AFM study on surface nanotopography of matrix olivines in Allende carbonaceous chondrite

By means of nanoscale surface observation, we have proposed a new approach for investigating fine crystals of cosmic materials to reveal their origin and growth conditions. Several different morphologies of polyhedral fine olivines with faceted faces have been found in Allende carbonaceous chondrite (4.5 byr in geochronological age). In the present work, molecular level topography of the faceted matrix olivine by Atomic Force Microscopy (AFM) has successfully been performed. The matrix olivine found to have preserved growth step pattern on its surface even though quite long time has passed since they formed in the early Solar System. The surface pattern suggests that the faceted matrix olivine could have been condensed from the gas phase, and possibly that these olivine crystals had continued to grow under a rapid cooling condition (0.1-1 K s⁻¹). The estimated cooling rate agrees well with predictions based on hypothetical rapid heating and cooling events such as shock wave heating.     

Seismic response of a cut‐and‐cover tunnel isolated by polymer material

An effective method for the seismic retrofitting of the sidewalls of cut‐and‐cover tunnels has not yet been established. Thus, a new method of seismic retrofitting for cut‐and‐cover tunnels, called the ‘polymer isolation method’, is developed here. In this method, thin walls made of polymer materials, called ‘isolation walls’, are inserted between the ground and the sidewalls of a tunnel. We demonstrate the effectiveness of the proposed method in reducing the seismic response of tunnels by using some numerical simulations. It is found that the proposed method depends on the thickness of the soil cover over the tunnel and the ratio of the stiffness between the soil and the structure. Furthermore, a simple chart is proposed for convenience to represent the applicability of the polymer isolation method to the design of seismic retrofits for cut‐and‐cover tunnels. Although this particular chart has been obtained through a limited case, some other typical cases in which the chart can also be implemented for special conditions are addressed, and the applicability and the limitations of this chart are suggested for possible conditions of the ground and of tunnel structures. Copyright © 2012 John Wiley & Sons, Ltd.     

Alkali (Rb/K) abundances in Allende barred-olivine chondrules: Implications for the melting conditions of chondrules

Abstract— In order to study abundances of alkali metals in chondrules, 25 petrographically characterized chondrules, including 18 barred olivine (BO) chondrules from the Allende (CV3) meteorite, were analyzed for alkalis (K and Rb) and alkaline earths (Sr, Ba, Ca and Mg) by mass spectrometric isotope dilution. Most BO chondrules with higher alkalis (>CI level) have nearly CI-chondritic Rb/K ratios, while those with lower alkalis clearly show higher Rb/K ratios than the CI-chondritic. In general, BO chondrules with higher Rb/K exhibit more depletion of alkalis relative to Ca. The mean olivine Fa for individual chondrules positively correlates with bulk alkali concentrations in BO type but not in porphyritic type chondrules. These observations suggest that some BO chondrules formed from more reducing assemblages of precursor minerals, which experienced more intensive vaporization losses of alkalis, accompanied by Rb/K fractionation, during the chondrule-formation melting.     

Thermochronology for the Granitic Pluton Related to Lead-Zinc Mineralization in Tsushima, Japan

Abstract: K–Ar datings and oxygen isotope analyses revealed a cooling history of the Uchiyama granitic pluton, which is genetically related to the Pb-Zn deposits (Taishu mine) in the Tsushima Islands, Japan. The pluton intrudes into the Paleogene Taishu Group to form the biotite-hornfels zone, while the Taishu vein-type Pb–Zn deposits occur in fissures developed in the non-hornfels zone about 1 to 3 km westward from the contact. Amphibole and biotite K-Ar ages of the pluton have a wide range from 19 to 13 Ma. Oxygen isotopes of the biotite and coexisting quartz grains indicate that isotopic exchange reactions have occurred under subsolidus conditions, and that the K-Ar ages are affected by various cooling rates in the pluton. The mineralization age of the Taishu ore deposits is obtained for the first time to be 15.40.8 Ma by a K-Ar age of 2 M ₁–muscovite in a calcite–quartz–muscovite–chlorite veinlet of the Shintomi orebody. Whole rock K-Ar ages of biotite-hornfels near the pluton represent similar ages to the ore deposits. Using blocking temperature calculated from reported diffusivity for argon, the pluton was cooled from 560 to 350C in the period of 17 to 14 Ma. The vein formation took place after the time when temperature in wall rocks of the pluton had dropped below the brittle-plastic transition (about 400C). These results imply that the cooling of the pluton has caused injection of magmatic fluids into meteoric hydrothermal systems, and the Pb-Zn mineralization has occurred due to this mixing at the age of about 15 Ma.     

