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41.
Hiroyuki Kagi Dmitry A. Zedgenizov Hiroaki Ohfuji Hidemi Ishibashi 《Geochemistry International》2016,54(10):834-838
We report cloudy micro- and nano-inclusions in a superdeep diamond from São-Luiz, Brazil which contains inclusions of ferropericlase (Mg, Fe)O and former bridgmanite (Mg, Fe)SiO3 and ringwoodite (Mg, Fe)2SiO4. Field emission-SEM and TEM observations showed that the cloudy inclusions were composed of euhedral micro-inclusions with grain sizes ranging from tens nanometers to submicrometers. Infrared absorption spectra of the cloudy inclusions showed that water, carbonate, and silicates were not major components of these micro- and nano-inclusions and suggested that the main constituent of the inclusions was infrared-inactive. Some inclusions were suggested to contain material with lower atomic numbers than that of carbon. Mineral phase of nano- and micro-inclusions is unclear at present. Microbeam X-ray fluorescence analysis clarified that the micro-inclusions contained transition metals (Cr, Mn, Fe, Co, Ni, Cu, Zn) possibly as metallic or sulfide phases. The cloudy inclusions provide an important information on the growth environment of superdeep diamonds in the transition zone or the lower mantle. 相似文献
42.
The concentrations of H+, nitrate (NO3
-), and sulfate (SO4
2-) in rainwater and their temporal changes were analyzed on the basis of continuous observation from 1 July 1991 to 30 June 1992 at a suburb of Nagoya, Japan. The yearly average for pH was 4.4. In general, an increasing pH with increase in precipitation amount was observed for rain events. Relatively high pH rainwater was sometimes observed at the beginning of rainfall, even though high concentrations of NO3
- and SO4
2- were involved. The high pH values were considered to be caused by the neutralization process with particulate matter containing cations. The yearly averaged ratio of equivalent concentration of nitrate to sulfate (N/S) in rainwater was 0.58. In the early stage of rain, the N/S value was usually more than 1.0 due to the difference of scavenging process between NO3
- and SO4
2-. High values of N/S ranging from 5 to 10 were found under the atmospheric conditions of calm winds and low humidity, during which it is possible that atmospheric particles float for a long time in the air before a rain event. The adsorption of NO3
- in the early stage of rainfall by particulate matter was suggested from the difference in scavenging processes of NO3
- and SO4
2-. A possible scavenging process, called limb cloud scavenging, is presented to explain the interaction of particles and nitrate ions at the early stage of rain. In limb cloud scavenging, the repeated migration of cloud particles or raindrops between the inside and outside of clouds increases the absorption of ions to a highly condensed level, thus increasing the N/S value of rainwater. The influence of global scale seasonal phenomena with large amounts of particulates, such as typhoons or Asian dust storms, was also studied. 相似文献
43.
Mst. Hawa Bibi Faruque Ahmed Hiroaki Ishiga Takashi Asaeda Takeshi Fujino 《Environmental Earth Sciences》2010,60(3):655-670
Geochemical analyses of lakebed and core sediments from Lake Sambe on the outskirts of Oda City in Shimane prefecture in southwestern
Japan were carried out in order to assess the water quality and the concentration and distribution patterns of sixteen elements.
The lake water showed a stratified condition with respect to dissolved O2, and As, Fe, and Mn concentrations in the bottom layers which increased in the summer. The chemical composition of the sediments,
as measured by X-ray fluorescence, included major and trace elements (P, Ca, Sc, Ti, V, Cr, Fe, Ni, Cu, Zn, As, Sr, Zr, Pb,
and Th), and total sulfur (TS). Elevated values of As, Zn, V, Fe, P, and TS were present in several layers of the upper cores
(from 0 to 5 cm) and other surface sediments. Increases in the abundances of these metals in lake sediments are probably related
to the reducing condition of the sediments, fine-grained organic rich sediments, and post-depositional diagenetic remobilization.
Moreover, correlations between the concentrations of trace metals and iron in the sediments suggest their adsorption onto
Fe (oxy)hydroxides, whereas correlations with sulfur indicate that they were precipitated as Fe-sulfides. The average abundances
of As, Pb, Zn, and Cu exceeded the lowest effect level and Interim Sediment Quality Guideline values that the New York State
Department of Environmental Conservation and the Canadian Council of Ministers of the Environment determined to have moderate
impact on aquatic organisms. In addition, concentrations of As and Zn exceeded the Coastal Ocean Sediment Database threshold
value, indicating potentially toxic levels. Therefore, the presence of trace metals in the lake sediments may result in adverse
effects on biota health. 相似文献
44.
