Simulations of seasonal variations of sulfur compounds in the remote marine atmosphere

A photochemical box model is used to simulate seasonal variations in concentrations of sulfur compounds at latitude 40° S. It is assumed that the hydroxyl radical (OH) addition reaction to sulfur in the dimethyl sulfide (DMS) molecule is the predominant pathway for methanesulfonic acid (MSA) production, and that the rate constant increases as the air temperature decreases. Concentration of the nitrate radical (NO₃) is a function of the DMS flux, because the reaction of DMS with NO₃ is the most important loss mechanism of NO₃. While the diurnally averaged concentration of OH in winter is a factor of about 8 smaller than in summer, due to the weak photolysis process, the diurnally averaged concentration of NO₃ in winter is a factor of about 4–5 larger than in summer, due to the decrease of DMS flux. Therefore, at middle and high latitudes in winter, atmospheric DMS is mainly oxidized by the reaction with NO₃. The calculated ratio of the MSA to SO₂ production rates is smaller in winter than in summer, and the MSA to non-sea-salt sulfate (nssSO₄ ^2-) molar ratio varies seasonally. This result agrees with data on the seasonal variation of the MSA/nssSO₄ ^2- molar ratio obtained at middle and high latitudes. The calculations indicate that during winter the reaction of DMS with NO₃ is likely to be a more important sink of NO_x (NO+NO₂) than the reaction of NO₂ with OH, and to serve as a significant pathway of the HNO₃ production. If dimethyl sulfoxide (DMSO) is produced through the OH addition reaction and is heterogeneously oxidized in aqueous solutions, half of the nssSO₄ ^2- produced in summer may be through the oxidation process of DMSO. It is necessary to further investigate the oxidation products by the reaction of DMS with OH, and the possibility of the reaction of DMS with NO₃ during winter.     

From an initial transient-state to a steady-state in metamorphic reactions: An experimental approach in the system dolomite-quartz-H2O

Abstract We carried out hydrothermal experiments in the system dolomite‐quartz‐H₂O to track the temporal change in reaction rates of simultaneous reactions during the development of reaction zones. Two types of configurations for the starting materials were prepared: dolomite single crystals + quartz powder + water and quartz single crystals + dolomite powder + water, both sealed separately in gold capsules. Runs at 0.1GPa and 600°C with cold seal pressure vessels gave the following results. (i) In short duration (45–71 h) runs metastable layer sequences involving wollastonite and talc occur in the reaction zone, whereas they disappear in longer duration (168–336 h) runs. (ii) The layer sequence of the reaction zones in short duration runs differs from place to place on the dolomite crystal even in the same run. (iii) The diversity of layer sequences in the short duration runs merges into a unique layer sequence in the longer duration runs. (iv) The reaction zone develops locally on the dolomite crystal, but no reaction zone was observed on the quartz crystal in any of the runs. The lines of evidence (i)–(iii) show that the system evolves from an initial transient‐ to a steady‐state and that the kinetic effect is important in the development of reaction zones. A steady diffusion model for the unique layer sequence Qtz/Di/Fo + Cal/Dol + Cal/Dol shows that the Dol + Cal layer cannot be formed by diffusion‐controlled process and that the stability of the layer sequence Qtz/Di/Fo + Cal/Dol depends not only on L‐ratios (a = /L_CaOCaO and b = /L_MgOMgO) but also on the relative rate P = (−2ξ₁ − ξ₂)/(–ξ₁ − 2ξ₂) of competing reactions: Dol + 2Qtz = Di + 2CO₂ (ξ₁) and 2Dol + Qtz = Fo + 2Cal + 2CO₂ (ξ₂). For smaller P the stability field will shift to higher values of a and b. The steady diffusion model also shows that the apparent‐non‐reactivity on the quartz surface can be attributed to void formation in a large volume fraction in the diopside layer.     

Wave energy in surface layers for energy-based damage evaluation

Seismic wave energy in surface layers is calculated based on vertical array records at four sites during the 1995 Hyogo-ken Nambu earthquake by assuming vertical propagation of SH waves. The upward energy generally tends to decrease as it goes up from the base layer to the ground surface particularly in soft soil sites. Theoretical study on 1D multi-layers model to investigate the basic energy flow mechanism indicates that the energy at the ground surface can be smaller on softer soils due to high soil damping during strong shaking even if resonance effect is considered. A simple calculation for a shear-vibrating structure resting on foundation ground shows that induced strain in the structure is directly related to the energy or the energy flux of surface layers. Hence, a general perception that soft soil sites tend to suffer heavier damage than stiff sites should be explained not by greater incident energy but by other reasons such as degree of resonance. Furthermore, it is recommended that not only acceleration or velocity but also S-wave velocity should be specified at a layer where a design seismic motion is given, so that the seismic wave energy can clearly be quantified in seismic design practice.     

