A 35 kyr record of organic matter composition and δ13C of n-alkanes in bog sediments close to Lake Baikal: Implications for paleoenvironmental studies

We characterized the compositions of organic compounds in a Cheremushka bog sediment core (deposited over the last 35 kyr), located at the eastern coast of Lake Baikal, to obtain basic information about the terrestrial organic matter (OM) which contributed to Lake Baikal sediments. The bog sediment was analyzed for the molecular composition of n-alkanes, lignin phenols and n-C₂₄ to C₃₀ alkanoic acids, as well as the carbon isotopic composition of plant wax derived n-C₂₇ to C₃₃ alkanes.Concentrations of lignin phenols [vanillyl (V) plus syringyl (S) phenols] normalized to total organic carbon (TOC) in the Holocene are twice those for the last glacial maximum (LGM), while concentrations of TOC-normalized n-C₂₄ to C₃₀ alkanoic acids do not change markedly in this period. Thus, the ratio of lignin phenols to n-C₂₄ to C₃₀ alkanoic acids increases from the LGM to the Holocene. This result is essentially consistent with pollen analysis indicating an expansion of woody plants in the Holocene and a prevailing herb-abundant environment for the LGM. The δ¹³C values of n-C₂₇ to C₃₃ alkanes (e.g. ?29‰ to ?33‰ for C₃₁) indicate the presence of C₃-dominant plants throughout the core.The contribution of terrestrial OM to Lake Baikal sediments was estimated using the biomarkers, on the assumption that the OM in the bog sediments is a representative of the terrestrial OM around the lake. Hence, the estimation using lignin phenol or n-C₂₄ to C₃₀ alkanoic acid parameters indicates that 11–24% of the TOC in the Academician Ridge sediments is land-derived for both the Holocene and the LGM, which is similar to the estimates from C/N values of bulk OM. However, the estimates for terrestrial OM using the n-C₂₇ to C₃₃ alkane parameter are generally higher than those using lignin phenol or n-C₂₄ to C₃₀ alkanoic acid parameters. The difference is thought to be associated with the difference in source and behavior of these biomarkers.     

Influences of the snow cover on landslide displacement in winter period: a case study in a heavy snowfall area of Japan

The displacement of a relatively small reactivated landslide in a snowy area in Japan was monitored over a long period. The displacement rate of the landslide, which was approximately of 20 mm d^?1 before the formation of snow cover, decelerated drastically during the continuous snow cover period every winter period. Possible causes included reduction in the amount of water that reached the ground surface (MR: meltwater and/or rainwater) and increase in snow load. Given that the actual displacement of the landslide was far below the predicted value based on the relationship between landslide displacement and MR immediately before the continuous snow cover period, the deceleration of landslide displacement was more likely attributable to the increase in snow load than to the reduction in MR. An investigation of the link between snow load and landslide displacement showed a negative logarithmic relationship. A dynamic analysis based on the limit equilibrium method showed that snow load increases the effective normal stress and the stability of a landslide in which the mean inclination angle of the slip surface is smaller than the internal friction angle. The stability of the actual slope was also analyzed by conducting soil tests on samples collected at the site and using the resultant parameters. The analysis also showed that the increase in snow load increases the safety factor and reduces the landslide displacement. The displacement of a relatively small landslide that has a shallow slip surface was found to be greatly influenced by snow cover.     

Estimating the impact force generated by granular flow on a rigid obstruction

Flowing sediments such as debris and liquefied soils could exert a tremendous amount of force as they impact objects along their paths. The total impact force generally varies with slope angle, velocity at impact, and thickness of the flowing sediment. Estimation of the impact force of flowing sediments against protective measures such as earth retaining structures is an important factor for risk assessment. In this paper, we conduct small-scale laboratory physical modeling of sand flow at different slopes and measure the impact force exerted by this material on a fixed rigid wall. We also conduct numerical simulations in the Eulerian framework using computational fluid dynamics algorithms to analyze and reproduce the laboratory test results. The numerical simulations take into consideration the overtopping of the wall with sand, which influenced the measured impact force–time history responses. In addition, the numerical simulations are shown to capture accurately the change of the impact force with slope angle. Finally, the modeling approach conducted in this study is used to estimate the quasi-static force generated by the sediment as it comes to rest on the wall following impact.     

