A new approach to interpreting Rock-Eval S2 and TOC data for kerogen quality assessment

A simple method for application in source potential mapping is used to assess the original oil and gas potentials in source rock horizons based upon Rock-Eval potential (S₂) and total organic carbon (TOC) values. The method assumes that kerogens consist of mixtures of end-members with assigned hydrogen index values. Based on suggested algorithms, the average amounts of oil-prone, gas-prone and inert organic material over source rock intervals are determined in TOC units. The method uses regression lines from plots of remaining hydrocarbon potentials (S₂) versus total organic carbon (TOC), and “quick-look” transparent overlays are used to read the appropriate kerogen mixture.Mineral matrix effects during pyrolysis, when strong, can cause erroneous results. This effect which occurs for oil-prone kerogens and adsorptive minerals can cause problems particularly for lean samples (S₂ = 0–3 mg HC/g rock) whilst the errors for richer samples are less.The method is applied on three sections of Upper Jurassic organic-rich rocks from the Danish North Sea sector, which are at different maturity stages. One of these sections is dominated by gas-prone material, one is dominated by oil-prone material and the third section contains a mixture of oil- and gas-prone material.The method has been compared with other methods that split kerogens in oil and gas generating potential and has given reasonable results.Experience using the method and a presented example suggest that sedimentological, system tract information may be derived from S₂ to TOC cross-plots. A constructed modelling example suggests that the end-member concept used in this approach may be used in forward type source rock prediction models when combined with sedimentological models. The resulting S₂–TOC plots can be used in order to check the forward modelling results against observed values.     

The inner core and the geodynamo

Using energy and entropy constraints applicable to the Earth's core, the heat flow at the core–mantle boundary (CMB) needed to sustain a given total dissipation in the core can be computed. Reasonable estimates for the present Joule dissipation in the core gives a present heat flow of 6 to 10 TW at the CMB. Palaeointensity data acquired from rocks younger than 3.5 Ga provide support that the Joule dissipation in the core before inner core crystallization was between today's value and four times lower than today. Prior to inner core crystallization (around 1 Ga), the magnetic field was maintained by thermal convection driven by core cooling, and our calculations of the two extreme cases predict that the heat flow at the CMB at that time was either 14 to 24 TW in the case of constant dissipation, or essentially the same as today in the lower field intensity case.     

Syndeformational recrystallization – dynamic or compositionally induced?

Dynamic recrystallization in the strict sense of the term is the reconstitution of crystalline material without a change in chemical composition, driven by strain energy in the form of dislocations. Driving potentials additional to internal strain energy may contribute to the recrystallization of naturally deformed minerals, which form solid solutions such as feldspar, amphiboles and pyroxenes, if they change their composition during recrystallization. To estimate the relative importance of these driving potentials, the chemical composition of porphyroclasts and recrystallized grains of plagioclase, clinopyroxene and hornblende have been investigated in samples from a high grade shear zone of the Ivrea Zone, Italy. The plagioclases show two different recrystallization microstructures: bulging recrystallization at grain boundaries and discrete zones of recrystallized grains across porphyroclasts probably involving fracturing. Deformation took place under amphibolite facies conditions on a retrograde P,T-path. Porphyroclast and recrystallized compositions from bulging recrystallization microstructures differ only in their Or-content and yield a ΔG between mean host grain and mean recrystallized grain composition at fixed P,T-conditions of approximately 5 Joules/10⁻⁴ m³. Extreme compositional variations yield approximately 60 J/10⁻⁴m³. The increase of free energy due to dislocations calculated for common glide systems in plagioclase are on the order of 100 Joules/10⁻⁴m³ for high values of dislocation densities of 10¹⁴m⁻². Thus, the effect of chemically induced driving energies on grain boundary velocity appears small for mean compositions but may be as great as that of deformational energies for larger chemical differences. In the other type of microstructure, porphyroclasts and recrystallized grains in discrete zones differ in their anorthite content. The maximum ΔG induced by the compositional disequilibrium is on the order of 100 J/10⁻⁴m³. This maximum value is of the same magnitude as the ΔG derived from high dislocation densities of 10¹⁴ m⁻². The resulting combined ΔG is approximately twice as high as for deformational ΔG alone, and heterogeneous nucleation may become a feasible recrystallization mechanism which is evident from the microstructures. The recrystallization mechanism depends on the nature of the driving potential. Grain boundary migration (GBM) and heterogeneous nucleation can release Gibbs free energy induced by compositional disequilibrium, whereas this is not likely for subgrain rotation. Therefore, only GBM and heterogeneous nucleation may link metamorphism and deformation, so that syndeformational recrystallization may represent a transitional process ranging from dynamic recrystallization to metamorphic reaction. Received: 8 July 1996 / Accepted: 17 November 1997     

L'escarpement de faille de la Têt est-il le résultat de la tectonique active Plio-Pléistocène ou d'une exhumation Pléistocène ?

