Fragment-collision model for compound chondrule formation: Estimation of collision probability

We propose a new scenario for compound chondrule formation named as “fragment-collision model,” in the framework of the shock-wave heating model. A molten cm-sized dust particle (parent) is disrupted in the high-velocity gas flow. The extracted fragments (ejectors) are scattered behind the parent and the mutual collisions between them will occur. We modeled the disruption event by analytic considerations in order to estimate the probability of the mutual collisions assuming that all ejectors have the same radius. In the typical case, the molten thin () layer of the parent surface will be stripped by the gas flow. The stripped layer is divided into about 200 molten ejectors (assuming that the radius of ejectors is 300 μm) and then they are blown away by the gas flow in a short period of time (). The stripped layer is leaving from the parent with the velocity of depending on the viscosity, and we assumed that the extracted ejectors have a random velocity Δv of the same order of magnitude. Using above values, we can estimate the number density of ejectors behind the parent as . These ejectors occupy ∼9% of the space behind the parent in volume. Considering that the collision rate (number of collisions per unit time experienced by an ejector) is given by Rcoll=σcollneΔv, where σcoll is the cross-section of collision [e.g., Gooding, J.K., Keil, K., 1981. Meteoritics 16, 17-43], we obtain by substituting above values. Since most collisions occur within the short duration () before the ejectors are blown away, we obtain the collision probability of Pcoll∼0.36, which is the probability of collisions experienced by an ejector in one disruption event. The estimated collision probability is about one order of magnitude larger than the observed fraction of compound chondrules. In addition, the model predictions are qualitatively consistent with other observational data (oxygen isotopic composition, textural types, and size ratios of constituents). Based on these results, we concluded that this new model can be one of the strongest candidates for the compound chondrule formation. It should be noted that all collisions do not necessarily lead to the compound chondrule formation. The formation efficiency and the future works which should be investigated in the forthcoming paper are also discussed.     

D/H fractionation factors between serpentine and water at 100° to 500°C and 2000 bar water pressure,and the D/H ratios of natural serpentines

D/H fractionation factors between serpentine (clinochrysotile) and water were experimentally determined to be: 1000 In α_ser-w = 2.75 × 10 ⁷/T² ? 7.69 × 10⁴/T + 40.8 in the temperature range from 100 to 500°C. The present results do not support the semi-empirical fractionation factors employed by Wenner and Taylor [1] for the interpretation of δD values of natural serpentines. About 100 serpentines from the Japanese Islands have δD values from ?110 to ?40‰ SMOW, with antigorite being from ?40 to ?60‰. The results are in accord with the two conclusions by Wenner and Taylor [1,2], that is, the presence of a latitude ?δD correlation and the more uniform and higher δD values of antigorite than chrysotile and lizardite.According to the present fractionation factors, almost none of the continental lizardite-chrysotile serpentines could have formed at a temperature below 500°C under equilibrium with fluids of δD values similar to the present-day local meteoric waters. The fluid responsible for oceanic serpentinization could be either a mixture of oceanic and magmatic water or oceanic water alone. However, full interpretation of the δD values of natural serpentines should wait until kinetic behaviors of hydrogen isotopes in serpentinization are better understood.     

Fugacity-concentration relationship of dilute hydrogen in water at elevated temperature and pressure

The fugacity vs. concentration ratio(Y) of dilute hydrogen dissolved in water was determined at temperatures below 500°C and pressures below 1000 bar by measuring H₂ concentrations in magnetite-hematite-water and palladium hydride-water systems. Combining these results with reported solubility data of H₂ in water and with the Shaw's expression for the activity-composition relationship of H₂H₂O mixture at higher temperatures, theP-T-Y diagram was constructed over theP-T range below 900°C and 1000 bar.     

Effect of occurrence rate of acoustic emissions on their statistical behavior

The parameterm in Ishimoto-Iida's relation was investigated for acoustic emissions (AEs) occurring in rock samples under uniaxial compression. In the experiment, we found: 1) The large AEs are counted without serious error but the number of small AEs is systematically underestimated at high AE rates, 2) the frequency distribution of maximum AE amplitudes becomes nonlinear in logarithmic scale with increasing AE rate, and 3) there exists a strong negative correlation betweenm-value and AE rate. The miscount of small AEs was interpreted as due to overlap of the large and small AEs. We call the miscount masking effect. A statistical analysis based on the masking effect showed that them-value decreases more effectively as the AE rate increases, and thus the masking effect is a possible origin both for the nonlinear frequency distribution of maximum AE amplitudes and for the negative correlation ofm-value with AE rate. We emphasize that one should be careful of the masking effect to examine correctly the change, ofm-value. In order to eliminate the masking effect, AEs should be measured by a measurement system with low sensitivity. Even if the masking effect is eliminated, them-value decreases before the main fracture of a rock sample. Them-value is a key parameter to predict the main fracture.     

