Mesoscale eddy effects on temporal variability of surface chlorophyll a in the Kuroshio Extension

We investigated the relationship between chlorophyll a (Chl-a) concentrations estimated from satellite observations and the activity of eddies in the Kuroshio Extension region. High (low) area-averaged Chl-a concentrations were frequently observed in the core of cyclonic (anticyclonic) eddies. Such relationships between Chl-a concentrations and eddy cores were not frequently observed in the southern part of the recirculation gyre, and advection of background meridional gradient of Chl-a by eddy-edge currents accounted for Chl-a spatial variability. Decadal-scale changes of Chl-a concentrations around the Kuroshio Extension were strongly affected by eddy activity and transport but not by large-scale near-surface isopycnal heaving. We also found that decadal changes of nutrient concentrations near the main stream could affect Chl-a concentrations in the southern part of the recirculation gyre via southward transport of eddies and mean flow.     

Sequentially sampled gas hydrate water,coupled with pore water and bottom water isotopic and ionic signatures at the Kukuy mud volcano,Lake Baikal: ambiguous deep-rooted source of hydrate-forming water

The isotopic and ionic composition of pure gas hydrate (GH) water was examined for GHs recovered in three gravity cores (165–193 cm length) from the Kukuy K-9 mud volcano (MV) in Lake Baikal. A massive GH sample from core St6GC4 (143–165 cm core depth interval) was dissociated progressively over 6 h in a closed glass chamber, and 11 sequentially collected fractions of dissociated GH water analyzed. Their hydrogen and oxygen isotopic compositions, and the concentrations of Cl^– and HCO₃ ^– remained essentially constant over time, except that the fraction collected during the first 50 minutes deviated partly from this pattern. Fraction #1 had a substantially higher Cl^– concentration, similar to that of pore water sampled immediately above (135–142 cm core depth) the main GH-bearing interval in that core. Like the subsequent fractions, however, the HCO₃ ^– concentration was markedly lower than that of pore water. For the GH water fractions #2 to #11, an essentially constant HCO₃ ^–/Cl^– ratio of 305 differed markedly from downcore pore water HCO₃ ^–/Cl^– ratios of 63–99. Evidently, contamination of the extracted GH water by ambient pore water probably adhered to the massive GH sample was satisfactorily restricted to the initial phase of GH dissociation. The hydrogen and oxygen isotopic composition of hydrate-forming water was estimated using the measured isotopic composition of extracted GH water combined with known isotopic fractionation factors between GH and GH-forming water. Estimated δD of ?126 to ?133‰ and δ¹⁸O of ?15.7 to ?16.7‰ differed partly from the corresponding signatures of ambient pore water (δD of ?123‰, δ¹⁸O of ?15.6‰) and of lake bottom water (δD of ?121‰, δ¹⁸O of ?15.8‰) at the St6GC4 coring site, suggesting that the GH was not formed from those waters. Observations of breccias in that core point to a possible deep-rooted water source, consistent with published thermal measurements for the neighboring Kukuy K-2 MV. By contrast, the pore waters of core St6GC4 and also of the neighboring cores GC2 and GC3 from the Kukuy K-9 MV show neither isotopic nor ionic evidence of such a source (e.g., elevated sulfate concentration). These findings constrain GH formation to earlier times, but a deep-rooted source of hydrate-forming water remains ambiguous. A possible long-term dampening of key deep-water source signatures deserves further attention, notably in terms of diffusion and/or advection, as well as anaerobic oxidation of methane.     

Importance of feeding on regenerable parts of prey for juvenile stone flounder Platichthys bicoloratus in estuarine habitats

Prey availability is one of the most important factors affecting the quality of nursery grounds. Estuaries play an important role as nursery grounds for juvenile stone flounder, but the mechanism behind the consistently high availability of prey has never been examined. This study investigates which prey is mainly selected by juvenile stone flounder (15–55 mm standard length) in the estuary of the Natori River, northern Japan. In a cage experiment, juveniles showed positive selection for the palps of the spionid polychaete Pseudopolydora kempi in March, and for the siphons of the bivalve Nuttallia olivacea in April, May and June in both sandy and muddy-sand habitats. This selective predation showed that sublethal predation on regenerable parts of invertebrates is important for stone flounder. Nuttallia olivacea, the dominant bivalve in the estuary, was more abundant and in better somatic condition in the sandy area in spite of the stronger siphon-cropping pressure by juvenile stone flounder. These results confirm that sublethal predation on highly abundant benthos plays an important role in forming estuarine habitats into areas of high prey availability for juvenile stone flounder, which leads to their high growth rate.     

Enhanced predictions of wave impact pressure by improved incompressible SPH methods

A new criterion is proposed for a more efficient assessment of free-surface particles in a particle-based simulation. Enhanced wave impact simulations are carried out by improved Incompressible SPH (ISPH) methods. The first improvement is the same as that in the Corrected ISPH (CISPH; [Khayyer A, Gotoh, H, Shao SD. Corrected incompressible SPH method for accurate water-surface tracking in breaking waves, Coast Eng 2008; 55 (3): 236–250]) method and is proposed for the improvement of momentum conservation. The second improvement is achieved by deriving and employing a higher order source term based on a more accurate differentiation to obtain a less fluctuating and more accurate pressure field. The enhanced performance of improved ISPH methods is demonstrated through the simulation of several fluid impact simulations in comparison with the experimental data and simulation results by other numerical methods.     

