Fragment-collision model for compound chondrule formation: Estimation of collision probability

We propose a new scenario for compound chondrule formation named as “fragment-collision model,” in the framework of the shock-wave heating model. A molten cm-sized dust particle (parent) is disrupted in the high-velocity gas flow. The extracted fragments (ejectors) are scattered behind the parent and the mutual collisions between them will occur. We modeled the disruption event by analytic considerations in order to estimate the probability of the mutual collisions assuming that all ejectors have the same radius. In the typical case, the molten thin () layer of the parent surface will be stripped by the gas flow. The stripped layer is divided into about 200 molten ejectors (assuming that the radius of ejectors is 300 μm) and then they are blown away by the gas flow in a short period of time (). The stripped layer is leaving from the parent with the velocity of depending on the viscosity, and we assumed that the extracted ejectors have a random velocity Δv of the same order of magnitude. Using above values, we can estimate the number density of ejectors behind the parent as . These ejectors occupy ∼9% of the space behind the parent in volume. Considering that the collision rate (number of collisions per unit time experienced by an ejector) is given by Rcoll=σcollneΔv, where σcoll is the cross-section of collision [e.g., Gooding, J.K., Keil, K., 1981. Meteoritics 16, 17-43], we obtain by substituting above values. Since most collisions occur within the short duration () before the ejectors are blown away, we obtain the collision probability of Pcoll∼0.36, which is the probability of collisions experienced by an ejector in one disruption event. The estimated collision probability is about one order of magnitude larger than the observed fraction of compound chondrules. In addition, the model predictions are qualitatively consistent with other observational data (oxygen isotopic composition, textural types, and size ratios of constituents). Based on these results, we concluded that this new model can be one of the strongest candidates for the compound chondrule formation. It should be noted that all collisions do not necessarily lead to the compound chondrule formation. The formation efficiency and the future works which should be investigated in the forthcoming paper are also discussed.     

Mesoscale eddy effects on temporal variability of surface chlorophyll a in the Kuroshio Extension

We investigated the relationship between chlorophyll a (Chl-a) concentrations estimated from satellite observations and the activity of eddies in the Kuroshio Extension region. High (low) area-averaged Chl-a concentrations were frequently observed in the core of cyclonic (anticyclonic) eddies. Such relationships between Chl-a concentrations and eddy cores were not frequently observed in the southern part of the recirculation gyre, and advection of background meridional gradient of Chl-a by eddy-edge currents accounted for Chl-a spatial variability. Decadal-scale changes of Chl-a concentrations around the Kuroshio Extension were strongly affected by eddy activity and transport but not by large-scale near-surface isopycnal heaving. We also found that decadal changes of nutrient concentrations near the main stream could affect Chl-a concentrations in the southern part of the recirculation gyre via southward transport of eddies and mean flow.     

Topography of the Moho and Conrad discontinuities in the Kyushu district,Southwest Japan

The first P-arrival time data from local earthquakes are inverted for two-dimensional variation of the depths to the Conrad and Moho discontinuities in the Kyushu district, southwest Japan. At the same time, earthquake hypocenters and station corrections are determined from the data. The depths to the discontinuities are estimated by minimizing the travel time residuals of first P-arrival phases for 608 earthquakes observed at 57 seismic stations. In the land area of Kyushu, the Conrad and Moho discontinuities are located within the depth ranges of 16–18 and 34–40 km, respectively. The Conrad discontinuity is not as largely undulated as the Moho discontinuity. The depth to the Moho is deep along the east coast of Kyushu, and the deepest Moho is closely related to markedly low velocity of P wave. We regard the deepest Moho as reflecting the Kyushu–Palau ridge subducting beneath the Kyushu district, together with the Philippine Sea slab. In western Kyushu, the shallow Moho is spreading in the north–northeast–south–southwest direction in the Okinawa trough region. Based on the presence of low-velocity anomaly in three-dimensional velocity structure and seismogenic stress field of shallow crustal earthquakes, the shallow Moho is interpreted as being due to lower crustal erosion associated with a small-scale mantle upwelling in the Okinawa trough region. The velocity discontinuity undulation basically has insignificant effect on hypocenter determination of the local earthquakes, but the Moho topography makes changes in focal depths of some upper mantle earthquakes. The depth variation of the Moho discontinuity has a good correlation with the Bouguer gravity anomaly map; i.e., the shallow Moho of western Kyushu and the deep Moho of eastern Kyushu closely correlate with the positive and negative Bouguer gravity anomalies, respectively.     

Decomposition of Phytoplankton in Seawater. Part I: Kinetic Analysis of the Effect of Organic Matter Concentration

Decomposition experiments were conducted on cultured phytoplankton (Skeletonema costatum) in seawater containing decomposer and consumer of size less than 500 μm. We determined the decomposition rates of bulk particulate organic matter (POM), the ratio of labile to semi-refractory fractions in the POM, and the POM carbon/ nitrogen (C/N) ratio during decomposition. To identify the kinetic mechanisms involved in the reactions of different order (e.g., first- and second-order), we studied the sensitivity of reaction rates to the initial concentration of POM, ranging from 2.4 to 71 mg-C L⁻¹. The results showed that decomposition consists of two first-order reactions: decomposition of labile and of semi-refractory particulate organic carbon (POC). The decomposition rate constants found for labile (0.13 day⁻¹ at 20°C), and semi-refractory POC (0.008 day⁻¹ at 20°C), and the carbon weight ratio of semi-refractory POC (13% at 20°C), were insensitive to the initial organic matter concentration. The time-dependence of the C/N ratio was also independent of this initial concentration. The decomposition rate constants and the content of semi-refractory POC did not change, regardless of the absence or presence of 25–500 μm organisms in natural seawater. This revised version was published online in July 2006 with corrections to the Cover Date.