A New Coastal Marine Ecosystem Model Study Coupled with Hydrodynamics and Tidal Flat Ecosystem Effect

A new coastal marine ecosystem model was developed, which was composed of pelagic and benthic ecosystems, and was applied to Mikawa Bay, Japan. This model deals with variations of biochemical and physical interactions among dissolved oxygen and C–N–P species (composition formed out of carbon, nitrogen and phosphorus elements) so that it resolves the flux dynamics of carbon, nitrogen, phosphorus and oxygen elements. The physical and biochemical mechanism figured in this model is constructed for the purpose of simulating the estuarine lower trophic ecosystem, in areas where the sea was too deep for light to reach the sea-bottom. As a result of coupling the benthic with pelagic system, the effect of process of sedimentation and nutrient diffusion back to the pelagic system could be indicated. In addition, by implementing the tidal flat ecosystem model's calculation result, the integrated model can include the effect of water purification in tidal flats where the light can reach the sea-bottom, and where sea-weed, sea grass and benthic algae exist. In this study, the model indicates that oxygen-depleted water exists at the sea-bottom especially in summer mainly caused by an increase of oxygen consumption in the benthic system and a decrease of the vertical mixing water process. Furthermore, by comparing the case – with the tidal flat ecosystem model and the case without it, the effect of water purification of tidal flat estuaries was indicated. From the viewpoint of a short time scale, the tidal flat has the potential to restrict red tide (rapid increase of phytoplankton), and from the viewpoint of a long time scale, it restricts the sedimentation of detritus. Restricting the sedimentation prevents oxygen-depleted water occurring in the coastal marine system of Mikawa Bay.     

Mesozoic radiolarians and radiolarian-bearing sequences in the circum-Pacific regions: A report of the symposium-'Radiolarians and Orogenic Belts'

Abstract This paper contains extended abstracts of the seven papers presented at the symposium 'Radiolarians and Orogenic Belts' held at the seventh meeting of the International Association of Radiolarian Paleontologists (INTERRAD). Important results of the symposium include the following: (1) Upper Paleozoic and Mesozoic cherts are widely distributed within accretionary complexes in the circum-Pacific orogenic belt. Radiolarian dating reveals that long durations of chert sedimentation in a pelagic environment are recorded on both sides of Pacific-rim accretionary complexes (e.g. New Zealand, Japan, Russian Far East, Canadian Cordillera). (2) Triassic radiolarian faunas from New Zealand and the Omolon Massif, northeast Siberia are similar in composition and are characterized by the absence of typical Tethyan elements. This suggests that radiolarian faunal provincialism may have been established as early as the Triassic. High-latitude radiolarian taxa exhibit a bi-polar distribution pattern. (3) The Lower Triassic interval in chert dominant pelagic sequences is mechanically weaker than other levels and acted as a décollement in accretionary events. This lithologic. contrast in physical property is considered to reflect radiolarian evolution, such as the end-Permian mass extinction.     

Age model, physical properties and paleoceanographic implications of the middle Pleistocene core sediments in the Choshi area, central Japan

Abstract   A continuous, well-preserved core was obtained from the Choshi area, on the Pacific side of Japan, to investigate paleoceanographic and paleoclimatic changes around the northwestern Pacific region during the middle Pleistocene. Siliciclastic sequences in the core are divided into five formations – the Obama, Yokone, Kurahashi and Toyosato Formations in the Inubo Group and the Katori Formation, in ascending order. Examination of calcareous nannofossils and magnetic polarities detected four datums in the core sediments of the Inubo Group: the top of Reticulofenestra asanoi , the base of Helicosphaera inversa , the top of Pseudoemiliania lacunosa and the Brunhes–Matuyama boundary. Fourteen marine isotope stages (MIS24–MIS11) were identified in the δ¹⁸O and δ¹³C records based on detected datums and the graphic correlation with the standard stack oxygen isotope curve. Magnetic susceptibility and gamma-ray attenuation porosity evaluator density were also measured and low values characterize the glacial intervals. Biogenic sedimentation by primary production may be larger during the glacial periods because of invasions of nutrient-rich northern surface-waters related to the southward shift of the Kuroshio front in the Choshi area.     

