无定形氢氧化铝的表面酸度

通过酸碱滴定法以及分析反应后的溶液和反应后固体的XRD表征等方法测定了合成氢氧化铝的表面酸度。XRD结果表现出4个宽峰,说明合成产物是无定形的。滴定实验的固体产物的XRD的分析表明,无定形的氢氧化铝在碱性的环境下(pH>10),迅速转化成为结晶的三羟铝石。滴定过程中和反应后的溶液分析计算出无定形氢氧化铝的溶解度,为1010.3。滴定实验中加入的酸或碱与溶解的铝和其表面羟基发生质子化作用或脱质子化作用。表面酸度常数,表面羟基密度和比表面积用FITEQL4.0进行了评价。无定形氢氧化铝的表面酸度@K.FUKUSHI$Research Center for…     

Using Strong Solar Coronal Emission Lines as Coronal Flux Proxies

We investigate the possibility that strong EUV lines observed with the Goddard Solar EUV Rocket Telescope and Spectrograph (SERTS) provide good proxies for estimating the total coronal flux over shorter wavelength ranges. We use coordinated SERTS and Yohkoh observations to obtain both polynomial and power-law fits relating the broad-band soft X-ray fluxes to the intensities of Fexvi 335 Ú and 361 Ú, Fexv 284 Ú and 417 Ú, and Mgix 368 Ú measured with SERTS. We found that the power-law fits best cover the full range of solar conditions from quiet Sun through active region, though not surprisingly the cooler Mgix 368 Ú line proves to be a poor proxy. The quadratic polynomial fits yield fair agreement over a large range for all but the Mgix line. However, the linear fits fail conspicuously when extrapolated into the quiet-Sun regime. The implications of this work for the Heii 304 Ú line formation problem are also briefly considered.     

The environments and clustering properties of 2dF Galaxy Redshift Survey selected starburst galaxies

We investigate the environments and clustering properties of starburst galaxies selected from the 2dF Galaxy Redshift Survey (2dFGRS) in order to determine which, if any, environmental factors play a role in triggering a starburst. We quantify the local environments, clustering properties and luminosity functions of our starburst galaxies and compare to random control samples. The starburst galaxies are also classified morphologically in terms of their broad Hubble type and evidence of tidal merger/interaction signatures. We find the starburst galaxies to be much less clustered on large (5–15 Mpc) scales compared to the overall 2dFGRS galaxy population. In terms of their environments, we find just over half of the starburst galaxies to reside in low to intermediate luminosity groups, and a further ∼30 per cent residing in the outskirts and infall regions of rich clusters. Their luminosity functions also differ significantly from that of the overall 2dFGRS galaxy population, with the sense of the difference being critically dependent on the way their star formation rates are measured. In terms of pin-pointing what might trigger the starburst, it would appear that factors relating to their local environment are most germane. Specifically, we find clear evidence that the presence of a near neighbour of comparable luminosity/mass within 20 kpc is likely to be important in triggering a starburst. We also find that a significant fraction (20–30 per cent) of the galaxies in our starburst samples have morphologies indicative of either an ongoing or a recent tidal interaction and/or merger. These findings notwithstanding, there remain a significant portion of starburst galaxies where such local environmental influences are not in any obvious way playing a triggering role, leading us to conclude that starbursts can also be internally driven.     

Effects of ulvoid (Ulva spp.) accumulation on the structure and function of eelgrass (Zostera marina L.) bed

The objective of this study is to clarify the effect of ulvoid (Ulva spp.) accumulation on the structure and function of an eelgrass bed by the coast of Iwakuni, Seto Inland Sea, Japan. We monitored eelgrass shoot density and volume of ulvoid accumulation in the study site and evaluated effects of the accumulated ulvoid canopy on the percent survival, seedling density, growth rates, photosynthetic photon flux density (PPFD) and carbon contents of eelgrass. Eelgrass shoot density decreased by the accumulation of ulvoid. Also, seedling density decreased by the increase in the ulvoid volumes. Shoot density, seedling density and leaf elongation were negatively correlated with ulvoid volume. Carbon contents in eelgrass decreased by the accumulation of ulvoid (canopy height: 25cm). These results suggest that accumulation of ulvoid bloom has significant negative impacts on the structure and function of eelgrass bed, i.e. decreases in vegetative shoot density, seedling density, shoot height and growth rate.     

Clasts of high-grade Sanbagawa schist in Middle Eocene conglomerates from the Kuma Group, central Shikoku, south-west Japan

Middle Eocene conglomerates which overlie the Sanbagawa metamorphic rocks contain clasts of metamorphic rock with isotope ages of 120-85 Ma, which fall within the age range reported from the Sanbagawa metamorphic rocks. They were derived from the chlorite to oligoclase zones of the Sanbagawa metamorphic belt. Clasts of garnet amphibolite and oligoclase-biotite schist show a mineral assemblage similar to the highest grade Sanbagawa schists. However, the metamorphic temperatures estimated by various mineralogical thermometers show that some of the clasts were formed at higher temperatures than the in situ Sanbagawa metamorphic rocks. Such higher grade rocks were at the surface by the Middle Eocene and for the most part they have been eroded away. Cretaceous and post-Cretaceous sediments overlie, or are in fault contact with, the Sanbagawa metamorphic rocks which suggests that rocks in the belt were uplifted and eroded from the latest Cretaceous to Middle Eocene time after strike-slip movement along the Median Tectonic Line. Since the Middle Eocene, the belt has experienced relatively slow uplift which was locally around 2 km in central Shikoku.     

New interpretation of the Franciscan mélange at San Simeon coast,California: tectonic intrusion into an accretionary prism

Many concepts and interpretations on the formation of the Franciscan mélange have been proposed on the basis of exposures at San Simeon, California. In this paper, we show the distribution of chaotic rocks, their internal structures and textures, and the interrelationship between the chaotic rocks and the surrounding sandstones (turbidites). Mélange components, particularly blueschists, oceanic rocks, including greenstone, pillow lava, bedded chert, limestone, sandstone, and conglomerate, have all been brecciated by retrograde deformation. The Cambria Slab, long interpreted as a trench slope basin, is also strongly deformed by fluidization, brecciation, isoclinal folding, and thrusting, leading us to a new interpretation that turbiditic rocks (including the Cambria Slab) represent trench deposits rather than slope basin sediments. These rocks form an accretionary prism above mélanges that were diapirically emplaced into these rocks first along sinistral-thrust faults, and then along dextral-normal faults. Riedel shear systems are observed in several orders of scale in both stages. Although the exhumation of the blueschist blocks is still controversial, the common extensional fractures and brecciation in most of the blocks in the mélanges and further mixture of various lithologies into one block with mélange muddy matrix indicate that once deeply buried blocks were exhumed from considerable depths to the accretionary prism body, before being diapirically intruded with their host mélange along thrust and normal faults, during which retrograde deformation occurred together with retrograde metamorphism. Recent similar examples of high-pressure rock exhumation have been documented along the Sofugan Tectonic Line in the Izu forearc areas, in the Mineoka belt in the Boso Peninsula, and as part of accretionary prism development in the Nankai and Sagami troughs of Japan. These modern analogues provide actively forming examples of the lithological and deformational features that characterize the Franciscan mélange processes.