Satellite detection of red tide in Ariake Sound, 1998–2001

High resolution SeaWiFS data was used to detect red tide events that occurred in the Ariake Sound, Japan, a small embayment known as one of the most productive areas in Japan. SeaWiFS chlorophyll data clearly showed that a large red tide event, which damaged seaweed (Nori) cultures, started early in December 2000 in Isahaya Bay, expanded to the whole sound and persisted to the end of February 2001. The monthly average of SeaWiFS data from May 1998 to December 2001 indicated that the chlorophyll peaks appeared twice a year, in early summer and in fall, after the peaks of rain and river discharge. The SeaWiFS data showed that the red tide event during 2000–2001 winter was part of the fall bloom; however, it started later and continued significantly longer than other years. Satellite ocean color data is useful to detect the red tide; however the algorithms require improvement to accurately estimate chlorophyll in highly turbid water and in red tide areas.     

Community Structure and Dynamics of Phytoplankton in the Western Subarctic Pacific Ocean: A Synthesis

The phytoplankton community in the western subarctic Pacific (WSP) is composed mostly of pico- and nanophytoplankton. Chlorophyll a (Chl a) in the <2 μm size fraction accounted for more than half of the total Chl a in all seasons, with higher contributions of up to 75% of the total Chl a in summer and fall. The exception is the western boundary along the Kamchatka Peninsula and Kuril Islands and the Oyashio region where diatoms make up the majority of total Chl a during the spring bloom. Among the picophytoplankton, picoeukaryotes and Synechococcus are approximately equally abundant, but the former is more important in term of carbon biomass. Despite the lack of a clear seasonal variation in Chl a concentration, primary productivity showed a large seasonal variation, and was lowest in winter and highest in spring. Seasonal succession in the phytoplankton community is also evident with the abundance of diatoms peaking in May, followed by picoeukaryotes and Synechococcus in summer. The growth of phytoplankton (especially >10 μm cell size) in the western subarctic Pacific is often limited by iron bioavailability, and microzooplankton grazing keeps the standing stock of pico- and nano-phytoplankton low. Compared to the other HNLC regions (the eastern equatorial Pacific, the Southern Ocean, and the eastern subarctic Pacific), iron limitation in the Western Subarctic Gyre (WSG) may be less severe probably due to higher iron concentrations. The Oyashio region has similar physical condition, macronutrient supply and phytoplankton species compositions to the WSG, but much higher phytoplankton biomass and primary productivity. The difference between the Oyashio region and the WSG is also believed to be the results of difference in iron bioavailability in both regions. This revised version was published online in July 2006 with corrections to the Cover Date.     

Binary and triple collisions causing instability in the free-fall three-body problem

Dominant factors for escape after the first triple-encounter are searched for in the three-body problem with zero initial velocities and equal masses. By a global numerical survey on the whole initial-value space, it is found that not only a triple-collision orbit but also a particular family of binary-collision orbits exist in the set of escape orbits. This observation is justified from various viewpoints. Binary-collision orbits experiencing close triple-encounter turn out to be close to isosceles orbits after the encounter and hence lead to escape. Except for a few cases, binary-collision orbits of near-isosceles slingshot also escape. This revised version was published online in July 2006 with corrections to the Cover Date.     

Geochemical study of arsenic and other trace elements in groundwater and sediments of the Old Brahmaputra River Plain,Bangladesh

The geochemical study of groundwaters and core sediments from the Old Brahmaputra plain of Bangladesh was conducted to investigate the distribution of arsenic and related trace elements. Groundwaters from tube wells are characterized by pH of 6.4–7.4, dissolved oxygen (DO) of 0.8–1.8 mg/l, Ca contents of 5–50 mg/l, and Fe contents of 0.2–12.9 mg/l. Arsenic concentrations ranged from 8 to 251 μg/l, with an average value of 63 μg/l. A strong positive correlation exists between As and Fe (r ² = 0.802; p = 0.001) concentrations in groundwater. The stratigraphic sequences in the cores consist of yellowish silty clays at top, passing downward into grayish to yellowish clays and sands. The uppermost 3 m and lower parts (from 13 to 31 m) of the core sediments are oxidized (average oxidation reduction potential (ORP) +170 and +220 mV, respectively), and the ORP values gradually become negative from 3 to 13 m depths (−35 to −180 mV), indicating that anoxic conditions prevail in the shallow aquifers of the Brahmaputra plain. Age determinations suggest that clay horizons at ~10 m depth were deposited at around 2,000 and 5,000 years BP (¹⁴C ages) during the transgressive phase of sea-level change. Elevated concentrations of As, Pb, Zn, Cu, Ni, Cr, and V are present in the silts and clays, probably due to adsorption onto clay particles. Significant concentrations of As occur in black peat and peaty sediments at depths between 9 and 13 m. A strong positive correlation between As and Fe was found in the sediments, indicating As may be adsorbed onto Fe oxides in aquifer sediments.     