Near-Infrared Photometric And Polarimetric Observations Of Comet Hale-Bopp

Near-infrared photometric and polarimetric observations of comet Hale-Bopp (1995 O1) using KONIC (Kiso Observatory Near-Infrared Camera) are reported. Observations were carried out on March 18 UT and April 26 UT 1997, when the heliocentric distances of the comet were 0.94 and 1.02 AU, and the phase angles were 48.5 deg and 32.9 deg, respectively. In the J, H, and K′ bands, we obtained linear polarization of the near-nucleus region of 16.4 ± 1.2, 18.8 ± 1.3, and 15.1 ± 0.9 percent on March 18UT and 7.1 ± 1.1, 8.9 ± 1.0, and 6.9 ± 0.6 percent on April 26, respectively. These values were higher than those observed for 1P/Halley. The maximum polarization was found at H band on both dates. Polarization maps showed higher polarization regions toward the anti-solar direction in the J and H bands. No distinct correlation was found between high polarization regions and bright regions. The projected expansion velocity of the arc structure of the dust jet was 375 ± 35.7 m/s on 17–19 March. The periodicity was found to be 11.1 ± 2.8 hours. This revised version was published online in July 2006 with corrections to the Cover Date.     

Fugacity-concentration relationship of dilute hydrogen in water at elevated temperature and pressure

The fugacity vs. concentration ratio(Y) of dilute hydrogen dissolved in water was determined at temperatures below 500°C and pressures below 1000 bar by measuring H₂ concentrations in magnetite-hematite-water and palladium hydride-water systems. Combining these results with reported solubility data of H₂ in water and with the Shaw's expression for the activity-composition relationship of H₂H₂O mixture at higher temperatures, theP-T-Y diagram was constructed over theP-T range below 900°C and 1000 bar.     

Process of the Tsushima Current formation revealed by ADCP measurements in summer

In order to clarify detailed current structures over the continental shelf margin in the East China Sea, ADCP measurements were carried out in summers in 1991 and 1994 by the quadrireciprocal method (Katoh, 1988) for removing diurnal and semidiurnal tidal flows from observed flows, together with CTD measurements. We discussed the process of the Tsushima Current formation in the East China Sea. The Tsushima Current with a volume transport of 2 Sv (1 Sv=10⁶ m³s^–1) was found north of 31°N. A current with a volume transport of 0.4 Sv was clearly found along the 100 m isobath. Between the Kuroshio and the current along the 100 m isobath, southeastward component of velocity was dominant compared to northwestward one. Four eastward to southeastward currents were found over the sea bed shallower than 90 m depth. Total volume transport of these four currents was 1 Sv, and they seemed to be originated from the Taiwan Strait. Intrusion of offshore water into the inner shelf northwest of Amami Oshima was estimated to have a volume transport of 0.6 Sv. It is concluded that the Tsushima Current is the confluence of these currents over the continental shelf margin with the offshore water intruding northwest of Amami Oshima.     

D/H fractionation factors between serpentine and water at 100° to 500°C and 2000 bar water pressure,and the D/H ratios of natural serpentines

D/H fractionation factors between serpentine (clinochrysotile) and water were experimentally determined to be: 1000 In α_ser-w = 2.75 × 10 ⁷/T² ? 7.69 × 10⁴/T + 40.8 in the temperature range from 100 to 500°C. The present results do not support the semi-empirical fractionation factors employed by Wenner and Taylor [1] for the interpretation of δD values of natural serpentines. About 100 serpentines from the Japanese Islands have δD values from ?110 to ?40‰ SMOW, with antigorite being from ?40 to ?60‰. The results are in accord with the two conclusions by Wenner and Taylor [1,2], that is, the presence of a latitude ?δD correlation and the more uniform and higher δD values of antigorite than chrysotile and lizardite.According to the present fractionation factors, almost none of the continental lizardite-chrysotile serpentines could have formed at a temperature below 500°C under equilibrium with fluids of δD values similar to the present-day local meteoric waters. The fluid responsible for oceanic serpentinization could be either a mixture of oceanic and magmatic water or oceanic water alone. However, full interpretation of the δD values of natural serpentines should wait until kinetic behaviors of hydrogen isotopes in serpentinization are better understood.     

Analysis of RC slab–beam–column sub‐assemblages subjected to bidirectional lateral cyclic loading using a new 3D macroelement

An existing two‐dimensional macroelement for reinforced concrete beam–column joints is extended to a three‐dimensional macroelement. The three‐dimensional macroelement for beam–column joints consists of six rigid interface plates and uniaxial springs for concrete, steel, and bond–slip, which model the inside of a beam–column joint. The mechanical models for the materials and the stiffness equation for the springs are also presented. To validate the model, we used test results from three slab–beam–column sub‐assemblages subjected to bi‐lateral cyclic load. It is revealed that the new joint model is capable of capturing the strength of beam–column joints and the bidirectional interaction in joint shear response, including the concentration of damage in the beam–column joint, the pinching nature in hysteretic behavior, the stiffness degradation, and strength deterioration resulting from cyclic and bidirectional loading. Copyright © 2017 John Wiley & Sons, Ltd.