Hide Yasuhara Naoki Kinoshita Hiroaki Ohfuji Dae Sung Lee Shinichiro Nakashima Kiyoshi Kishida 《Applied Geochemistry》2011,26(12):2074-2088
Examining the evolution of fracture permeability under stressed and temperature-elevated conditions, a series of flow-through experiments on a single rock fracture in granite has been conducted under confining pressures of 5 and 10 MPa, under differential water pressures ranging from 0.04 to 0.5 MPa, and at temperatures of 20–90 °C, for several hundred hours in each experiment. Measurements of fluid and dissolved mass fluxes, and post-experimental microscopy, were conducted to constrain the progress of mineral dissolution and/or precipitation and to examine its effect on transport properties. Generally, the fracture aperture monotonically decreased with time at room temperature, and reached a steady state in relatively short periods (i.e., <400 h). However, once the temperature was elevated to 90 °C, the aperture resumed decreasing and kept decreasing throughout the rest of the experimental periods. This reduction may result from the removal of the mineral mass from the bridging asperities within the fracture. Post-experimental observations by scanning electron microscopy, coupled with energy dispersive X-ray spectroscopy (SEM-EDX), revealed the formation of several kinds of secondary minerals such as silica and calcite. However, the precipitated minerals seemed to have had little influence on the flow characteristics within the fracture, because the precipitation was limited to quite local and small areas. The evolving rates and ultimate magnitudes of the fracture aperture are likely to be controlled by the stress exerted over the contacting asperities and temperatures, and by the prescribed flow conditions. Thus, this complex behavior should be attributed to the coupled chemically- and mechanically-induced effect. A coupled chemo–mechano conceptual model, accounting for pressure and free-face dissolutions, is presented in this paper to follow the evolution of the fracture permeability observed in the flow-through experiments. This model addresses the two dissolution processes at the contacting asperities and the free walls within the fractures, and is also capable of describing multi-mineral dissolution behavior. The model shows that the evolution of a fracture aperture (or related permeability) and of element concentrations may be followed with time under arbitrary temperature and pressure conditions. The model predictions for the evolving fracture aperture and elements concentrations show a relatively good agreement with the experimental measurements, although it is not possible to replicate the abrupt reduction observed in the early periods of the experiments, which is likely to be due to an unaccounted mechanism of more stress-mediated fracture compaction driven by the fracturing of the propping asperities. 相似文献
45.
Neocalanus flemingeri, Neocalanus plumchrus, Neocalanus cristatus and Eucalanus bungii are large and dominant mesozooplankton occurring throughout the subarctic Pacific. They are an important trophic link and transporter of organic matter to the mesopelagic zone. Vertical distributions of these copepods were investigated from March to October 2000 in the Oyashio region of the western subarctic Pacific. Neocalanus plumchrus and N. flemingeri were distributed in the surface layer (0–50 m) and N. cristatus and E. bungii in the subsurface layer (50–100 m). However, when examined in detail, clear seasonal and vertical differences were observed. Neocalanus plumchrus was concentrated in the top 20 m from late April to the end of July, and N. flemingeri showed a little deeper distribution from May to July. Neocalanus cristatus showed a deeper distribution than that of grazing individuals of E. bungii from April to early July, but grazing individuals of E. bungii (C3–C6) showed a deeper distribution than that of N. cristatus from the end of July to October. Early copepodites of E. bungii were distributed much shallower than late copepodite stages and overlapped with copepodites of N. plumchrus and N. flemingeri. These results suggest that the four species of large copepods have established habitat segregation by season, vertical distribution and food resource partitioning in the Oyashio region as well as other regions of the North Pacific. 相似文献
46.
Geochemical study of the Holocene sediments of the Meghna River Delta, Chandpur, Bangladesh was conducted to investigate the distribution of arsenic and related trace and major elements. The work carried out includes analyses of core sediments and provenance study by rare earth element (REE) analysis. Results showed that the cores pass downward from silty clays and clays into fine to medium sands. The uppermost 3 m of the core sediments are oxidized [average oxidation reduction potential (ORP) + 230 mV], and the ORP values gradually become negative with depths (−45 to −170 mV), indicating anoxic conditions prevail in the Meghna sediments. The REE patterns of all lithotypes in the study areas are similar and are comparable to the average upper continental crust. Arsenic and other trace elements (Pb, Zn, Cu, Ni, and Cr) have greater concentrations in the silts and clays compared to those in the sands. Positive correlation between As and Fe was found in the sediments, indicating As may be adsorbed on Fe oxides in aquifer sediments. 相似文献
47.
