Preferential dissolution of SiO<Subscript>2</Subscript> from enstatite to H<Subscript>2</Subscript> fluid under high pressure and temperature

Stability and phase relations of coexisting enstatite and H₂ fluid were investigated in the pressure and temperature regions of 3.1–13.9 GPa and 1500–2000 K using laser-heated diamond-anvil cells. XRD measurements showed decomposition of enstatite upon heating to form forsterite, periclase, and coesite/stishovite. In the recovered samples, SiO₂ grains were found at the margin of the heating hot spot, suggesting that the SiO₂ component dissolved in the H₂ fluid during heating, then precipitated when its solubility decreased with decreasing temperature. Raman and infrared spectra of the coexisting fluid phase revealed that SiH₄ and H₂O molecules formed through the reaction between dissolved SiO₂ and H₂. In contrast, forsterite and periclase crystals were found within the hot spot, which were assumed to have replaced the initial orthoenstatite crystals without dissolution. Preferential dissolution of SiO₂ components of enstatite in H₂ fluid, as well as that observed in the forsterite H₂ system and the quartz H₂ system, implies that H₂-rich fluid enhances Mg/Si fractionation between the fluid and solid phases of mantle minerals.     

准噶尔板块东北缘富铌玄武岩的发现及其地质意义

富铌玄武岩是硅过饱和,富Ｎａ2Ｏ,ＴｉＯ2,Ｐ2Ｏ5,同时富集高场强元素的一类岛弧玄武岩,这类玄武岩的ｗ(Ｎｂ)>7×10-6,(ｗ(Ｌａ)/ｗ(Ｎｂ))ＭＮ<2。它是由来源于70100ｋｍ深处、受ａｄａｋｉｔｅ熔体交代过的地幔楔橄榄岩部分熔融形成的,是大洋板块俯冲作用的产物。目前发现的富铌玄武岩大多分布在环太平洋新生代岛弧环境,与洋壳俯冲作用密切相关[1 5]。本研究在准噶尔板块东北缘富蕴县的索尔库都克附近首次发现了富铌玄武岩。它产于下泥盆统托让格库都克组中、上部。该地层自下而上的岩石组合为:玄武岩 火山凝灰角砾岩 火山集块岩 含…     

来自于九年后日本海纳霍德卡溢油污染海岸的碳氢化合物降解细菌和石蜡

近十年来，石油类碳氢化合物，尤其是油溢带来的污染引起了广泛的关注。油溢会影响到自然菌落及其受污染菌落点的物理和化学性质。生物降解碳氢化合物是一种主要的除去油类泄漏污染源的方法。1997年1月2日，一艘名为纳霍德卡（Nakhodka）的俄罗斯油轮在日本海发生重油溢漏污染事故。纳霍德卡号油溢事件导致粘稠的流体污染了海岸，影响了周围的生态环境。本文详述了碳氢化合物降解细菌（假单胞菌种）的褪变，确定了九年后来自于纳霍德卡号油溢污染海岸的有机化合物。经过十年的生物修复，纳霍德卡溢油变硬．XRD分析结果中与石墨和方解石有关的0．422，     

Hydrocarbon-Degrading Bacteria and Paraffin from Polluted Seashores 9 Years after the Nakhodka Oil Spill in the Sea of Japan

Pollution of petroleum hydrocarbons, in particular oil spills, has attracted much attention in the past and recent decades. Oil spills influence natural microbial community, and physical and chemical properties of the affected sites. The biodegradation of hydrocarbons by microorganisms is one of the primary ways by which oil spill is eliminated from contaminated sites. One such spill was that of the Russian tanker the Nakhodka that spilled heavy oil into the Sea of Japan on January 2, 1997. The impact of the Nakhodka oil spill resulted in a viscous sticky fluid fouling the shores and affected natural ecosystems. This paper describes the weathering of hydrocarbon-degrading bacteria （genus Pseudomonas） and crystallized organic compounds from the Nakhodka oil spill-polluted seashores after nine years. The Nakhodka oil has hardened and formed crust of crystalline paraffin wax as shown by XRD analysis （0.422, 0.377, and 0.250 nm d-spacing） in association with graphite and calcite after 9 years of bioremediation. Anaerobic reverse side of the oil crust contained numerous coccus typed bacteria associated with halite. The finding of hydrocarbon-degrading bacteria and paraffin wax in the oil crust may have a significant effect on the weathering processes of the Nakhodka oil spill during the 9- year bioremediation.     