Ti-rich hydroandradites from the Sanbagawa metamorphic rocks of the Shibukawa area,central Japan

Ti-rich hydroandradite often occurs, though usually as a minor constituent, in serpentinized ultramafic rocks and associated gabbroic rocks of the Sanbagawa metamorphic belt. The chemistry of the host rocks is commonly characterized by undersaturation with SiO₂. Two Ti-rich hydroandradites from metasomatized gabbroic rocks of the Shibukawa area have been chemically analysed by the wet method. Mössbauer experiments indicate the presence of Fe³⁺ and Fe²⁺ in the octahedral sites of these Ti-rich hydroandradites. Wet chemical analyses for total reducing capacity of the present garnets by two different methods together with Mössbauer data imply the presence of octahedral Ti³⁺ in their structure. Ti-rich hydroandratites, apart from their hydrous property, have a similar crystal chemistry to natural Ti-rich andradites. Ti-rich hydroandradites were probably formed in rocks with unusual chemical compositions within a P-T region of 300–400° C and 4–7 kb under limited conditions of relatively low oxygen fugacity and low μCO₂.     

Tectonic evolution along the northernmost border of the Philippine Sea plate since about 1 Ma

Recent structural, tephrochronologic and magnetostratigraphic studies conducted along the northernmost border of the Philippine Sea (PHS) plate enable us to reconstruct the precise tectonic evolution along the convergent boundary between the PHS plate and the Northeast Japan (NEJ) plate or the North American (NAM) plate since about 1 Ma. The authors of the present study split the tectonic evolution into five stages and present the characteristics of each stage. A plate tectonic interpretation is proposed, based upon the tectonic evolution, with special reference to the mode of convergent motion. In brief, our interpretations are as follows: the relative motion between the PHS and the NEJ plates was not recognized geologically within the area studied from about 1.0 to 0.9 Ma (Stage 1), suggesting either none or small influence from the coupling between the two plates during that period of time. Convergence between the PHS and the NEJ plates was possibly in N-S direction from 0.9 to 0.5 Ma (Stage II), and probably north-northwestward since 0.5 Ma (Stages III to V). The mode of the convergent motion was that of buoyant subduction in Stages II and III. The mode changed gradually from buoyant subduction during Stage IV to collision in Stage V (0.07 Ma to the present).     

Acetylene reducing activity at a tropical seagrass bed in Papua New Guinea

Acetylene reduction activity at a tropical seagrass bed in Papua New Guinea was studied. Blades of every species of seagrass studied (Enhalus acoroides, Thalassia hemprichii, Halodule uninervis, Syringodium isoetifolium) at the bed showed active acetylene reduction in the rage of 0.025–0.050 mol cm^–2d^–1. It is suggested that epiphytic blue-green algae would be responsible for active acetylene reduction. Acetylene reducing activity was observed also at rhizosphere of seagrasses, microbial communities on the detritus and periphyton on snail shells. It is estimated that total nitrogen fixed at the seagrass bed will be equivalent to 6.7% of that required for the growth of seagrasses.     