Felsic dykes in the Neoproterozoic Nagar Parkar Igneous Complex,SE Sindh,Pakistan: geochemistry and tectonic settings

The Nagar Parkar Igneous Complex consists of Neoproterozoic igneous and metamorphic rocks dissected by mafic, felsic, and rhyolitic dykes. The latter can be classified broadly into porphyritic felsic dykes intruding gray and pink granites at Nagar Parkar and the surrounding areas, and the orthophyric felsic dykes intruding amphibolites, deformed pink granites, and the alkaline mafic dykes in the Dhedvero area, north of Nagar Parkar. The porphyritic felsic dykes are composed of perthites, quartz, and albitic plagioclase whereas the orthopheric felsic dykes contain K-feldspar (dominant), plagioclase, and minor quartz. Geochemically, the porphyritic and orthophyric felsic dykes are subalkaline and alkaline demonstrating post-orogenic A2- and OIB-A1-type characteristic on Nb–Y–Ce and Nb–Y–3Ga ternary plots, respectively. One orthophyric felsic dyke contains normative acmite and sodium metasilicate. This study suggests two distinct tectonic regimes for the origin of the felsic dykes of the area. The porphyritic felsic dykes show similarities with the ~800–700 Ma granites of the area, the rhyolite dykes of the Mount Abu, western Rajasthan in India, and the granites of the Seychelles microcontinent. The orthophyric felsic dykes show chemical resemblance with the Tavidar volcanic suite of western Rajasthan and the Silhouette and North islands of the Seychelles microcontinent. This study confirms spatial and temporal links among the Rodinian fragments exposed in the Nagar Parkar area of Pakistan, western Rajasthan of India, and the Seychelles microcontinent.     

Mesozooplankton responses to iron-fertilization in the western subarctic Pacific (SEEDS2001)

A mesoscale iron-fertilization experiment was carried out in the western subarctic Pacific during summer 2001. The iron-patch was traced for 14 days after the fertilization, and the abundance and behavior of mesozooplankton were compared with those outside of the patch. The phytoplankton biomass in the patch rapidly increased to over 15 times the initial level by the later half of the observation period, and was composed of large-sized (>10 mm), centric diatoms. Dominant zooplankton species in the upper 200-m depth were large copepods: Neocalanus plumchrus, Neocalanus cristatus, Eucalanus bungii and Metridia pacifica. Mesozoplankton biomass as well as species composition did not change significantly in the patch over the observation period. Furthermore, no changes of vertical distribution or diel vertical migration were observed for any species or stages of mesozooplankton throughout the observation period. However, the abundance of the first copepodite stages of N. plumchrus and E. bungii increased several fold in the patch after the diatom bloom formation compared to the densities outside the patch. The increases of both species are considered to be due to lowered mortality during the egg and nauplius stages. Spawning of N. plumchrus takes place at depth using lipid storage, while spawning of E. bungii takes place in the surface layer supported by grazing. These facts suggest that the relative importance of nauplii in the diets of the large copepods was decreased in the patch by the diatom bloom. Gut-pigment contents of dominant copepods in the patch increased 4–18 times, and the maximum values were observed during the bloom peak. However, the grazing impact on phytoplankton was low throughout the experiment, especially during the bloom period (<6% of the primary production).     

