Incorporation of U,Pb and Rare Earth Elements in Calcite through Crystallisation from Amorphous Calcium Carbonate: Simple Preparation of Reference Materials for Microanalysis

Uncertainty for elemental and isotopic measurements in calcite by LA‐ICP‐MS is largely controlled by the homogeneity of the reference materials (RMs) used for calibration and validation. In order to produce calcite RMs with homogeneous elemental and isotopic compositions, we incorporated elements including U, Pb and rare earth elements into calcite through heat‐ and pressure‐induced crystallisation from amorphous calcium carbonate that was precipitated from element‐doped reagent solution. X‐ray absorption spectra showed that U was present as U(VI) in the synthesised calcite, probably with a different local structure from that of aqueous uranyl ions. The uptake rate of U by our calcite was higher in comparison with synthetic calcite of previous studies. Variations of element mass fractions in the calcite were better than 12% 2RSD, mostly within 7%. The ²⁰⁷Pb/²⁰⁶Pb ratio in the calcite showed < 1% variations, while the ²³⁸U/²⁰⁶Pb ratio showed 3–24% variations depending on element mass fractions. Using the synthetic calcite as primary RMs, we could date a natural calcite RM, WC‐1, with analytical uncertainty as low as < 3%. The method presented can be useful to produce calcite with controlled and homogeneous element mass fractions and is a promising alternative to natural calcite RMs for U‐Pb geochronology.     

Simulation of risk-consistent earthquake motion

A method to combine probabilistic seismic hazard analysis and stochastic earthquake motion models is presented. A set of parameters characterizing stochastic earthquake motion models is determined on a consistent probabilistic basis. The method proposed herein consists of two steps. First, the ground motion intensity is determined in the context of the conventional hazard curve technique. Next, other ground motion parameters such as duration, predominant frequency and spectral shape parameters are determined as conditional means corresponding to the annual probability of exceedance for the ground motion intensity. Some example applications are presented.     

Active right-lateral strike-slip fault zone along the southern margin of the Japan Sea

We describe an active right-lateral strike-slip fault zone along the southern margin of the Japan Sea, named the Southern Japan Sea Fault Zone (SJSFZ). Onshore segments of the fault zone are delineated on the basis of aerial photograph interpretations and field observations of tectonic geomorphic features, whereas the offshore parts are interpreted from single-/multichannel seismic data combined with borehole information. In an effort to evaluate late Quaternary activity along the fault zone, four active segments separated by uplifting structures are identified in this study. The east–northeast-trending SJSFZ constitutes paired arc-parallel strike-slip faults together with the Median Tectonic Line (MTL), both of which have been activated by oblique subduction of the Philippine Sea plate during the Quaternary. They act as the boundaries of three neotectonic stress domains around the eastern margin of the Eurasian plate: the near-trench Outer zone and NW–SE compressive Inner zone of southwest Japan arc, and the southern Japan Sea deformed under E–W compression from south to north.     

Simulation of groundwater flow and environmental effects resulting from pumping

In coastal lowland plains, increased water demand on a limited water resource has resulted in declining groundwater levels, land subsidence and saltwater encroachment. In southwestern Kyushu, Japan, a sinking of the land surface due to over pumping of groundwater has long been recognized as a problem in the Shiroishi lowland plain. In this paper, an integrated model was established for the Shiroishi site using the modular finite difference groundwater flow model, MODFLOW, by McDonald and Harbaugh (1988) and the modular three-dimensional finite difference groundwater solute transport model, MT3D, by Zheng (1990) to simulate groundwater flow hydraulics, land subsidence, and solute transport in the alluvial lowland plain. Firstly, problems associated with these groundwater resources were discussed and then the established model was applied. The simulated results show that subsidence rapidly occurs throughout the area with the central prone in the center part of the plain. Moreover, seawater intrusion would be expected along the coast if the current rates of groundwater exploitation continue. Sensitivity analysis indicates that certain hydrogeologic parameters such as an inelastic storage coefficient of soil layers significantly contribute effects to both the rate and magnitude of consolidation. Monitoring the present salinization process is useful in determining possible threats to fresh groundwater supplies in the near future. In addition, the integrated numerical model is capable of simulating the regional trend of potentiometric levels, land subsidence and salt concentration. The study also suggests that during years of reduced surface-water availability, reduction of demand, increase in irrigation efficiency and the utilization of water exported from nearby basins are thought to be necessary for future development of the region to alleviate the effects due to pumping.     

Sedimentary humic acid and fulvic acid as fluorescent organic materials

Fluorescence and absorption spectra of sedimentary humic acid (HA) and fulvic acid (FA), with molecular weights ranging from < 10,000 to >300,000, were measured at 20°C and pH 8. The maximum excitation and emission wavelengths of HA were longer than those of FA, being independent of molecular weight. The excitation and emission maxima can be utilized to differentiate between sedimentary HA and FA. It is suggested that the fluorophors in HA are of a higher molecular weight aromatic groups than those in FA.Smaller molecules were found to have a greater fluorescence than larger ones for sedimentary humic substances and this phenomenon is similar to those obtained for humic substances of terrestrial origin. The absorption coefficient (1/g/cm) of HA decreased, while that of FA increased with the increase in molecular weight. It was shown that fluorescence intensity per weight concentration unit of HA increases and that of FA decreases with increasing absorption coefficient.     

