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921.
The Earth’s gravity field observed by the Gravity Recovery and Climate Experiment (GRACE) satellite mission shows variations due to the integral effect of mass variations in the atmosphere, hydrosphere and geosphere. Several institutions, such as the GeoForschungsZentrum (GFZ) Potsdam, the University of Texas at Austin, Center for Space Research (CSR) and the Jet Propulsion Laboratory (JPL), Pasadena, provide GRACE monthly solutions, which differ slightly due to the application of different reduction models and centre-specific processing schemes. The GRACE data are used to investigate the mass variations in Fennoscandia, an area which is strongly influenced by glacial isostatic adjustment (GIA). Hence the focus is set on the computation of secular trends. Different filters (e.g. isotropic and non-isotropic filters) are discussed for the removal of high frequency noise to permit the extraction of the GIA signal. The resulting GRACE based mass variations are compared to global hydrology models (WGHM, LaDWorld) in order to (a) separate possible hydrological signals and (b) validate the hydrology models with regard to long period and secular components. In addition, a pattern matching algorithm is applied to localise the uplift centre, and finally the GRACE signal is compared with the results from a geodynamical modelling. The GRACE data clearly show temporal gravity variations in Fennoscandia. The secular variations are in good agreement with former studies and other independent data. The uplift centre is located over the Bothnian Bay, and the whole uplift area comprises the Scandinavian Peninsula and Finland. The secular variations derived from the GFZ, CSR and JPL monthly solutions differ up to 20%, which is not statistically significant, and the largest signal of about 1.2 Gal/year is obtained from the GFZ solution. Besides the GIA signal, two peaks with positive trend values of about 0.8 Gal/year exist in central eastern Europe, which are not GIA-induced, and also not explainable by the hydrology models. This may indicate that the recent global hydrology models have to be revised with respect to long period and secular components. Finally, the GRACE uplift signal is also in quite good agreement with the results from a simple geodynamical modelling.  相似文献   
922.
Monitoring Continental Surface Waters by Satellite Altimetry   总被引:4,自引:1,他引:3  
The monitoring of continental water stages is a requirement for meeting human needs and assessing ongoing climatic changes. However, regular gauging networks fail to provide the information needed for spatial coverage and timely delivery. Although the space missions discussed here were not primarily dedicated to hydrology, 18 years of satellite altimetry have furnished complementary data that can be used to create hydrological products, such as time series of stages, estimated discharges of rivers or volume change of lakes, river altitude profiles or leveling of in situ stations. Raw data still suffer uncertainties of one to several decimeters. These require specific reprocessing such as waveform retracking or geophysical correction editing; much work still remains to be done. Besides, measuring the flow velocity appears feasible owing to SAR interferometer techniques. Inundated surfaces, and the time variations of their extent, are currently almost routinely computed using satellite imagery. Thus, the compilation of the continuous efforts of the scientific community in these various investigative directions, such as recording from space the discharges of rivers or the change in water volume stored in lakes, can be foreseen in the near future.  相似文献   
923.
This article deals with the following two questions. Are acoustic measurements in running waters appropriate for a highly resolved investigation of the bedload transport? Which characterizations of the bedload regarding mass and shape are possible via the acoustic signals? The signals were recorded by means of data recorders (Tascam Inc. DAP1 Portable Data Recorder) and hydrophones (International Transducer Corp. ITC‐4001 A). The ITC‐4001 is a shallow water omnidirectional transducer containing a flexural disc transducer utilizing Channelite‐5400 ceramics mounted in a rugged corrosion‐resistant housing. These hydrophones were screwed onto the bottom side of stainless steel plates, serving as a contact surface for the bedload in motion above them. After more than 100 series of tests in the laboratory, which indicated the basic relations between the dimension, shape and weight of the bedload and the resulting signal, field tests of the measuring system were conducted. By artificially produced flood waves in the small brooks Riverisbach, Olewiger Bach and by a winter flood wave in the River Moselle, it is possible to elaborate similar structures of the signal course of the bedload movement. The highest transport rates can be observed at the beginning of the increasing limbs and behind the peaks of the waves. At the beginning of the waves, the increasing transport power of the water and the loose material can be considered as the cause for this result. The high stream velocity behind the wave peaks explains the increase in the bedload transport so that material from the channel beds is unfastened and will be mobilized. The characterization of the bedload regarding the shape and mass is still limited regarding the field measurements and could be solved only for homogeneous grain sizes and single stones under laboratory conditions. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
924.
