Infrared spectroscopic taxonomy for carbonaceous chondrites from speciation of hydrous components

Abstract— Mid‐infrared absorption spectra for all types of carbonaceous chondrites were obtained in this study to establish a versatile method for spectroscopic classification of carbonaceous chondrites. Infrared spectra were measured using a conventional KBr pellet method and diamond press method. Spectra of hydrous carbonaceous chondrites exhibit intense O‐H stretching vibrations. CI chondrites are identifiable by a characteristic sharp absorption band appearing at 3685 cm^?1, which is mainly attributable to serpentine. X‐ray diffraction analysis showed the presence of serpentine. However, Yamato (Y‐) 82162 (C1) does not have the band at 3685 cm^?1 because of its thermal metamorphism. CM and CR chondrites have an intense absorption band at approximately 3600 cm^?1. This absorption tends to appear in CM chondrites more strongly than CR chondrites because the intensity ratios of an OH stretching mode at 3520 cm^?1 compared to 3400 cm^?1 for CM chondrites are in the range of 0.95–1.04, which is systematically higher than those of CR chondrites (0.86–0.88). Therefore, the two types of chondrites are distinguishable by their respective infrared spectra. The spectrum feature of the Tagish Lake meteorite is attributable to neither CI nor CM chondrites. CO chondrites are characterized by weak and broad absorption at 3400 cm^?1. CV chondrites have weak or negligible absorption of water. CK chondrites also have no water‐induced absorption. CH and CB chondrites have a sharp absorption at 3692 cm^?1 indicating the presence of chrysotile, which is also supported by observations of X‐ray diffraction and TEM. The combination of spectroscopic classification and the diamond press method allows classification of carbonaceous chondrites of very valuable samples with small quantities. As one example, carbonaceous chondrite clasts in brecciated meteorites were classified using our technique. Infrared spectra for a fragment of carbonaceous clasts (<1 μg) separated from Willard (b) and Tsukuba were measured. The 3685 cm^?1 band found in CI chondrites was clearly detected in the clasts, indicating that they are CI‐like clasts.     

Interannual and seasonal variation of the Huanghe (Yellow River) water discharge over the past 50 years: Connections to impacts from ENSO events and dams

The Huanghe, the second largest river in China, is now under great pressure as a water resource. Using datasets of river water discharge, water consumption and regional precipitation for the past 50 years, we elucidate some connections between decreasing water discharges, global El Niño/Southern Oscillation (ENSO) events and anthropogenic impacts in the drainage basin. Global ENSO events, which directly affected the regional precipitation in the river basin, resulted in approximately 51% decrease in river water discharge to the sea. The degree of anthropogenic impacts on river water discharge is now as great as that of natural influences, accelerating the water losses in the hydrological cycle. The large dams and reservoirs regulated the water discharge and reduced the peak flows by storing the water in the flood season and releasing it in the dry season as needed for agricultural irrigation. Thus, as a result, large dams and reservoirs have shifted the seasonal distribution patterns of water discharge and water consumption and finally resulted in rapidly increasing water consumption. Meanwhile, the annual distribution pattern of water consumption also changed under the regulation of dams and reservoirs, indicating that the people living in the river basin consume the water more and more to suit actual agricultural schedule rather than depending upon natural pattern of annual precipitation. The combination of the increasing water consumption facilitated by the dams and reservoirs and the decreasing precipitation closely associated with the global ENSO events over the past half century has resulted in water scarcity in this world-famous river, as well as in a number of subsequent serious results for the river, delta and coastal ocean.     

Primary proton spectrum around the knee deduced from the emulsion-chamber data obtained at Mts. Fuji and Kanbala

We have done extensive Monte Carlo simulations using the new simulation codes of CORSIKA and COSMOS to compare with the gamma-family data obtained at Mts. Fuji (3750 m above sea level) and Kanbala (5500 m above sea level). Then, we estimated the primary proton and helium spectra around the knee energy region using a multiple-layered feed-forward neural network as a classifier of primary particle kind. The selection efficiency of proton-induced family events is estimated to be 82%. The flux value of protons at 2×10¹⁵ eV is (5.5±1.5)×10⁻¹⁴ (m⁻² s⁻¹ sr⁻¹ GeV⁻¹). The result suggests heavy-enriched primary composition around the knee region.     

