Ultra-high Excess Argon in Kyanites: Implications for Ultra-high Pressure Metamorphism in Northeast Japan

A laser fusion Ar-Ar technique applied on single crystals of kyanite from river sands of the Kitakami Mountain region of northeast Japan yielded ages of up to 16 Ga, more than three times the age of the earth. Although the age values are geologically meaningless, the ultra-high excess argon in kyanites is unique and hitherto unreported. We interpret this to be an artifact of ultra-high argon pressure derived from radiogenic argon in potassium-rich phases such as phengites during the Barrovian type retrogression of the ultra-high pressure rocks in this region.     

Trends and relationships in victims’ recovery perceptions: a case study of the recovery process following the Great East Japan Earthquake

Natural Hazards - In the aftermath of a disaster, the recovery process has long-term, multi-dimensional, and interactive aspects. To clarify the recovery conditions and victims’ perceptions...     

Strength estimation and stress–dilatancy characteristics of natural gas hydrate-bearing sediments under high effective confining pressure

Acta Geotechnica - Gas production by depressurization can significantly increase the effective stress in hydrate-bearing sediments. Therefore, strength and deformation characteristics of sediments...     

GeoFEM Kinematic Earthquake Cycle Simulation in Southwest Japan

— We construct a viscoelastic FEM model with 3-D configuration of the subducting Philippine Sea plate in Southwest Japan to simulate recent 300-year kinematic earthquake cycles along the Nankai-Suruga-Sagami trough, based on the kinematic earthquake cycle model. This 300-year simulation contains a series of three great interplate earthquakes. The inclusion of viscoelasticity produces characteristic velocity field during earthquake cycles regardless of the assumed constant plate coupling throughout the interseismic period. Just after the occurrence of interplate earthquakes, the viscoelastic relaxation creates the seaward motion in the inland region. In the middle period, the seaward motion gradually decreases, and the resultant velocity field is similar to the elastic one. Later, just before the next interplate earthquake, displacements due to the interplate coupling in the viscoelastic material are distributed more broadly in the forearc region than in the purely elastic one, since the viscoelastic relaxation due to the previous earthquake mostly disappears. The effects of such interplate earthquake cycles on five major inland faults in southwest Japan, where large intraplate earthquakes occurred during this period, are quantitatively evaluated using the Coulomb failure function (CFF). The calculated change in CFF successfully predicts the occurrence of the 1995 Kobe earthquake (M～7). The occurrence of other inland earthquakes, however, cannot be explained by the calculated changes in CFF, and especially the 1891 Nobi earthquake (M～8), the largest inland earthquake in Japan, which occurred at the time close to the local minimum of CFF. This implies that further improvements are necessary for our FEM modeling, such as the modeling of steady east-west compressive force and stress interactions between the inland faults.     

K–Ar and 40Ar/39Ar phengite ages of Sanbagawa schist clasts from the Kuma Group, central Shikoku, southwest Japan

Conglomerates of the Kuma Group, central Shikoku, southwest Japan contain Sanbagawa schist clasts with a variety of metamorphic grades and lithologies. K–Ar and ⁴⁰Ar/³⁹Ar dating of phengite show all the pelitic schist clasts from low- to high-grade zones have similar phengite ages (82–84 Ma) that are significantly older than those from the in situ Sanbagawa sequence of central Shikoku. This is because the Kuma–Sanbagawa sequence was exhumed earlier than the in situ Asemi sequence with an exhumation process intermediate between those for the Kanto Mountains and the in situ Asemi sequences. ⁴⁰A/³⁹Ar plateau ages (103 and 117 Ma) of phengite in amphibolites indicate the timing of the early stage of the exhumation of the metamorphic pile, probably close to the peak metamorphic age.     

Refinement of the age of the Middle Miocene Fort Ternan Beds,Western Kenya,and its implications for Old World biochronology

It has become increasingly obvious over the past two decades that the fossiliferous strata at Fort Ternan, Kenya, are probably somewhat younger than 14 Ma, an age which has long been attached to the deposits. This realisation flows from geological and biochronological observations. In order to test the hypothesis, resampling of all the lava flows in the region of Fort Ternan was undertaken in 2003, especially those underlying the Fort Ternan Beds in the Kipchorion Gorge where the sequence is the most complete. Samples obtained from lava flows underlying and overlying the fossil beds were analysed for anorthoclase K/Ar and ⁴⁰Ar/³⁹Ar and biotite ⁴⁰Ar/³⁹Ar age determinations. The results reveal that the age of the fossiliferous sediments is ca $13.7\pm 0.3\text{Ma}$. Since Fort Ternan yielded the ‘core fauna’ that defines Faunal Set IV of the East African biochronological sequence this refinement of its age will impact on age estimates of neighbouring Faunal Sets, as well as on other faunas correlated to Fort Ternan, including those in Europe belonging to MN Zones MN 5, MN 6 and MN 7/8. To cite this article: M. Pickford et al., C. R. Geoscience 338 (2006).     