A series of numerical experiments for data assimilation with the Ensemble Kalman Filter (EnKF) in a shallow water model are reported. Temperature profiles measured at a North Sea location, 55°30ˊ North and 0°55ˊ East (referred to as the CS station of the NERC North Sea project), are assimilated in 1-D simulations. Comparison of simulations without assimilation to model results obtained when assimilating data with the EnKF allows us to assess the filter performance in reproducing features of the observations not accounted for by the model. The quality of the model error sampling is tested as well as the validity of the Gaussian hypothesis underlying the analysis scheme of the EnKF. The influence of the model error parameters and the frequency of the data assimilation are investigated and discussed. From these experiments, a set of optimal parameters for the model error sampling are deduced and used to test the behavior of the EnKF when propagating surface information into the water column.  相似文献   
925.
Thallium (Tl) is a rare element of high toxicity. Sediments sampled in three representative locations near industries utilizing Tl‐containing raw materials from the Pearl River Basin, China were analyzed for their total Tl contents and the Tl contents in four sequentially extracted fractions (i.e., weak acid exchangeable, reducible, oxidizable, and residual fraction). The results reveal that the total Tl contents (1.25–19.1 µg/g) in the studied sediments were slightly high to quite high compared with those in the Chinese background sediments. This indicates the apparent Tl contamination of the investigated sediments. However, with respect to the chemical fractions, Tl is mainly associated with the residual fraction (>60%) of the sediments, especially of those from the mining area of Tl‐bearing pyrite minerals, indicating the relatively low mobility, and low bioavailability of Tl in these sediments. This obviously contrasts with the previous findings that Tl is mainly entrapped in the first three labile fractions of the contaminated samples. Possible reasons were given for the dominating association of Tl with the residual fraction (>95%) of the mining area sediments. The significant role of certain K‐containing silicates or minerals of these sediments on retaining Tl in the residual fraction, discovered by this study, provides a special field of research opportunity for the Tl‐containing wastewater treatment.  相似文献   
926.
The documentation and management of information concerning geological sites are important activities in all the steps of the geoheritage conservation and its day-to-day management. This documentation is mostly available on the web; it includes varied types of data such as pictures, scientific publications, news, and blog articles. In order to ensure the efficient management of the geoheritage resources, scientists and people involved in the promotion of the geoheritage and geotourism should have access to this documentation and kept updated of the most recent and relevant information. In this study, we propose the development of a web information monitoring system that automates the search and the collection of different types of documents related to the Algerian geosites available on the web. It is designed as a tool that continuously browses the web using the most popular search engines and then disseminates the results to the users through periodic newsletters. This proposed system will also serve to chronologically organize all the pictures of geosites gathered from the web and thus in order to study the evolution of Algerian geosites over time. For this purpose, we use one of the crowdsourcing methods in the field of knowledge management that is games with a purpose (GWAP). The idea here is to involve people in sorting pictures of geosites through a playful interface. The results obtained show that this system is a valuable tool that can assist geoscientists and decision makers in enhancing the geoheritage.  相似文献   
927.
The chemical potential of oxygen (µO2) in equilibrium with magnesiowüstite solid solution (Mg, Fe)O and metallic Fe has been determined by gas-mixing experiments at 1,473 K supplemented by solid-cell EMF experiments at lower temperatures. The results give:
where IW refers to the Fe-"FeO" equilibrium. The previous work of Srecec et al. (1987) and Wiser and Wood (1991) agree well with this equation, as does that of Hahn and Muan (1962) when their reported compositions are corrected to a new calibration curve for lattice parameter vs. composition. The amount of Fe3+ in the magnesiowüstite solid solution in equilibrium with Fe metal was determined by Mössbauer spectroscopy on selected samples. These data were combined with literature data from gravimetric studies and fitted to a semi-empirical equation:
These results were then used to reassess the activity-composition relations in (Mg, Fe)2SiO4 olivine solid solutions at 1,400 K, from the partitioning of Mg and Fe2+ between olivine and magnesiowüstite in equilibrium with metallic Fe experimentally determined by Wiser and Wood (1991). The olivine solid solution is constrained to be nearly symmetric with , with a probable uncertainty of less than ±0.5 kJ/mol (one standard deviation). The results also provide a useful constraint on the free energy of formation of Mg2SiO4.Editorial responsibility: B. Collins  相似文献   
928.
