax to analyse urban access and explain land values. However, the spatial dependence of urban land markets has not been addressed in such studies. Further, the selection of meaningful variables is commonly conducted under non-spatialized modelling conditions. The objective of this paper is to construct a land value map using a geostatistical approach using Space Syntax and a spatialized variable selection. The methodology is applied in Guatemala City. We used an existing dataset of residential land value appraisals and accessibility metrics. Regression-kriging was used to conduct variable selection and derive a model for spatial prediction. The prediction accuracy is compared with a multivariate regression. The results show that a spatialized variable selection yields a more parsimonious model with higher prediction accuracy. New insights were found on how Space Syntax explains land value variability when also modelling the spatial dependence. Space Syntax can contribute with relevant spatialized information for predictive land value modelling purposes. Finally, the spatial modelling framework facilitates the production of spatial information of land values that is relevant for planning practice.     

Evaluating the Global Environment Facility: A goodwill gesture or a serious attempt to deliver global benefits?

Over its 17 years, the UN's Global Environment Facility (GEF) has allocated US $7.5 billion intended to develop and implement scientifically and socially credible solutions to key global environmental problems such as climate change, biological diversity loss and degradation of transboundary aquatic systems. We studied 906 GEF projects to analyse the challenges that it is facing in delivering solutions that are likely to be sustainable in the long-term. The research included desk reviews of relevant documents and follow-up interviews with a wide range of stakeholders. Some of the challenges the GEF faces are deeply rooted in temporal and spatial mismatches of scale between human economies and their environmental consequences and the strongly sectoral way current society is managed. We conclude that the GEF obtained impressive results for tackling problems of limited complexity and easily quantified benefits but progress is slower on more complex and less tangible problems impeding sustainable development. Potentially, the GEF could enable adaptive management through a ‘learning by doing’ process, transforming it into an innovative mechanism for delivering global benefits. Continued emphasis on ‘easy wins’ would not allow it to achieve this goal.     

Very high electrical conductivity beneath the Münchberg Gneiss area in Southern Germany: implications for horizontal transport along shear planes

New magnetotelluric data from the Münchberg Gneiss complex in Southern Germany reveal a zone of extremely high electrical conductivity. 1-D modelling of the data is justified in the period range 0.01 to 10  s. At least three layers are required to explain the steepness of the apparent resistivity curves, and the best-fitting models comprise four layers with successively higher conductivities. The layers of highest conductivity at depths between 2.2 and 3.6  km correlate with pronounced bands of high seismic reflectivity (profile DEKORP 85-4N). The Münchberg complex is today widely recognized as a tectonic klippe, consisting of rocks whose metamorphic and stratigraphic order is inverted rather than overturned. The material was transported into its present position by predominantly horizontal tectonic forces along shear zones. We interpret the high conductivity and high reflectivity as remnants of this transport process.     

Stable calcium isotopic compositions of Hawaiian shield lavas: Evidence for recycling of ancient marine carbonates into the mantle

We report high-precision ⁴⁴Ca/⁴⁰Ca measurements (2σ_m < 0.06‰) of Hawaiian shield stage tholeiites. Our data reveal ∼0.3‰ variation in their ⁴⁴Ca/⁴⁰Ca, which comprises ∼20% of the ⁴⁴Ca/⁴⁰Ca variation observed in global carbonates. The ⁴⁴Ca/⁴⁰Ca variation is correlated with Sr/Nb and ⁸⁷Sr/⁸⁶Sr, and this pattern is best explained by adding up to 4% ancient carbonate into the Hawaiian plume. Mass-balance calculations show that up to 40% of the Ca budget and 65% of the Sr budget in some Hawaiian (Makapuu-stage Koolau) lavas are derived from recycled carbonates. Our finding demonstrates, for the first time with the application of Ca isotopes, that ancient recycled carbonates are important components of mantle plumes which feed some of the largest terrestrial volcanoes. Thus, recycling of carbonates into the mantle is an essential part of the global Ca and C cycles.     

Evaluation of the leukoproliferative response of English sole (Pleuronectes vetulus) as a biomarker for immune dysfunction

The leukoproliferative (LP) response of splenic leukocytes from the marine benthic fish, English sole (Pleuronectes vetulus), stimulated with the mitogens lipopolysaccharide (LPS), concanavalin A (Con A), and pokeweed mitogen (PWM) was examined as a biomarker of immunotoxic effects. English sole were exposed to an organic-solvent extract of a sediment contaminated with polycyclic aromatic compounds (PACs) or placed on a reference sediment modified with the PAC contaminated sediment. For both treatments, English sole had an augmented LP response to Con A, no significant change in the response to LPS, and the LP response to PWM showed no consistent relationship to exposure to PACs. In a field study, English sole from a contaminated site had a significantly augmented LP response to Con A and PWM. Fish from a non-urban site also had an augmented LP response to Con A and to LPS relative to fish from another non-urban reference site. Overall, the results demonstrated that although the LP response in splenic leukocytes of English sole to Con A was linked to contaminant exposure, the LP response to Con A did not exhibit high specificity as an indicator of chemical contaminant exposure. However, the concerted use of Con A, LPS, and PWM allowed for identification of apparent chemical-contaminant induced alterations of the LP response in English sole from an urban area of Puget Sound.