For the measurement of atmospheric NO2 vertical column density (VCD), Kitt Peak Solar Flux Atlas can be substituted as an extraterrestrial solar radiation. Compared with differential analysis method, the Taylor expansion of integrated transfer equation underestimates the VCD. This underestimation is as large as 35% when the amount of NO2 is 1 × 1017 cm-2 and observation is conducted with an air mass factor of 10. Even when the VCD is 2 × 1016 cm-2 and the air mass factor is 4, the relative error of the retrieved VCD is still no less than 3%. If the observation is restricted under the small air mass factor condition (≤4), with Kitt Peak Solar spectrum as an extraterrestrial solar radiation, only an atmospheric layer of 2 km thick from ground can be studied, which will make the absorption too weak to be detected by normal instruments.The VCD in winter Tokyo area was observed and analyzed by differential method, which shows a good precision even when the absorption is as low as 3%. The largest average VCD was about 1.3 × 1017 cm-2, and the lowest was about 1.3 × 1016 cm-2. The trend of its variation was almost the same as the ground level observation by Saltzman reagent method. 相似文献
48.
Space observations of solar flares such as those from Yohkoh, SOHO, TRACE, and RHESSI have revealed a lot of observational
evidence of magnetic reconnection in solar flares: cusp-shaped arcades, reconnection inflows, plasmoids, etc. Thus it has
been established, at least phenomenologically, that magnetic reconnection does occur in solar flares. However, a number of
fundamental questions and puzzles still remain in the physics of reconnection in solar flares. In this paper, we discuss the
recent progresses and future prospects in the study of magnetic reconnection in solar flares from both theoretical and observational
points of view. 相似文献
49.
Hiroshi Tsuno Atsuyuki Ohta Hiroyuki Kagi Noboru Imai Hiroaki Tao Masaharu Nomura 《Geostandards and Geoanalytical Research》2006,30(1):55-62
The oxidation states of chromium in GSJ JSO-2 (artificially contaminated soil) and three other geochemical reference materials (GSJ JSO-1, JLS-1 and JMS-1) were observed using X-ray near edge structure (XANES). For comparison, other artificially contaminated soil materials (mimic-JSO-2) were prepared by adding Cr(VI) into JSO-1. Their oxidation states of chromium were determined using XANES. The chromium contents were 1118 μg g-1 for JSO-2, 1352 μg g-1 for mimic-JSO-2 and 69-113 μg g-1 for the other reference materials. Most chromium was present as hexavalent in mimic-JSO-2. No hexavalent species were detected in other samples. These results for chromium oxidation state in JSO-2 and mimic-JSO-2 obtained with XANES resembled those obtained from a chemical extraction method. The present JSO-2 has no trace of Cr(VI), although Cr(VI) was added as a major species during preparation. On the other hand, the content of Cr(VI) obtained in mimic-JSO-2 agreed with the original Cr(VI) content. A time-elapse study showed that Cr(VI) contents in mimic-JSO-2 decreased gradually to 70% of the original abundance during 240-day preservation in dry conditions. Moreover, the abundance of Cr(VI) decreased markedly to 15% after 240 days in the wet mimic-JSO-2 containing 20% m/m of water. These experiments suggested that soil humidity enhanced the reduction of Cr(VI) and that Cr(VI) was reduced even in dry conditions. Consequently, it is reasonable to infer that Cr(VI) doped into JSO-2 was completely reduced to Cr(III) during the preservation period of 5 years. The certification of the long-term stability of the chemical form in reference materials will be much more important in future. 相似文献
50.
Ore value-tonnage diagrams for resource assessment 总被引:4,自引:0,他引:4
An ore value-tonnage diagram has been proposed for assessing mineral resources. Diagrams of W+Mo, and Pb+Zn deposits show
a good linearity between ore value and logarithms of cumulative ore tonnage. Diagrams of the massive sulfide, orthomagmatic,
placer, porphyry, replacement, and stratabound types are also linear. It is assumed, therefore, that deposits of each of these
commodities and these types belong to a single population. In contrast, the ore value-tonnage relations of all the deposits
analyzed here is approximated by the combination of two exponential functions. The same feature is seen for deposits of the
Cu+W+Mo, Cu+Pb+Zn, and Au+Ag commodities, and of the vein and unconformity-related types. This suggests that deposits belonging
to each of such categories are divided into the high and low value groups. We can expect, accordingly, to find high value
deposits of such categories. 相似文献