Symmetrical fft technique and its applications to earthquake engineering

The objective of this paper is to propose an FFT technique symmetrical for time and frequency, in which the symmetrization is done by introducing generating functions. By the symmetrical treatment, it becomes possible to derive several complementary relations in the time and frequency domains. Based on the idea of the symmetrical FFT technique, the phase problem of seismic waves is discussed not only in the frequency domain but also in the time domain. Furthermore, the deconvolution technique to evaluate the minimum-phase-shift and all-pass functions of seismic waves, which is not discussed sufficiently in earthquake engineering, is developed in the two domains. Numerical examples to present these basic ideas are also illustrated in the symmetrical framework.     

Mesozoic radiolarians and radiolarian-bearing sequences in the circum-Pacific regions: A report of the symposium-'Radiolarians and Orogenic Belts'

Abstract This paper contains extended abstracts of the seven papers presented at the symposium 'Radiolarians and Orogenic Belts' held at the seventh meeting of the International Association of Radiolarian Paleontologists (INTERRAD). Important results of the symposium include the following: (1) Upper Paleozoic and Mesozoic cherts are widely distributed within accretionary complexes in the circum-Pacific orogenic belt. Radiolarian dating reveals that long durations of chert sedimentation in a pelagic environment are recorded on both sides of Pacific-rim accretionary complexes (e.g. New Zealand, Japan, Russian Far East, Canadian Cordillera). (2) Triassic radiolarian faunas from New Zealand and the Omolon Massif, northeast Siberia are similar in composition and are characterized by the absence of typical Tethyan elements. This suggests that radiolarian faunal provincialism may have been established as early as the Triassic. High-latitude radiolarian taxa exhibit a bi-polar distribution pattern. (3) The Lower Triassic interval in chert dominant pelagic sequences is mechanically weaker than other levels and acted as a décollement in accretionary events. This lithologic. contrast in physical property is considered to reflect radiolarian evolution, such as the end-Permian mass extinction.     

Classification and distribution of Oligocene Aetiocetidae (Mammalia; Cetacea; Mysticeti) from western North America and Japan

Abstract Fossil whales in the very rare, primitive, extinct cetacean family Aetiocetidae are small, relict, toothed mysticetes that persisted into Late Oligocene time after more highly derived baleen-bearing mysticetes had already evolved. No known aetiocetid could be ancestral to baleen-bearing mysticetes, but aetiocetid morphology is in many ways intermediate between archaeocetes and baleen-bearing mysticetes, demonstrating the probable transitional steps passed through in the evolution of baleen-bearing mysticetes. Their discovery indicates that mysticetes evolved from Archaeocetes, and supports theories of the monophyly of Cetacea. Late Oligocene aetiocetids have been found on both sides of the North Pacific Ocean: on Vancouver Island, British Columbia, Canada; in Oregon and Washington, USA; in Baja California Sur, México; and the islands of Kyushu and Hokkaido, Japan. The most primitive North American aetiocetid, Chonecetus sookensis Russell, 1968, is from the early Late Oligocene Hesquiat Formation on Vancouver Island, British Columbia, Canada. A more derived, Late Oligocene species, Chonecetus goedertorum Barnes and Furusawa, new species, from the Late Oligocene Pysht Formation, Olympic Peninsula, Washington, has the primitive placental mammalian tooth count of 11/11. The type genus of the family, Aetiocetus Emlong, 1966, has as its type species, A. cotylalveus Emlong, 1966, known only from the Late Oligocene Yaquina Formation on the coast of Oregon. It has 11 upper teeth on each side of the rostrum. A more derived species, Aetiocetus weltoni Barnes and Kimura, new species, from a higher stratigraphic level in the Yaquina Formation, has a more posteriorly positioned cranial vertex and a tooth count of 11/12. We describe four new species of aetiocetids in three genera from the Late Oligocene Morawan Formation near Ashoro, Hokkaido, Japan. The most primitive, Ashorocetus eguchii Barnes and Kimura, new genus and species, has a primitive stage of cranial telescoping, and is closely related to Chonecetus Russell, 1968. Another, Morawanocetus yabukii Kimura and Barnes, new genus and species, in some ways intermediate between Chonecetus and Aetiocetus, has a suite of unique derived characters, including a much foreshortened brain case. The third, Aetiocetus tomitai Kimura and Barnes, new species, is the most primitive species of Aetiocetus yet discovered. The fourth, Aetiocetus polydentatus Sawamura, new species, the most derived species of Aetiocetus known, has a highly telescoped cranium, homodonty, polydonty and a dental count of 13–14/14–15. The fossil record now indicates considerable diversity in the family, with several different contemporaneous lineages in three new subfamilies: Chonecetinae, Morawanocetinae and Aetiocetinae. Aetiocetids are not known outside the North Pacific. Many Recent mysticetes are essentially cosmopolitan, and aetiocetids might have also been relatively widely dispersed. We suspect that with time their remains will be found around other ocean basins also. If so, then they may be potentially useful in trans-oceanic geological correlations.     