Regional-Scale Excess Ar wave in a Barrovian type metamorphic belt, eastern Tibetan Plateau

Laser step heating ⁴⁰Ar/³⁹Ar analysis of biotite and muscovite single crystals from a Barrovian type metamorphic belt in the eastern Tibetan plateau yielded consistent cooling ages of ca. 40 Ma in the sillimanite zone with peak metamorphic temperatures higher than 600°C and discordant ages from 46 to 197 Ma in the zones with lower peak temperatures. Chemical Th‐U‐Total Pb Isochron Method (CHIME) monazite (65 Ma) and sensitive high mass‐resolution ion microprobe (SHRIMP) apatite (67 Ma) dating give the age of peak metamorphism in the sillimanite zone. Moderate amounts of excess Ar shown by biotite grains with ages of 46 to 94 Ma at metamorphic grades up to the high‐grade part of the kyanite zone probably represent incomplete degassing during metamorphism. In contrast, the high‐grade part of the kyanite zone yields biotite ages of 130 to 197 Ma. The spatial distribution of these older ages in the kyanite zone along the sillimanite zone boundary suggests they reflect trapped excess argon that migrated from higher‐grade regions. The most likely source is muscovite that decomposed to form sillimanite. The zone with extreme amounts of excess argon preserves trapped remnants of an ‘excess argon wave’. We suggest this corresponds to the area where biotite cooled below its closure temperature in the presence of an elevated Ar wave. Extreme excess Ar is not recognized in muscovite suggesting that the entrapment of the argon wave by biotite took place when the rocks had cooled down to temperatures lower than the closure temperature of muscovite. The breakdown of phengite during ultrahigh‐pressure (UHP) metamorphism may be a key factor in accounting for the very old apparent ages seen in many UHP metamorphic regions. This is the first documentation of a regional Ar‐wave spatially associated with regional metamorphism. This study also implies that resetting of the Ar isotopic systems in micas can require temperatures up to 600°C; much higher than generally thought.     

Loss of 40Ar(rad) from leucite-bearing basanite at low temperature: implications on K/Ar dating.

The Bakony-Balaton Highland Volcanic Field (BBHVF) is located in the central part of Transdanubia, Pannonian Basin, with over 50 alkali basaltic volcanoes. The basanite plug of Hegyestu erupted in the first phase of volcanic activity. K/Ar and Ar/Ar ages were published for the BBHVF. K/Ar and Ar/Ar ages of the leucite-bearing basanite of Hegyestás were conflicting. This is caused by the special Ar retention feature of leucite in this basanite. K/Ar ages measured in the usual way were 25–45% younger, but after HCl treatment of the rock, or after reducing the baking temperature of the argon extraction line from 250°C to 150°C, they became similar to the Ar/Ar ages. All Ar/Ar determinations were performed after HF treatment. HCl treatment dissolved olivine, nepheline, leucite, magnetite and from 1-1 sample analcime or calcite. K dissolution studies from different locations of Hegyestü have shown that K content is mostly ≈2%, but it may decrease to ≈0.3%. HCl treatment dissolved 28.0–63.5% of the K content. The calculated K concentration for the dissolved part of samples with ~2%K was 4.02-6.42%: showing that leucite is responsible for the low temperature loss of ⁴⁰Ar(rad). Ar may release at low temperature from very finegrained mineral, or when the Ar release mechanism changes. A ⁴⁰Ar(rad) degassing spectrum has been recorded in the 55–295°C range of baking temperature and the data were plotted in the Arrhenius diagram. The diagram shows that a change of the structure in the 145–295°C range caused the loss of ⁴⁰Ar(rad). On fractions of HCl treated rock 7.56±0.17 Ma isochron K/Ar age has been determined. This is regarded as minimum age of eruption and it is similar to the Ar/Ar isochron age (7.78±0.07 Ma).     

Variations in the oxygen-isotope composition of ancient Lake Superior between 10,600 and 8,800 cal BP

Variations in the oxygen-isotope composition of paleo-water bodies in the Lake Superior Basin provide information about the timing and pathways of glacial meltwater inflow into and within the Lake Superior Basin. Here, the oxygen-isotope compositions of Lake Superior have been determined using ostracodes from four sediment cores from across the Basin (Duluth, Caribou and Ile Parisienne sub-basins, Thunder Bay trough). The δ¹⁸O values indicate that lake water (Lake Minong) at ~10,600–10,400 cal [~9,400–9,250] BP was dominated by glacial meltwater derived from Lake Agassiz and the Laurentide Ice Sheet (LIS). From that time to ~9,000 cal [~8,100] BP, a period associated with formation of thick varves across the Lake Superior Basin, the δ¹⁸O values of Lake Minong decreased even further (−24 to −28‰), symptomatic of an increasing influx of glacial meltwater. Its supply was reduced between ~9,000 and ~8,900 cal [~8,100–8,000] BP, and lake water δ¹⁸O values grew higher by several per mil during this period. Between ~8,900 and ~8,800 cal [~8,000–7,950] BP, there was a return to δ¹⁸O values as low as −29‰ in some parts of the Lake Superior Basin, indicating a renewed influx of glacial meltwater before its final termination at ~8,800–8,700 cal [~7,950–7,900] BP. The sub-basins in the Lake Superior Basin generally displayed very similar patterns of lake water δ¹⁸O values, typical of a well-mixed system. The final stage of glacial meltwater input, however, was largely expressed near its input (Thunder Bay trough) and recognizable in dampened form mainly in the Duluth sub-basin to the west. Water in the easternmost Ile Parisienne sub-basin was enriched in ¹⁸O relative to the rest of the lake, particularly after ~10,000 cal [~8,900] BP, probably because of a strong influence of local precipitation/runoff, and perhaps also enhanced evaporation. By ~9,200 cal [~8,250] BP, lake water δ¹⁸O values in the Ile Parisienne sub-basin were similar to the adjacent Lake Huron Basin, suggesting a strong hydraulic connection between the two water bodies, and common responses to southern Ontario’s shift to warmer and dry climatic conditions after ~9,000 cal [~8,100] BP.