New discoveries in dynamics of an M8 earthquake-phenomena and their implications from the 2003 Tokachi-oki earthquake using a long term monitoring cabled observatory

At the 2003 Tokachi-oki earthquake of M8, seafloor phenomena such as a generation process of tsunami, seafloor uplifts, turbidity current, etc., were observed using a cabled observatory installed on the seafloor. The turbidity current was observed as a benthic storm caused presumably by the mainshock. The seafloor uplifts were observed at the mainshock and continuously after the mainshock. The uplifts were 0.35, 0.37, and 0.12 m for epicentral distances of 25.5, 31.4, and 81.7 km, respectively. After the mainshock, a continuous uplift of the seafloor is observed at all three pressure gauge locations indicating that there was a change in the state of friction on the plate boundary interface by the mainshock. In this paper, we first show what was observed using the cabled observatory installed right above the focal area of the earthquake, and then we discuss to summarize these phenomena associated with the earthquake, its possible causes, and future directions in long term monitoring of seismogenic processes.     

Groundwater resources management under environmental constraints in Shiroishi of Saga plain, Japan

A sinking of the land surface due to the pumping of groundwater has long been recognized as an environmental issue in the Shiroishi plain of Saga, Japan. Land subsidence can have several negative economic and social implications such as changes in groundwater and surface water flow patterns, restrictions on pumping in land subsidence prone areas, localized flooding, failure of well casings as well as shearing of structures. To minimize such an environmental effect, groundwater management should be considered in this area. In this study, a new integrated numerical model that integrates a three-dimensional numerical groundwater flow model coupled with a one-dimensional soil consolidation model and a groundwater optimization model was developed to simulate groundwater movement, to predict ground settlement and to search for optimal safe yield of groundwater without violating physical, environmental and socio-economic constraints. It is found that groundwater levels in the aquifers greatly vary from season to season in response to the varying climatic and pumping conditions. Consequently, land subsidence has occurred rapidly throughout the area with the Shiroishi plain being the most prone. The predicted optimal safe yield of the pumping amount is about 5 million m³. The study also suggests that pumping with this optimal amount will minimize the rate of land subsidence over the entire area. An erratum to this article can be found at     

Terrestrial organic matter controlling gas hydrate formation in the Nankai Trough accretionary prism, offshore Shikoku, Japan

Sediment core samples from Sites 1175, 1176, and 1178, ODP Leg 190, Nankai Trough were analyzed for sedimentary organic matter and inorganic elemental compositions to clarify geochemical conditions for the formation of gas hydrate. Low chloride concentrations and anomalously low core temperature infer the existence of gas hydrate at Site 1178. Trace amounts of gas hydrate are also suggested for Site 1176. Site 1175 does not have any significant evidence of gas hydrate, although all the three sites are within the gas hydrate stability zone. The sediment from Site 1178 is characterized by abundant terrigenous organic matter, older geologic ages, and comparatively higher maturity levels, suggesting high rates of CO₂ generation during diagenesis. The CO₂ generation potential of sediment may be one of the crucial conditions for the formation of gas hydrate.     

岩石碎裂作用的分形尺度(英文)

各种各样的统计幂定律关系经常成功地被用来描述碎屑大小分布和断口形状 (不平整度 )的分级规律 ,表明碎裂作用是一种尺度不变的作用过程。一条新的有关岩石碎裂作用破裂能量的尺度律 ,可以由分形几何以及Griffith能量平衡的概念推导出来 ,而且它与先前三条关于大小缩减或Hall Petch关系的理论是相一致的。从材料强度的观点来看 ,断口形状的分形维数是形状因子和岩石Weibull均质系数的函数。在任何一次采集中 ,如果碎屑都是致密压实的 ,那么大小分布和碎屑不平整度的分形维数是相同的。然而有些地壳碎屑在三维体积上已不再是致密压实的 ,破裂的地壳可被当作分形的多孔物质来处理。在此情况下 ,地壳碎屑形状的分形容量与地壳断口大小分布的分形维数相关 ,可以预期 ,在大地构造及地震强度的分形分析中 ,地壳断口大小分布的分形维数可作为断裂制约条件之一。     

Progress in optical dating of guano-rich sediments associated with the Deep Skull, West Mouth of the Great Cave of Niah, Sarawak, Borneo

The West Mouth of the Great Cave of Niah is one of the major archaeological sites in Southeast Asia; the radiocarbon chronology of this site currently places the earliest presence of Homo sapiens (a Deep Skull find) in Southeast Asia at about 45 ka BP. An optical dating programme using sand-sized quartz was initiated in the West Mouth to complement the radiocarbon chronology. This paper reports on the progress in dating a key sample (sample 376r) that was taken from deposits containing the Deep Skull. A somewhat novel procedure was developed to separate and clean quartz grains from the unusual guano-rich deposits. From this, only a small quantity of quartz grains could be recovered and 36 aliquots (1 mm in diameter) were prepared, each consisting of 80 grains. This sample was dated by means of the single-aliquot regenerative-dose (SAR) method using the protocols of Murray and Wintle [2000. Luminescence dating of quartz using an improved single-aliquot regenerative-dose protocol. Radiation Measurements 32, 57–73], and of Choi et al. [2003. Luminescence dating of well-sorted marine terrace sediments on the southeastern coast of Korea. Quaternary Science Reviews 22, 407–421]. The results showed a wide distribution of equivalent doses; this distribution is inferred to be due to bioturbation, variable bleaching at deposition, and to local variations in the dose rate within the sample site. Dose rates were measured using both field (in-situ γ-ray spectrometry, IGRS) and laboratory (inductively coupled plasma mass spectrometry/atomic emission spectrometry, ICP-MS/AES; and isotope dilution, ID) methods. There was significant disagreement between the concentrations of radioisotopes found using laboratory and field measurements, indicating sediment heterogeneity and also possible disequilibrium in the ²³⁸U decay chain. Future work in the West Mouth should therefore concentrate on taking sediment samples of at least 500–600 cm³, improving the dose rate estimates (e.g. by high-resolution γ-ray spectrometry) and investigating other luminescence signals (e.g. red thermoluminescence) as potential geochronometers.