Formation of bipolar flow by the stellar wind embeded in molecular disk

The interaction of the isotropic stellar wind with the rotating isothermal cloud surrounding the young star is investigated. The density distribution of the cloud is taken as that for the equilibrium state of the rotating isothermal cloud modified by adding the rarefied interstellar gas in the polar region. The development of the shock envelope and the structure of the shell induced by the stellar wind are obtained. It is shown that the envelope of the shock front elongates and opens to the polar direction with half opening angle of about 20 degrees resulting the bipolar flow which is able to reproduce well the observed properties for the outflow in the bipolar sources.     

慢地震与深部不连续颤动和慢滑事件同时发生

我们对日本西南部南海俯冲板块界面过渡带发生的超低频地震进行报道。由矩震级为3.1～3.5的超低频地震引起的地震波显示其卓越长周期约为20s。超低频地震活动伴随深源低频颤动和慢滑事件同时发生,并随之移动。慢地震一直被认为会增加向上倾斜的大型逆冲地震断裂带上的应力,而这3种现象的同时发生提高了人们对慢地震的探测和特性鉴定水平。     

Enhanced predictions of wave impact pressure by improved incompressible SPH methods

A new criterion is proposed for a more efficient assessment of free-surface particles in a particle-based simulation. Enhanced wave impact simulations are carried out by improved Incompressible SPH (ISPH) methods. The first improvement is the same as that in the Corrected ISPH (CISPH; [Khayyer A, Gotoh, H, Shao SD. Corrected incompressible SPH method for accurate water-surface tracking in breaking waves, Coast Eng 2008; 55 (3): 236–250]) method and is proposed for the improvement of momentum conservation. The second improvement is achieved by deriving and employing a higher order source term based on a more accurate differentiation to obtain a less fluctuating and more accurate pressure field. The enhanced performance of improved ISPH methods is demonstrated through the simulation of several fluid impact simulations in comparison with the experimental data and simulation results by other numerical methods.     

The Tiger Sulfide Chimney,Yonaguni Knoll IV Hydrothermal Field,Southern Okinawa Trough,Japan: The First Reported Occurrence of Pt–Cu–Fe‐Bearing Bismuthinite and Sn‐Bearing Chalcopyrite in an Active Seafloor Hydrothermal System

A sulfide chimney ore sampled from the flank of the active Tiger vent area in the Yonaguni Knoll IV hydrothermal field, south Okinawa trough, consists of anhydrite, pyrite, sphalerite, galena, chalcopyrite and bismuthinite. Electron microprobe analysis indicates that the chalcopyrite contains up to 2.4 wt% Sn, whereas bismuthinite contains up to 1.7 wt% Pt, 0.8 wt% Cu and 0.5 wt% Fe. The Sn‐rich chalcopyrite and Pt–Cu–Fe‐bearing bismuthinite are the first reported occurrence of such minerals in an active submarine hydrothermal system. The results confirm that Sn enters the chalcopyrite as a solid solution towards stannite by the coupled substitution of Sn⁴⁺Fe²⁺ for Fe³⁺Fe³⁺, whereas Pt, Cu and Fe enter the bismuthinite structure as a solid solution during rapid nucleation. The fluid inclusions homogenization temperatures in anhydrite (220–310°C) and measured end‐member temperature of the vent fluids on‐site (325°C) indicate that Sn‐bearing chalcopyrite and Pt–Cu–Fe‐bearing bismuthinite express the original composition of the minerals that precipitated as metastable phases at a temperature above 300°C. The result observed in this study implies that sulfides in ancient volcanogenic massive sulfide deposits have similar trace element distribution during nucleation but it is remobilised during diagenesis, metamorphism or supergene enrichment processes.     

Advanced Micro-XRF Method to Separate Sedimentary Rhythms and Event Layers in Sediments: Its Application to Lacustrine Sediment from Lake Suigetsu,Japan

Event-related sedimentary layers, which are deposited occasionally due to volcanic eruptions, earthquakes or heavy rains, are often contained in the rhythmical sequences of lacustrine and marine sediments. We have developed an analytical method for separating the sedimentary rhythms and the event layers identified using the scanning X-ray analytical microscope (SXAM) and obtained sequential profiles of seven elements Al, Si, K, Ca, Ti, Mn, and Fe in the lacustrine sediment from Lake Suigetsu, Japan. Two types of event layers could be detected from the elemental composition of 33 layers of sediment: three known volcanic ash layers and 30 clay layers containing 12 turbidites. The recurrence interval of the latter, which may potentially be initiated and archived by locally important earthquakes, is estimated to be an average of 640 ± 160 years by using Sompi event analysis (SEA) based on an autoregressive (AR) model. After removing those portions that represented event layers from the elemental profiles, we obtained event-removed (ER) temporal profiles based on the tephrochronology of the three volcanic ash layers. The ER temporal profiles of manganese and iron, probably representing the siderite content, showed a millennial-scale variation in the Holocene that corresponded well with ice-rafting events in the North Atlantic.