Alteration and mass transfer inferred from the Hirabayashi GSJ drill penetrating the Nojima Fault, Japan

Abstract Mineralogical and geochemical studies on the fault rocks from the Nojima–Hirabayashi borehole, south-west Japan, are performed to clarify the alteration and mass transfer in the Nojima Fault Zone at shallow depths. A complete sequence from the hornblende–biotite granodiorite protolith to the fault core can be observed without serious disorganization by surface weathering. The parts deeper than 426.2 m are in the fault zone where rocks have suffered fault-related deformation and alteration. Characteristic alteration minerals in the fault zone are smectite, zeolites (laumontite, stilbite), and carbonate minerals (calcite and siderite). It is inferred that laumontite veins formed at temperatures higher than approximately 100°C during the fault activity. A reverse component in the movement of the Nojima Fault influences the distribution of zeolites. Zeolite is the main sealing mineral in relatively deep parts, whereas carbonate is the main sealing mineral at shallower depths. Several shear zones are recognized in the fault zone. Intense alteration is localized in the gouge zones. Rock chemistry changes in a different manner between different shear zones in the fault zone. The main shear zone (MSZ), which corresponds to the core of the Nojima Fault, shows increased concentration of most elements except Si, Al, Na, and K. However, a lower shear zone (LSZ-2), which is characterized by intense alteration rather than cataclastic deformation, shows a decreased concentration of most elements including Ti and Zr. A simple volume change analysis based on Ti and Zr immobility, commonly used to examine the changes in fault rock chemistry, cannot account fully for the different behaviors of Ti and Zr among the two gouge zones.     

The Upper Jurassic–Lower Cretaceous of eastern Heilongjiang, northeast China: stratigraphy and regional basin history

In eastern Heilongjiang, the Upper Jurassic is marine and restricted to the Suibin and Dong’an areas, where it is characterized faunally by Callovian–Volgian (Tithonian) bivalves and florally by dinoflagellates. The Lower Cretaceous is widely distributed in eastern Heilongjiang, and characterized faunally by Berriasian–Valanginian bivalves, Barremian–Albian ammonites and Aucellina, and florally by dinoflagellates. To the west, the marine facies grade into non-marine beds. Thus, in the east, for example in the Dong’an and Dajiashan areas, near the northwestern Palaeo-Pacific, the Lower Cretaceous is marine; westward, in the Yunshan, Longzhaogou, Peide, and Zhushan areas, marine and non-marine deposits alternate, whereas further west still, e.g. in the Jixi Basin, non-marine facies are intercalated with marine beds. This regional distribution is indicative of a large, shallow embayment opening eastwards to the Palaeo-Pacific; during the Early Cretaceous successive transgressive-regressive events influenced the climate and biota of eastern Heilongjiang and northeastern China. Many of the Lower Cretaceous sections contain abundant coals, demonstrating that in this region the Early Cretaceous was an important coal-forming period. Some non-marine bivalve species are common to the Lower Cretaceous Jixi Group of eastern Heilongjiang, the Jehol Group of western Liaoning and the Transbaikalian Group of Siberia, suggesting that these groups are of comparable Early Cretaceous age.     

Dynamic compaction properties of bentonite-based materials

Dynamic compaction tests of bentonite-based materials (BBMs) with 100, 70 and 50% bentonite contents have been performed using five powdery bentonites with different physicochemical properties to establish the simplified evaluation method for dynamic compaction properties of BBMs. For a given bentonite content and a total compaction energy condition, the maximum dry density, ρ_dmax, and the optimum water content, w_opt, which are well-known indexes of compaction properties, for BBMs were determined according to the type of bentonite used for BBMs. For evaluation of those values of BBMs derived in this study, the plastic limit of BBM, w_pbbm, was defined as the plastic limit that was measured using the sample pulverized to a maximum grain size of less than 425 μm in the case of BBM with sand having a maximum grain size of more than 425 μm and was measured using the powdery bentonite itself in the case of BBM without sand. This study proposed equations for evaluating ρ_dmax and w_opt of BBMs with more than 50% bentonite content under the total compaction energy conditions of 551–2755 kN-m/m³ using w_pbbm. Finally, we related the equations derived in this study to the equation for evaluating hydraulic properties of compacted BBMs proposed in previous work and proposed the preparation method of BBMs with more than 50% bentonite content for constructing BBM buffer by in-situ compaction method.     

Rare earth element measurements and mapping of minerals in the Allende CAI, 7R19‐1, by NanoSIMS ion microprobe

We have established analytical procedures for quantitative rare earth element (REE) measurements by NanoSIMS 50L ion microprobe with 2–10 μm spatial resolution. Measurements are performed by multidetection using energy filtering under several static magnetic field settings. Relative sensitivity factors and REE oxide/REE element secondary ion ratios that we determined for the NanoSIMS match values previously determined for other ion microprobes. REE measurements of 100 ppm REE glass standards yielded reproducibility and accuracy of 0.5–2.5% and 5–15%, respectively. REE measurements of minerals of an Allende type‐A CAI, 7R19‐1, were performed using three different methods: spot analysis, line profile, and imaging. These data are in excellent agreement with previous REE measurements of this inclusion by IMS‐3f ion microprobe. The higher spatial resolution NanoSIMS measurements provide additional insight into the formation process of this CAI and offer a promising new tool for analysis of fine‐grained and complexly zoned materials.