High-temperature thermal expansion and elasticity of calcium-rich garnets

We present new high temperature elasticity data on two grossular garnet specimens. One specimen is single-crystal, of nearly endmember grossular, the other is polycrystalline with about 22% molar andradite. Our data extend the high temperature regime for which any garnet elasticity data are available from 1000 to 1350 K and the compositional range of temperature data to near endmember grossular. We also present new data on the thermal expansivity of calcium-rich garnet. We find virtually no discernable differences in the temperatureT derivatives at ambient conditions of the isotropic bulkK _S and shearμ moduli when comparing our results between these two specimens. These calcium-rich garnets have the lowest values of ¦(?K _S /?T) _P ¦ = (1.47,1.49) x 10^-2GPa/K, and among the highest values of ¦(?μ/?T) _P ¦ = 1.25 x 10^-2GPa/K, when compared with other garnets. Small, but measurable, nonlinear temperature dependences of most of the elastic moduli are observed. Several dimensionless parameters are computed with the new data and used to illustrate the effects of different assumptions on elastic equations of state extra-polated to high temperatures. We discuss how dimensionless parameters and other systematic considerations can be useful in estimating the temperature dependence of some properties of garnet phases for which temperature data are not yet available. While we believe it is premature to quantitatively predict the temperature variation ofK _S andμ for majorite garnets, our results have bearing on the amount of diopside required to explain the shear velocity gradients in Earth's transition zone.     

Borehole image analysis of the Nankai Accretionary Wedge, ODP Leg 196: Structural and stress studies

Electrical images recorded with Resistivity-At-Bit (RAB) from two sites drilled during Ocean Drilling Program (ODP) Leg 196 were analyzed to study the effects of subduction at the Nankai margin. For the first time in the history of scientific deep-sea drilling in ODP, in situ complete borehole images of the décollement zone were obtained. Analyses of all drilling-induced fracture data indicated that the maximum horizontal compressive stress (S_Hmax) axes have an azimuth of 303°, and analyses of breakout data from RAB images indicated an azimuth of 310°. These azimuths approximate the convergence direction of the Philippine Sea plate towards the Eurasian plate. The frontal thrust at Site 808 was encountered at about 389 mbsf. Density, porosity, resistivity, and gamma ray data change across the frontal thrust. The décollement zone at the deformation front was identified between 937 and 965 mbsf. The base of the décollement is sharply defined as the maximum extent of conductive fracturing and is marked by abrupt changes in physical properties [Mikada, H., Becker, K., Moore, J.C., Klaus, A., Austin, G.L., Bangs, N.L., Bourlange, S., Broilliard, J., Brückmann, W., Corn, E.R., Davis, E.E., Flemings, P.B., Goldberg, D.B., Gulick, S.S., Hansen, M.B., Hayward, N., Hills, D.J., Hunze, S., Ienaga, M., Ishiguro, H., Kinoshita, M., Macdonald, R.D., McNeill, L., Obana, S., Hong, O.S., Peacock, S., Pettigrew, T.L., Saito, S., Sawa, T., Thaiprasert, N., Tobin, H.J., Tsurumi, H., 2002. Proc. ODP, Initial Rep., 196, College Station, TX, (Ocean Drilling Program)]. The upper boundary of the décollement is marked by several sets of conductive fractures and by high variability in physical properties. The décollement zone is characterized by intense brittle fracturing. These fractures are considered to be the consequence of cyclic stresses and high fluid pressures in this zone. We analyzed fracture dips and their orientations at both sites and found that they are all consistent with a unique stress field model surrounding the two sites.     

An efficient method to compute the dynamic response of a fluid-filled crack

The vibration of a fluid-filled crack is considered to be one of the most plausible source mechanisms for the long-period events and volcanic tremors occurring around volcanoes. As a tool for the quantitative interpretation of source process of such volcanic seismic signals, we propose a method to numerically simulate the dynamic response of a fluid-filled crack. In this method, we formulate the motions of the fluid inside and the elastic solid outside of the crack, using boundary integrals in the frequency domain and solve the dynamic interactions between the fluid and the elastic solid using the point collocation method. The present method is more efficient compared with the time-domain finite difference method, which has been used in simulations of a fluid-filled crack and enables us to study the dynamics of a fluid-filled crack over a wide range of physical parameters. The method also allows us direct calculation of the attenuation quality factor of the crack resonance, which is an indispensable parameter for estimating the properties of the fluid inside the crack. The method is also designed to be flexible to many applications, which may be encountered in volcano seismology, and thus, extensions of the method to more complicated problems are promising.