Analyses Of Jovian Decametric Radiation -Bursts Interacting With N-Bursts

Dynamic spectra of S-bursts of Jovian decametric radiations are obtained by using a high time resolution radio spectrograph which has a time resolutionof 2 msec and the bandwidth of 2 MHz.Within occurrence of 65 S-burst events observed in the period from 1983 to 1999, 26 events have been identified as the S-N burst events, which are characterized by the interaction between the S-burst emissions and the Narrow band emissions. In the dynamic spectra of the S-N burst, the trend of emissions with negative and slower frequency drift named as “Trailing Edge Emission” are often observed shortly after the appearance of the S-burst.Detailed analyses of these phenomena revealed that the Trailing Edge Emission is not a manifestation of S-burst with slower drift rate but a variation ofN-burst. The results suggested that S-burst and the associated Trailing Edge Emission are formed simultaneously started from a common region with different drift rates. It has been further suggested that the appearance of the S-burstsis not controlled by the geometrical effect between the source region and theobserver, but directly reflects the generation of the source region widelydistributed in an altitude range from a few thousands km to 30,000 km, alongthe Io flux tube. This revised version was published online in July 2006 with corrections to the Cover Date.     

Improved Estimates of Wide-Ranging Sea Surface Temperature from GMS S-VISSR Data

We have developed an algorithm to estimate the wide-ranging Sea Surface Temperature (SST) data from the GMS-5 (Geostationary Meteorological Satellite) S-VISSR (Stretched-Visible Infrared Spin Scan Radiometer). Better SST estimates are realized by averaging the temporal variation of the VISSR calibration table and decreasing noise of the split-window terms using a spatial filter. The effects of the satellite zenith angle were examined in detail for better estimates, and VISSR-derived SSTs with root-mean-square (rms) error of 0.8 K were achieved using a new algorithm. The accuracy of SST estimates has been improved by using the temporal-spatial average of the split-window terms. Using the new techniques, we demonstrate that the hourly wide-ranging SST image data can be used to study the daily variations of SSTs in the Northern and Southern Pacific Oceans.     

贵阳地表水-地下水的硫和氯同位素组成特征及其污染物示踪意义

喀斯特地表水和地下水的交换活跃,地下水系统容易受到地表污染物的污染。为了解喀斯特城市地表水—地下水系统污染特征和污染物质来源,对贵阳市地表水、地下水、雨水和城市排污污水的硫同位素和氯同位素组成变化进行了研究。贵阳市不同类型水体的δ³⁷Cl值在-4.07‰～+2.03‰之间变化,δ34SSO4值变化为-20.4‰～+20.9‰。大气输入物质和城市排污污水的δ³⁷Cl、δ³⁴S及Cl^-/SO₄^2-比值与地表水和地下水的不同,稳定硫和氯同位素的结合研究为示踪地下水污染物来源提供了有效研究手段。贵阳市地下水中的Cl^-和SO^₄2-至少有4种来源,人为活动通过城市排污和大气输入向地下水系统大量输入了硫酸盐和氯离子。      

Trace element distribution in mineral separates of the Allende inclusions and their genetic implications

Concentrations of the REE, Sc, Co, Fe, Zn, Ir, Na and Cr were determined by instrumental neutron activation and mass spectrometric isotope dilution analysis for mineral separates of the coarseand fine-grained types (group I and II of Martin and Mason's classification) of the Allende inclusions.These data, combined with data on mineral/liquid partition coefficients, oxygen isotope distributions and diffusion calculations, suggest the following: (1) Minerals in the coarse-grained inclusions (group I) crystallized in a closed system with respect to refractory elements. On the other hand, differences in oxygen isotope distributions among minerals preclude a totally molten stage in the history of the inclusion. Group I inclusions were formed by rapid condensation (either to liquid or solid) in a supercooled solar nebula; extrasolar pyroxene and spinel dust were included but not melted in the condensing inclusions, thus preserving their extrasolar oxygen isotope composition. REE were distributed by diffusion during the subsequent heating at subsolidus temperatures; because oxygen diffuses much more slowly at these temperatures, the oxygen isotope anomalies were preserved. (2) The fine-grained (group II) inclusions were also formed by condensation from a super-cooled nebular gas; however, REE-rich clinopyroxene and spinel were formed early and REE-poor sodalite and nepheline were formed later and mechanically mixed with clinopyroxene and spinel to form the inclusions. The REE patterns of the bulk inclusions and the mineral separates are fractionated, indicating that REE abundances in the gaseous phase were already fractionated at the time of condensation of the minerals. (3) Pre-existing Mg isotope anomalies in the coarse-grained inclusions must have been erased during the heating stage thus resetting the ²⁶Al-²⁶Mg chronometer.     

Seasonal variations of spectra of wind speed and air temperature in the mesoscale frequency range

Seasonal variations of the spectra of wind speed and air temperature in the mesoscale frequency range from 1.3 × 10^-4 to 1.5 × 10^-3 Hz (10 min to 2 h periods) have been studied through observations over land for one year. Spectrographs [time series of isopleths of spectral densities, f · S(f) vs f] of wind speed and air temperature contain occasional peaks that are attributed to short-lived mesoscale atmospheric activity with narrow frequency bands. Significant spectral peaks of wind speed were found in 19% of the total observations in winter, and in 15–16% in the other seasons; for air temperature, they occured in 12% of observations in autumn, and in 16–19% in the other seasons. The peaks most often occurred in the period range from 30 min to 1 h; most had durations less than 24 h. Mesoscale fluctuations of wind speed and air temperature were highly correlated, and in most cases, phase differences were 90–180 ° with air temperature leading wind speed. Significant spectral peaks of wind speed often occurred during northerly seasonal cold winds in winter, and accompanied tropical and/or mid-latitude cyclones in the other seasons. When the peaks occurred, wind speed was usually relatively high and the atmospheric surface layer was unstable.     