Variously colored gem-quality topazes from Ouro Preto, Minas Gerais, Brazil, were studied by optical absorption spectroscopy and photoluminescence methods. In the near infrared range (750–2500 nm) the absorption spectra display an identical pattern of narrow intense absorption lines caused by overtones and combination vibrations of OH groups, which do not relate to the coloration of the topazes studied. Their colors were found to be caused by combination of three sets of absorption features, (1), (2), and (3) in the visible and near-UV range, which are due to different color center. (1) denotes a pair of broad split bands with maxima 18 000 and 25 000 cm–1 caused by electronic spin-allowed dd transitions of Cr3+ ions. They cause a light rose to deep violet color and characteristic pleochroism of Cr3+-containing topazes. Photoluminescence evidences of at least three different types of Cr3+ complexes which, most probably, differ by ligand surroundings, O4F2, O4F(OH) and O4(OH) (2) Corresponds to the intense weakly polarized UV absorption edge. Two different parts, the thermally stable one, caused by ligand-to-metal charge transfer, and the thermally unstable one, caused by some defect center(s), contribute to the edge. (3) denotes a system of two broad unstructured bands with maxima around 19 000 cm–1 (X>Y Z) and 24 000 cm–1 (Y Z X). They cause the unique orange color and characteristic pleochroism of Brazilian Imperial topazes. Combinations of (1) and (3) absorption features cause various yellow-rose colors of the samples. Investigations of natural irradiated and thermally treated topazes show that the color centers (1) and (3) transform to each other at annealing and X- or gamma irradiation. The color of natural orange-red Imperial topazes is assumed to be caused by Cr4+, stabilized by other impurity ions and/or defect irradiation EPR centers. At T=300 °C Cr4+ reduces to Cr3+, the color of Imperial topazes changes to pale rose, caused by spin-allowed bands of Cr3+. In artificially irradiated crystals the (3)-center, Cr4+, may be induced according to the reaction 2Cr3+ Cr4+ + Cr2+, which involves chromium pairs in adjacent Al sites of the structure. Such artificially induced color is unstable at room temperature and in daylight. The process of the decay of (3)-centers may be described as a recombination Cr4++Cr2+ 2Cr3+ that results in vanishing of the (3)-bands accompanied by the appearance or increase in Cr3+ dd bands, the original orange color turning to a pale rose.  相似文献   
929.
We describe the ground segment, pre-launch operations concepts, and data products supporting the SOHO mission. Our goal is threefold: first, we provide a historical view of the design and development of the systems described here, as a background perspective to those who will use the system and those who may build such systems for future missions. Second, because we hope that many researchers from the solar and space physics communities will visit these facilities during the mission, we provide an overview for the benefit of the end-user. We anticipate that visitors to GSFC may plan observations for one or more of SOHO's complement of instruments, and such researchers may use the facilities to analyze data gathered by the SOHO instruments. Third, we present the working plan for investigators with groundbased or other spacebased instruments to collaborate with SOHO.  相似文献   
930.
Abstract A field investigation is presented of the strewnfield of the mesosiderite Vaca Muerta, originally found in 1861. The area, 11.5 km long, 2.1 km wide, is located about 60 km southeast of Taltal, Chile, in the Atacama Desert. It has yielded 80 meteorites with a total mass exceeding 3782 kg. Most fragments were found in an undisturbed state, but some had been broken by prospectors. The present studies, in connection with historical records, indicate that the original mass of Vaca Muerta exceeded 6 metric tons. One impact feature, somewhat modified by man, consists of a 10.5-m diameter, 1.7-m deep hole, without an uplifted rim. Small masses were scattered up to 85 m from the hole.  相似文献   
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