Modification to the crystal structure of chlorite during early stages of its dissolution

Early stage processes of Mg-rich chlorite (clinochlore) dissolution were examined, focusing especially on the structural modification at grain edges during dissolution. Focused ion beam transmission electron microscopy sample preparation was applied to crystals dissolved in a flow-through reaction system at pH 3.0 and 25°C for 31 days. The obtained Si and Mg dissolution rates are −11.49 and −11.14 (logR, mol/(m²/s)), respectively, implying dissolution is non-stoichiometric. TEM-EDX analyses of dissolved samples reveal the development of 20–50-nm thick amorphous zone at an outermost rim with a chemical gradient of Mg, lower towards the solid surface, and Si enrichment in this amorphous zone. Crystalline material is partially interwoven with amorphous one at the interface between the amorphous and crystalline regions. These results indicate that the amorphous zone was produced by selective leaching of cations except for Si. Chlorite dissolution may proceed via the formation and thickening of leached layer as a by-product of release to solution of Si at slightly slower rate than Mg.     

Exsolved garnet-bearing pyroxene megacrysts from some South African kimberlites

Clinopyroxene and orthopyroxene megacrysts containing garnet lamellae up to 1.2 mm thick as an exsolved phase are found rarely in kimberlites from Frank Smith and Bellsbank. Chemically the clinopyroxenes are characteristically subcalcic, being within the range of 100 Ca/Ca + Mg + Fe = 27 to 36, and the orthopyroxenes are characterized by high Al₂O₃ and Cr₂O₃. Immediately after crystallization during very slow cooling, clinopyroxene and orthopyroxene exsolve wide-spaced orthopyroxene and clinopyroxene phases parallel to (100) of the host phases, respectively, then both host and exsolved phases exsolve garnet lamellae. Topotactic relations between pyroxenes and garnet are determined by X-ray for the first time. Partitioning of major and minor elements among the coexisting clinopyroxene, orthopyroxene and garnet in pyroxene megacrysts is the same as that of the granular-type garnet peridotite xenoliths in Lesotho and South African kimberlies. Mineralogy and chemistry indicate that subcalcic clinopyroxene and orthopyroxene megacrysts contain respectively about 10 and 3 mole % of the garnet molecule in solid solution.     

Polyphenols in the benzene-ethanol extractives of an organic soil

A variety of phenolic compounds has been isolated from a crude peat wax. The compounds have been analyzed by thin layer chromatography, gas chromatography and mass spectrometry.     

Complexes of activity of the solar cycle and very large scale convection

The magnetic field pattern associated with large scale convective motions, which are much larger than the supergranules and have been conceived as a source of maintenance of the solar differential rotation, is calculated in the framework of a slowly and differentially rotating thin spherical shell, including the effects of thermal conductivity and viscosity. The approximations of Boussinesq are used and the initial state of the magnetic field is assumed to be purely toroidal.The resulting magnetic field pattern rotates rigidly on the differentially rotating Sun with some phase delay to the convective pattern, if it is assumed that only the predominant mode with the maximum growth rate is actually realized in the solar convection zone. The obtained magnetic and convective patterns and their properties seem to explain naturally the various aspects of large scale ordering of solar activity such as the existence and behavior of complexes of activity, the rigid body rotation of proton flare active longitudes, their association with UMR's, the existence of ghost and mirror image of UMR's themselves and the fact that the rotational period derived from sunspot data is shorter than that derived spectroscopically from fluid velocity.     

Lake-level changes during the past 100,000 years at Lake Baikal, southern Siberia

Lake-level changes inferred from seismic surveying and core sampling of the floor of Lake Baikal near the Selenga River delta can be used to constrain regional climatic history and appear to be correlated to global climate changes represented by marine oxygen isotope stages (MIS). The reflection pattern and correlation to the isotope stages indicate that the topset and progradational foreset sediments of the deltas formed during periods of stable lake levels and warm climatic conditions. During warm stages, the lake level was high, and during cold stages it was low. The drop in the lake level due to cooling from MIS 5 through MIS 4 is estimated to be 33-38 m; from MIS 3 through MIS 2, it fell an additional 11-15 m. Because the lake level is chiefly controlled by evaporation and river input, we infer that more water was supplied to Lake Baikal during warm stages.     

Estimation of property loss and business interruption loss caused by storm surge inundation due to climate change: a case of Typhoon Vera revisit

This paper estimates property loss and business interruption loss under scenarios of storm surge inundation to explore the economic impact of climate change on Ise Bay, Japan. Scenarios-based analyses are conducted with respect to Typhoon Vera, which caused the most severe storm surge in the recorded history of Japan in 1959. Four different hazard scenarios are chosen from a series of typhoon storm surge inundation simulations: Typhoon Vera’s landfall with respect to the condition of the past seawall; Typhoon Vera’s landfall with respect to the condition of the current seawall; intensifying Typhoon Vera, but retaining its original tracks; and intensifying Typhoon Vera, but choosing the worst tracks from various possible typhoon tracks. Our economic loss estimation takes advantage of fine geographical scale census and economic census data that enable us to understand the spatial distribution of property loss and business interruption loss as well as identify the most potentially affected areas and business sectors on a sub-city scale. By comparing the property loss and business interruption loss caused by different hazard scenarios, the effect of different seawalls is evaluated and the economic impact of future climate change is estimated. The results indicate that although the current seawall can considerably reduce the scale of losses, climate change can cause Ise Bay to experience more serious storm surge inundation. Moreover, the resulting economic losses would increase significantly owing to a combination of climate change and the worst track scenario. It is, therefore, necessary to consider more countermeasures to adapt to climate change in this area.