Distribution of arsenic and other trace elements in the Holocene sediments of the Meghna River Delta, Bangladesh

Geochemical study of the Holocene sediments of the Meghna River Delta, Chandpur, Bangladesh was conducted to investigate the distribution of arsenic and related trace and major elements. The work carried out includes analyses of core sediments and provenance study by rare earth element (REE) analysis. Results showed that the cores pass downward from silty clays and clays into fine to medium sands. The uppermost 3 m of the core sediments are oxidized [average oxidation reduction potential (ORP) + 230 mV], and the ORP values gradually become negative with depths (−45 to −170 mV), indicating anoxic conditions prevail in the Meghna sediments. The REE patterns of all lithotypes in the study areas are similar and are comparable to the average upper continental crust. Arsenic and other trace elements (Pb, Zn, Cu, Ni, and Cr) have greater concentrations in the silts and clays compared to those in the sands. Positive correlation between As and Fe was found in the sediments, indicating As may be adsorbed on Fe oxides in aquifer sediments.     

Correlation study between suspended particulate matter and DOAS data

Continuous data of aerosol optical thickness monitored using differential optical absorption spectroscopy (DOAS) are correlated with the concentration of ground-measured suspended particulate matter (SPM). A high correlation is found between the DOAS and the ground SPM data, making it possible to calculate the mass extinction efficiency of the aerosols in the atmosphere. It is found that the value of mean mass extinction efficiency (MEE) varies over a range of 2.6–13.7m2 g?1, with smaller and larger values occurring for size distributions dominated by coarse and fine particles, respectively.     

Ore value-tonnage diagrams for resource assessment

An ore value-tonnage diagram has been proposed for assessing mineral resources. Diagrams of W+Mo, and Pb+Zn deposits show a good linearity between ore value and logarithms of cumulative ore tonnage. Diagrams of the massive sulfide, orthomagmatic, placer, porphyry, replacement, and stratabound types are also linear. It is assumed, therefore, that deposits of each of these commodities and these types belong to a single population. In contrast, the ore value-tonnage relations of all the deposits analyzed here is approximated by the combination of two exponential functions. The same feature is seen for deposits of the Cu+W+Mo, Cu+Pb+Zn, and Au+Ag commodities, and of the vein and unconformity-related types. This suggests that deposits belonging to each of such categories are divided into the high and low value groups. We can expect, accordingly, to find high value deposits of such categories.     

Temporal alteration of fracture permeability in granite under hydrothermal conditions and its interpretation by coupled chemo-mechanical model

Examining the evolution of fracture permeability under stressed and temperature-elevated conditions, a series of flow-through experiments on a single rock fracture in granite has been conducted under confining pressures of 5 and 10 MPa, under differential water pressures ranging from 0.04 to 0.5 MPa, and at temperatures of 20–90 °C, for several hundred hours in each experiment. Measurements of fluid and dissolved mass fluxes, and post-experimental microscopy, were conducted to constrain the progress of mineral dissolution and/or precipitation and to examine its effect on transport properties. Generally, the fracture aperture monotonically decreased with time at room temperature, and reached a steady state in relatively short periods (i.e., <400 h). However, once the temperature was elevated to 90 °C, the aperture resumed decreasing and kept decreasing throughout the rest of the experimental periods. This reduction may result from the removal of the mineral mass from the bridging asperities within the fracture. Post-experimental observations by scanning electron microscopy, coupled with energy dispersive X-ray spectroscopy (SEM-EDX), revealed the formation of several kinds of secondary minerals such as silica and calcite. However, the precipitated minerals seemed to have had little influence on the flow characteristics within the fracture, because the precipitation was limited to quite local and small areas. The evolving rates and ultimate magnitudes of the fracture aperture are likely to be controlled by the stress exerted over the contacting asperities and temperatures, and by the prescribed flow conditions. Thus, this complex behavior should be attributed to the coupled chemically- and mechanically-induced effect. A coupled chemo–mechano conceptual model, accounting for pressure and free-face dissolutions, is presented in this paper to follow the evolution of the fracture permeability observed in the flow-through experiments. This model addresses the two dissolution processes at the contacting asperities and the free walls within the fractures, and is also capable of describing multi-mineral dissolution behavior. The model shows that the evolution of a fracture aperture (or related permeability) and of element concentrations may be followed with time under arbitrary temperature and pressure conditions. The model predictions for the evolving fracture aperture and elements concentrations show a relatively good agreement with the experimental measurements, although it is not possible to replicate the abrupt reduction observed in the early periods of the experiments, which is likely to be due to an unaccounted mechanism of more stress-mediated fracture compaction driven by the fracturing of the propping asperities.