Fluctuations of electron precipitation to the dayside auroral zone modulated by compression and expansion of the magnetosphere

Concurrent variations of CNA fluctuations and geomagnetic fluctuations are classified into Type 1 (substorm-type), Type 2 (Pc5-type), and Type 3 which is the object of the present study. Type 3 apparently has peculiar characteristics in that CNA fluctuations at a certain auroral-zone station show a pronounced positive correlation with magnetic fluctuations at distant low-latitude stations. The magnetic fluctuations of this type are identified to generalized Si which tends to take place much more frequently than the so-called Si. The CNA fluctuations of this type are found to take place on the dayside auroral zone only when preceded by a magnetic substorm on the night side. Considering the change of the growth rate of electron cyclotron instability and enhancement of pitch angle diffusion due to the change of magnetic field intensity, the following model is proposed to explain the occurrence mechanism of Type 3 concurrent variations. The CNA fluctuations take place only when two conditions are satisfied; generation of the accelerated electrons in association with substorm onset and modulation of the precipitation of the electrons by compression and expansion of the magnetosphere, in other words, by generalized Si.     

A survey of possible impact structures on 25143 Itokawa

We determined the morphologies and dimensions of possible impact craters on the surface of Asteroid 25143 Itokawa from images taken by the Hayabusa spacecraft. Circular depressions, circular features with flat floors or convex floors, and circular features with smooth surfaces were identified as possible craters. The survey identified 38 candidates with widely varying morphologies including rough, smooth and saddle-shaped floors, a lack of raised rims and fresh material exposures. The average depth/diameter ratio was 0.08±0.03: these craters are very shallow relative to craters observed on other asteroids. These shallow craters are a result of (1) target curvature influencing the cratering process, (2) raised rim not being generated by this process, and (3) fines infilling the craters. As many of the crater candidates have an unusual appearance, we used a classification scheme that reflects the likelihood of an observed candidate's formation by a hypervelocity impact. We considered a variety of alternative interpretations while developing this scheme, including inherited features from a proto-Itokawa, spall scars created by the disruption of the proto-Itokawa, spall scars following the formation of a large crater on Itokawa itself, and apparent depressions due to random arrangements of boulders. The size-frequency distribution of the crater candidates was close to the empirical saturation line at the largest diameter, and then decline with decreasing diameter.     

The Sunyaev–Zel'dovich effect and Faraday rotation contributions of galaxy groups to the CMB angular power spectrum

The Sunyaev–Zel'dovich (SZ) effect and the Faraday rotation from haloes are examined over a wide mass range, including gas condensation and magnetic field evolution. Contributions to the cosmic microwave background (CMB) angular power spectrum are evaluated for galaxy clusters, galaxy groups and galaxies. Smaller mass haloes are found to play a more important role than massive haloes for the B -mode polarization associated with the SZ CMB anisotropies. The B modes from the Faraday rotation dominate the secondary B modes caused by gravitational lensing at  ℓ > 3000  . Measurement of B -mode polarization in combination with the SZ power spectrum can potentially provide important constraints on intracluster magnetic field and gas evolution at early epochs.     

Cluster formation and the Sunyaev–Zel'dovich power spectrum in modified gravity: the case of a phenomenologically extended DGP model

We investigate the effect of modified gravity on cluster abundance and the Sunyaev–Zel'dovich (SZ) angular power spectrum. Our modified gravity is based on a phenomenological extension of the Dvali–Gabadadze–Porrati model which includes two free parameters characterizing deviation from Λ cold dark matter cosmology. Assuming that Birkhoff's theorem gives a reasonable approximation, we study the spherical collapse model of structure formation and show that while the growth function changes to some extent, modified gravity gives rise to no significant change in the linear density contrast at collapse time. The growth function is enhanced in the so called normal branch, while in the 'self-accelerating' branch it is suppressed. The SZ angular power spectrum is computed in the normal branch, which allows us to put observational constraints on the parameters of the modified gravity model using small scale cosmic microwave background observation data.