Carbon and Noble Gas Isotopes in the Tengchong Volcanic Geothermal Area, Yunnan, Southwestern China

Carbon and noble gas isotope analyses are reported for bubbling gas samples from the Tengchong volcanic geothermal area near the Indo-Eurasian suture zone. All samples contain a resolvable component of mantle-derived 3He. Occurrence of mantle-derived 3He coincides with surface volcanism. However, 3He occurs over a larger geographic areathan do surface volcanics. δ13C values for CO2 and CH4 vary from -33.4‰ to 1.6 ‰ and from -52.8‰ to -2.8‰, respectively. He and C isotope systematics indicate that CO2 and CH4 in the CO2-rich gases originated predominantly from magmatic component mixed with crustal CO2 produced from carbonate. However, breakdown of organic matter and near-surface processes accounts for the CH4 and CO2 in N2-rich gases. 3He/4He ratio distribution pattern suggests that mantle-derived He and heat sources of high-temperature system in central Tengchong originate from a hidden magma reservoir at subsurface. CO2-rich gases with the highest 3He/4He ratio (5.2 Ra) may be representative of the     

Simulations of seasonal variations of sulfur compounds in the remote marine atmosphere

A photochemical box model is used to simulate seasonal variations in concentrations of sulfur compounds at latitude 40° S. It is assumed that the hydroxyl radical (OH) addition reaction to sulfur in the dimethyl sulfide (DMS) molecule is the predominant pathway for methanesulfonic acid (MSA) production, and that the rate constant increases as the air temperature decreases. Concentration of the nitrate radical (NO₃) is a function of the DMS flux, because the reaction of DMS with NO₃ is the most important loss mechanism of NO₃. While the diurnally averaged concentration of OH in winter is a factor of about 8 smaller than in summer, due to the weak photolysis process, the diurnally averaged concentration of NO₃ in winter is a factor of about 4–5 larger than in summer, due to the decrease of DMS flux. Therefore, at middle and high latitudes in winter, atmospheric DMS is mainly oxidized by the reaction with NO₃. The calculated ratio of the MSA to SO₂ production rates is smaller in winter than in summer, and the MSA to non-sea-salt sulfate (nssSO₄ ^2-) molar ratio varies seasonally. This result agrees with data on the seasonal variation of the MSA/nssSO₄ ^2- molar ratio obtained at middle and high latitudes. The calculations indicate that during winter the reaction of DMS with NO₃ is likely to be a more important sink of NO_x (NO+NO₂) than the reaction of NO₂ with OH, and to serve as a significant pathway of the HNO₃ production. If dimethyl sulfoxide (DMSO) is produced through the OH addition reaction and is heterogeneously oxidized in aqueous solutions, half of the nssSO₄ ^2- produced in summer may be through the oxidation process of DMSO. It is necessary to further investigate the oxidation products by the reaction of DMS with OH, and the possibility of the reaction of DMS with NO₃ during winter.     

Numerical study of the oxidation process of dimethylsulfide in the marine atmosphere

A box model, involving simple heterogeneous reaction processes associated with the production of non-sea-salt sulfate (nss-SO ₄ ^2– ) particles, is used to investigate the oxidation processes of dimethylsulfide (DMS or CH₃SCH₃) in the marine atmosphere. The model is applied to chemical reactions in the atmospheric surface mixing layer, at intervals of 15 degrees latitude between 60° N and 60° S. Given that the addition reaction of the hydroxyl radical (OH) to the sulfur atom in the DMS molecule is faster at lower temperature than at higher temperature and that it is the predominant pathway for the production of methanesulfonic acid (MSA or CH₃SO₃H), the results can well explain both the increasing tendency of the molar ratio of MSA to nss-SO ₄ ^2– toward higher latitudes and the uniform distribution with latitude of sulfur dioxide (SO₂). The predicted production rate of MSA increases with increasing latitude due to the elevated rate constant of the addition reaction at lower temperature. Since latitudinal distributions of OH concentration and DMS reaction rate with OH are opposite, a uniform production rate of SO₂ is realized over the globe. The primary sink of DMS in unpolluted air is caused by the reaction with OH. Reaction of DMS with the nitrate radical (NO₃) also reduces DMS concentration but it is less important compared with that of OH. Concentrations of SO₂, MSA, and nss-SO ₄ ^2– are almost independent of NO _x concentration and radiation field. If dimethylsulfoxide (DMSO or CH₃S(O)CH₃) is produced by the addition reaction and further converted to sulfuric acid (H₂SO₄) in an aqueous solution of cloud droplets, the oxidation process of DMSO might be important for the production of aerosol particles containing nss-SO ₄ ^2– at high latitudes.     

An Improved Mellor–Yamada Level-3 Model: Its Numerical Stability and Application to a Regional Prediction of Advection Fog

This note describes a numerically stable version of the improved Mellor–Yamada (M–Y) Level-3 model proposed by Nakanishi and Niino [Nakanishi, M. and Niino, H.: 2004, Boundary-Layer Meteorol. 112, 1–31] and demonstrates its application to a regional prediction of advection fog. In order to ensure the realizability for the improved M–Y Level-3 model and its numerical stability, restrictions are imposed on computing stability functions, on L/q, the temperature and water-content variances, and their covariance, where L is the master length scale and q ²/2 the turbulent kinetic energy per unit mass. The model with these restrictions predicts vertical profiles of mean quantities such as temperature that are in good agreement with those obtained from large-eddy simulation of a radiation fog. In a regional prediction, it also reasonably reproduces the satellite-observed horizontal distribution of an advection fog.