Finite element analysis and experimental verification of the scrap tire rubber pad isolator

A new base isolation system using scrap tire rubber pads (STRP) has been introduced for seismic mitigation of ordinary residential buildings. The rubber and the steel reinforcing cords used in manufacturing the tire are the alternative materials of the proposed base isolation system. The steel reinforcing cords represent the steel plates used in conventional laminated rubber bearings. These steel reinforcing cords shall prevent the lateral bulging of the rubber bearing. The proposed base isolation system has no bonding between the superstructure and the foundation beam which allows for rollover deformation. In the first part of the study, the STRP layers were just stacked one on top of another without applying the adhesive. This paper presents loading test as well as finite element analysis (FE analysis) of strip STRP isolators that are subjected to any given combination of static vertical and lateral loads. The results of the static vertical and horizontal loading test conducted on STRP isolators were used to calculate the mechanical properties of the isolators, including stiffness and damping values. The load–displacement relationship of STRP isolators were compared between experimental and FE analysis results and the results were found to be in close agreement. The stress state within the STRP isolators was also analyzed in order to estimate the maximum stress demand in the rubber and steel reinforcing cords. These STRP isolators have several advantages over conventional laminated rubber bearings including superior damping properties, lower incurred cost, light weight and easily available material. This study suggests that using the STRP as low cost base isolation device for ordinary residential buildings is feasible.     

Dynamic FE simulation of four‐story steel frame modeled by solid elements and its validation using results of full‐scale shake‐table test

Dynamic finite element analyses of a four‐story steel building frame modeled as a fine mesh of solid elements are performed using E‐Simulator, which is a parallel finite element analysis software package for precisely simulating collapse behaviors of civil and building structures. E‐Simulator is under development at the National Research Institute for Earth Science and Disaster Prevention (NIED), Japan. A full‐scale shake‐table test for a four‐story frame was conducted using E‐Defense at NIED, which is the largest shaking table in the world. A mesh of the entire structure of a four‐story frame with approximately 19 million degrees of freedom is constructed using solid elements. The density of the mesh is determined by referring to the results of elastic–plastic buckling analyses of a column of the frame using meshes of different densities. Therefore, the analysis model of the frame is well verified. Seismic response analyses under 60, 100, and 115% excitations of the JR Takatori record of the 1995 Hyogoken‐Nanbu earthquake are performed. Note that the simulation does not reproduce the collapse under the 100% excitation of the Takatori record in the E‐Defense test. Therefore, simulations for the 115% case are also performed. The results obtained by E‐Simulator are compared with those obtained by the E‐Defense full‐scale test in order to validate the results obtained by E‐Simulator. The shear forces and interstory drift angles of the first story obtained by the simulation and the test are in good agreement. Both the response of the entire frame and the local deformation as a result of elastic–plastic buckling are simulated simultaneously using E‐Simulator. Copyright © 2014 John Wiley & Sons, Ltd.     

Simulation of the effect of wind speedup in the formation of transverse dune fields

A computer simulation model for transverse‐dune‐field dynamics, corresponding to a uni‐directional wind regime, is developed. In a previous formulation, two distinct problems were found regarding the cross‐sectional dune shape, namely the erosion in the lee of dunes and the steepness of the windward slopes. The first problem is solved by introducing no erosion in shadow zones. The second issue is overcome by introducing a wind speedup (shear velocity increase) factor, which can be accounted for by adding a term to the original transport length, which is proportional to the surface height. By incorporating these features we are able to model dunes whose individual shape and collective patterns are similar to those observed in nature. Moreover we show how the introduction of a non‐linear shear‐velocity‐increase term leads to the reduction of dune height, and this may result in an equilibrium dune field configuration. This is thought to be because the non‐linear increase of the transport length makes the sand trapping efficiency lower than unity, even for higher dunes, so that the incoming and the outgoing sand flux are in balance. To fully describe the inter‐dune morphology more precise dynamics in the lee of the dune must be incorporated. Copyright © 2000 John Wiley & Sons, Ltd.     

Groundwater-level Changes Due to Pressure Gradient Induced by Nearby Earthquakes off Izu Peninsula, 1997

Anomalous water level changes were observed at two wells associated with seismic swarm activity off Izu Peninsula on March, 1997. These are coseismic water level drops followed by gradual postseismic water level rise at the time of large earthquakes during the swarm activity. The post-seismic water level rises, which can be fitted by an exponential function with a time constant of about six hours, are explained in terms of the horizontal pressure diffusion due to the pressure gradient in the aquifer induced by the coseismic static strain.