Pressure dependence on partition coefficients for trace elements between olivine and the coexisting melts

Partition coefficients between olivine and melt at upper mantle conditions, 3 to 14 GPa, have been determined for 27 trace elements (Li, Be, B, Na, Mg, Al, Si, P, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Rb, Sr, Y, Zr, Cs, Ba, La and Ce) using secondary-ion mass-spectrometry (SIMS) and electron-probe microanalysis (EPMA). The general pattern of olivine/melt partitioning on Onuma diagrams resembles those reported previously for natural systems. This agreement strongly supports the argument that partitioning is under structural control of olivine even at high pressure. The partition coefficients for mono- and tri-valent cations show significant pressure dependence, both becoming larger with pressure, and are strongly correlated with coupled substitution into cation sites in the olivine structure. The dominant type of trace element substitution for mono- and tri-valent cations into olivine changes gradually from (Si, Mg)↔(Al, Cr) at low pressure to (Si, Mg)↔(Al, Al) and (Mg, Mg)↔(Na, Al) at high pressure. The change in substitution type results in an increase in partition coefficients of Al and Na with pressure. An inverse correlation between the partition coefficients for divalent cations and pressure has been observed, especially for Ni, Co and Fe. The order of decreasing rate of partition coefficient with pressure correlates to strength of crystal field effect of the cation. The pressure dependence of olivine/melt partitioning can be attributed to the compression of cation polyhedra induced by pressure and the compensation of electrostatic valence by cation substitution. Received: March 6, 1997 / Revised, accepted: March 12, 1998     

Fast Oxidation Reaction of Nitrite by Dissolved Oxygen in the Freezing Process in the Tropospheric Aqueous Phase

Nitrite oxidation in the tropospheric aqueous phase by freezing was evaluated by freezing a field sample. Nitrite oxidation by dissolved oxygen in the freezing process is much faster than by other oxidation processes, such as reactions with ozone, hydrogen peroxide or dissolved oxygen in an aqueous solution at pHs 3 to –6. At pH 4.5 and 25°C, the lifetime of nitrite in the aqueous phase is ca. 1 hr in oxidation by ozone (6×10^-10 mol dm^-3), ca. 10 hr in oxidation by H₂O₂ (2×10^-4 mol dm^-3), and 7.5 hr (Fischer and Warneck, 1996) in photodissociation at midday in summer. Under the same conditions at a temperature below 0°C, the lifetime of nitrite in the freezing process is estimated as ca. 2 sec when the droplets are frozen within a second. The reaction by freezing is affected by the presence of salts, such as NaCl or KCl, or orgnaic compounds, such as methanol or acetone. The results of freezing a field rain or fog sample showed that nitrite oxidation proceeds below pH 6, and the conversion ratio of nitrate from nitrite increases with decreasing pH. The oxidation of nitrite by freezing was also observed in freezing fog particles generated by an ultrasonic humidifier. The ratios of the concentrations of ions in the winter sample to those in the summer sample (or those in the fog sample) were almost the same values. However, the concentration of nitrite in the winter sample was lower than that estimated by the ratios of other ions. From the present study, it seems that the freezing process plays an important role in the nitrite sink process in the tropospheric aqueous phase.     

ESR diagram: a method to distinguish vitrinite macerals

It has been found that samples consisting of a homogeneous vitrinite show a good ESR correlation of spin concentration with geothermal parameters and that a graph of ESR line width vs g-value can be useful in the identification of the maceral and the determination of the coalification rank.     

The theory of the nutation for the rigid earth model at the second order

We perform a complete reconstruction of the series of the nutation for a rigid Earth model with the use of the very accurate theories ELP2000 and VSOP82 for the motion of the Moon and the planets respectively, in such a way that all the individual contributions up to 0.005 mas should be taken. This implies the introduction of the planetary effects, of the influence of second-order parts of the potential of the Earth (J3, triaxiality), and some improvements due to an extension of the theory at the second order. All this increase notably the number of coefficients to be taken in account, and modifies also in a significant way the value of some of them.     

Large-Eddy Simulation of Pollutant Removal from a Three-Dimensional Street Canyon

Large-eddy simulations were conducted to investigate the mechanism of pollutant removal from a three-dimensional street canyon. Five block configurations with aspect ratios (building height to length) of 1, 2, 4, 8 and $\infty $ were used to create an urban-like array. A pollutant was released from a ground-level line source at the centre of the target canyon floor. For smaller aspect ratios, the relative contribution of the turbulent mass flux to net mass flux at the roof level, which was spatially averaged along the roof-level ventilation area, was closer to unity, indicating that turbulent motions mainly affected pollutant removal from the top of the canyon. As aspect ratio increased, the relative contribution became smaller, owing to strong upwind motions. However, the relative contribution again reached near unity for the infinite aspect ratio (i.e. a two-dimensional street canyon) because of lowered lateral flow convergence. At least 75 % of total emissions from the three-dimensional street canyon were attributable to turbulent motions. Pollutant removal by turbulent motions was related to the coherent structures of low-momentum fluid above the canyons. Though the coherent structure size of the low-momentum fluid differed, the positions of low-momentum fluid largely corresponded to instantaneous high concentrations of pollutant above the target canyon, irrespective of canyon geometry.