Late Paleozoic adakites and Nb-enriched basalts from northern Xinjiang, northwest China: Evidence for the southward subduction of the Paleo-Asian Oceanic Plate

Abstract   Volcanic rocks consisting of adakite and Nb-enriched basalt are found in the early Devonian Tuoranggekuduke Group in the northern margin of the Kazakhstan-Junggar Plate, northern Xinjiang, northwest China. The geochemical characteristics of the andesitic and dacitic rocks in this area resemble that of adakites. The relatively high Al₂O₃, Na₂O and MgO content and Mg^♯ values indicate that the adakites were generated in relation to oceanic slab subduction rather than the partial melting of basaltic crust. A slightly higher SrI and a lower ɛ _Nd( t  = 375 Ma) compared to adakites of mid-oceanic ridge basalt (MORB) imply that slab sediments were incorporated into these adakites during slab melting. The Nb-enriched basalt lavas, which are intercalated in adakite lava suite, are silica saturated and are distinguished from the typical arc basalts by their higher Nb and Ti content (high field strength element enrichment). They are derived from the partial melting of the slab melt-metasomatized mantle wedge peridotite. Apparently, positive Sr anomalies and a slightly higher heavy rare earth element content in these adakites compared to their Cenozoic counterparts indicate that the geothermal gradient in the Paleo-Asian Oceanic subduction zone and the depth of the Paleo-Asian Oceanic slab melting are between those of their Archean and Cenozoic counterparts. The distribution of the adakites and Nb-enriched basalts in the northern margin of the Kazakhstan-Junggar Plate, northern Xinjiang, indicates that the Paleo-Asian Oceanic Plate subducted southward beneath the Kazakhstan-Junggar Plate in the early Devonian period.     

Stable isotope-guided analysis of congener-specific PCB concentrations in a Japanese coastal food web

Organisms collected from a coastal ecosystem in Japan were analyzed for concentrations of 205 polychlorinated biphenyls (PCBs) congeners; analyses were guided by δ¹³C and δ¹⁵N measurements. The regression slopes of log PCB concentration on δ¹⁵N value are regarded as indices of biomagnification in food webs. The slope (wet weight basis) of ΣPCBs was +0.104; the slope (lipid weight basis) was close to zero. Lipid content increased from 0.06% in a primary producer to 8.32% in the highest trophic level consumer. Hence, biomagnification of ΣPCBs (wet weight basis) can be attributed to increase of lipid content through the food web. For most of the congeners, the slopes (wet weight basis) exceeded those (lipid weight basis) by ca. 0.10. Slopes increased with increasing PCB chlorination levels between chlorine numbers 1–6; slopes decreased at higher chlorination levels. This decrease is likely caused by a decrease in membrane permeability with increasing molecular weight.     

DO-increasing effects of a microscopic bubble generating system in a fish farm

We have developed a "microscopic bubble generating system for the fish farm" and evaluated its ability to improve the quality of seawater and costs of it in marine cages of red sea bream (Pagrus major) in Kusuura Bay, Japan. Our results revealed that DO concentration of bubbling net pens increased and became significantly higher than the level outside the net pen (between 0.52 and 0.87 mg/L), and the whole water column was nearly saturated. Temperatures of the bubbling net pens decreased slightly between 0.08 and 0.12 degrees C in all the layers. Furthermore, micro-bubbles seemed to reach the deeper water due to the downward flow and diffusion. This study demonstrated that the microscopic bubble generating system developed in our research project could increase efficiently the dissolved oxygen concentration throughout all water layers of the fish farm. A capital and operation costs of the system is recoverable within a year.     

Juxtaposition of adakite, boninite, high-TiO2 and low-TiO2 basalts in the Devonian southern Altay, Xinjiang, NW China

We present petrographic and geochemical data on representative samples of the Devonian adakite, boninite, low-TiO₂ and high-TiO₂ basalts and associated rocks in the southern Altay areas, Xinjiang, NW China. These volcanic rocks mostly occur as tectonic blocks within suture zones between the Siberian and Junggar plates. Adakite occurs in the Suoerkuduke area ca. 40 km south of Fuyun, and actually represents a poorly-sorted massive volcaniclastic deposit, mostly consisting of a suite of hornblende andesite to pyroxene andesite. The geochemical features of the adakite suggest its generation by melting of subducted oceanic crust. Boninite occurs in the Saerbulake area ca. 20 km southwest of Fuyun, as pillowed lava or pillowed breccia. It is associated with high-TiO₂ basalt/gabbro and low-TiO₂ basalt. The boninites are metamorphosed, but contain relict clinopyroxene with Mg# (=100*Mg/(Mg+Fe)) of 90–92, and Cr₂O₃ contents of 0.5–0.7 wt% and chromian spinel with Cr/(Cr+Al) ratio of 0.84. The bulk rock compositions of the boninites are characterized by low and U-shaped REE with variable La/Yb ratios. They are classified as high-Ca boninite. The Cr-rich cpx phenocryst and Chromian spinel suggests that the boninites were formed by melting of mildly refractory mantle peridotite fluxed by a slab-derived fluid component under normal mantle potential temperature conditions. Basaltic rocks occur as massive flows, pillowed lavas, tuff breccia, lapilli tuff and blocks in tectonic mélanges. Together with gabbros, the basaltic rocks are classified into high-TiO₂ (>1.7 wt%) and low-TiO₂ (<1.5 wt%) types. They show variable trace element compositions, from MORB-type through transitional back-arc basin basalt to arc tholeiite, or within plate alkalic basalt. A notable feature of the Devonian formations in the southern Altay is the juxtaposition of volcanic rocks of various origins even within a limited area; i.e. the adakite and the boninites are associated with high-TiO₂ and low-TiO₂ basalts and/or gabbros, respectively. This is most likely produced by complex accretion and tectonic processes during the convergence in the Devonian–Carboniferous paleo-Asian Ocean between the Siberian and Junggar plates.