The Têt Fault looks like an active fault. Its activity, attested for Pliocene, remains discussed for Pleistocene. We propose a new scenario of evolution for the Têt Fault, highlighting the importance of Pleistocene exhumation processes. It is based on a relationship between morphology and basin filling. During Pleistocene, the fault activity is weak and vertical displacements seem to have no considerable impact on the drainage features. This study concludes that Pliocene offset may also be reduced: the fault activity generating relief is anterior to Pliocene. To cite this article: J.-M. Carozza, S. Baize, C. R. Geoscience 336 (2004).     

Premiers résultats d'une étude géophysique sur le flanc nord des glissements de Storegga (Norvège)

The Storegga slides, off Norway, are among the largest submarine slides ever known on a continental slope. The HYDRATECH cruise on N/O Le Suroît aimed at a high-resolution survey of an area at the northern boundary of the slides. This survey images in great detail the bottom simulating reflector (BSR) extent and properties, the various fluid escape structures and the sediment deformations. The combination and the quality of the data help to understand the still poorly constrained relationships between fluid escapes, gas hydrates and slope stability in the survey area. To cite this article: H. Nouzé et al., C. R. Geoscience 336 (2004).     

Spectral analysis of geomagneticPc3 pulsations recorded at Budkov and Niemegk

Summary The dependence of the individual parameters of geomagnetic Pc3 pulsations, of their frequencies, amplitudes, phases, flattening of their polarization ellipses, the orientation of their major axis and the sense of rotation of the disturbance vector, are determined from the records made at the Budkov and Niemegk Observatories. Also their diurnal variations at both stations and the correlation of the numerical values between both stations are given.     

Siting criteria for heat extraction from hot dry rock; Application to Switzerland

For selecting possible hot dry rock extraction sites for geothermal energy applications, the following criteria have been considered: (i) depth to the crystalline basement, (ii) temperatures at depth, (iii) pattern of regional stress field and (iv) natural permeability (=degree of fracturing) of basement rocks. A contour map of the basement topography is presented. From outcrops at the nothern border of Switzerland (crystalline rocks of the Black Forest massif, mainly granites and gneisses of Hercynian age) the basement dips gently toward the SE under the Mesozoic and Tertiary sediments of the Molasse Basin and reaches its maximum depth (7 km) underneath the front of the Alps. Some 30 km further SE the basement rocks appear at the surface (Aar- and Gotthard-massif, Penninic units), where they are deformed and fractured to a great extent. Temperature-depth profiles have been obtained by model calculations. Locally increased heat product on (in granite batholiths) at the base of the Molasse Basin, combined with the blanketing effect of the overlying sediments, could raise the temperatures to 150–170°C at a depth of 5 km. According to earthquake fault-plane solutions (P-axes) the regional stress field in the area of the Swiss Alps and in its northern Foreland is characterized by the maximum horizontal compression oriented N(150±20)°E in the upper crust.In situ stress determinations (overcoring experiments) show that considerable excess horizontal compressive stress is present in the Alpine crust (up to 200 bar). The deep Alpine tunnels exhibited considerable fracturing of crystalline rocks at depths greater than 1–2 km. Information about the degree of fracturing has also been obtained by refraction profiles. The velocitydepth functions show lower than normal velocities in the uppermost 1.5 km, indicating that the rocks there are fractured. A 30–40 km wide region, running along the axis of the Molasse Basin (which coincides with the majority of the population and most of the industry of Switzerland) would provide the best hot dry rock sites.Paper presented at the Second NATO-CCMS Meeting on Dry Hot Rock Geothermal Energy, 28–30 June 1977, Los Alamos, New Mexico, USA. Contribution No. 198, Institute of Geophysics ETH Zurich.