Late Pleistocene and Holocene vegetation and climate records from Lake Kotokel, central Baikal region

Climatically driven Late Pleistocene and Holocene vegetation changes were reconstructed based on pollen records from the sediments of Lake Kotokel and Cheremushka Bog, located on the eastern shore of Lake Baikal. The described paleoenvironmental record has higher resolution than records collected from Lake Baikal and unites individual events identified in prior studies of bottom and onshore cores. Remarkable shifts in landscapes and expansions of index plants are as follows. Forest tundra and/or forest steppe landscape with birch, spruce, Artemisia, and Poaceae prevailed at ca. 50–25 ¹⁴C kyr BP. Tundra and/or steppe vegetation dominated by Artemisia and Poaceae was typical for the Last Glacial Maximum. The expansion of shrub birch and willow occurred at ca. 15.5 ¹⁴C kyr BP. Two peaks of spruce expansion at ca. 47.5–42.4 ¹⁴C kyr BP (Karginian time) and at ca. 14.5–13 ka (Bølling-Allerød warm intervals) suggest that the condition were more humid than today. A slight increase in Artemisia at ca. 11–10.5 ¹⁴C kyr BP (13–12 ka) was indicative of the Younger Dryas event. An expansion of birch forests with fir at ca. 12–6.4 ka suggests higher humidity. The currently dominant Scots and Siberian pine forests with birch expanded since 6.4 ka.     

Practical evaluation of carbon sources of forest soils in Slovenia from stable and radio-carbon isotope measurements

Carbon sources were estimated by measuring carbon isotope ratios (??¹³C and ??¹⁴C) with accelerator mass spectrometry (AMS) in forest soils of different lithology. Six locations were selected in temperate deciduous and coniferous stands in Slovenia (?irovski vrh, Idrija, Ko?evski Rog, Pohorje, Gori?nica, and Rakitna), where carbonate rocks consisting of limestone and dolomite are abundant as underlying bedrock. Carbon isotope fractionation would not have occurred in two carbonaceous soils, since the values of both ??¹³C and ??¹⁴C changed consistently in these soils after thermal (550°C, 2?h) or chemical (1?M HCl, 24?h) treatments. Organic components were found to be predominant carbon sources (70?C100%) in the uppermost portions (0?C2?cm in depth). In deeper portions at a depth of about 30?C35?cm, soil carbon may be derived completely from underlying carbonate minerals in Idria, western part of Slovenia. The Combination of heat and chemical treatments with AMS provides practical information on soil carbon sources in carbonaceous soils.     

Use of DEM data to monitor height changes due to deforestation

Deforestation has been a major cause of climate change and other environmental problems. An accurate estimation of the volume of deforested area is needed for United Nations Reducing Emissions from Deforestation and Forest Degradation (UN-REDD+) policies implementation and global carbon accounting. Accurate information about three-dimensional (3-D) structure of forests is required to quantify forest carbon stock. This study demonstrates the use of different digital elevation models (DEMs) to monitor changes in height due to deforestation in Cambodia to support climate change mitigation policies of UN-REDD+. The Shuttle Radar Topographic Mission-DEM (SRTM-DEM), Advanced Spaceborne Thermal Emission and Reflection Radiometer Global DEM (ASTER-GDEM) and Panchromatic Remote sensing Instrument for Stereo Mapping-Digital Surface Model (PRISM-DSM) data were calibrated using Ice Cloud and land Elevation Satellite Geoscience Laser Altimeter System (ICESat–GLAS) data. The results obtained from this study clearly indicate the changes in the height of forests due to deforestation activity. The height of cutover forest generated from the PRISM-DSM and SRTM-DEM is more reliable than that from the PRISM-DSM and ASTER-GDEM data. Field data has also been used to validate the height of the cutover forests, which shows ±5 m uncertainties in the estimation.     

Re-Os isotope systematics and fractionation of siderophile elements in metal phases from CBa chondrites

We report Os isotope compositions of metal grains in two CB_a chondrites (Bencubbin and Gujba) determined using a micromilling sampling coupled with thermal ionization mass spectrometry, together with the abundances of major and trace siderophile elements obtained by electron probe microanalysis and femtosecond laser ablation inductively coupled plasma–mass spectrometry. The CB_a metal grains presented ¹⁸⁷Os/¹⁸⁸Os ratios akin to carbonaceous chondrites with limited variations (0.1257–0.1270). Most of the CB_a metal grains were scattered along a ¹⁸⁷Re-¹⁸⁷Os reference isochron of IIIAB iron meteorites, indicating that the CB_a metals experienced limited Re-Os fractionation at the time of their formation. The Re/Os ratios of sampling spots for the CB_a metals, recast from the observed ¹⁸⁷Os/¹⁸⁸Os ratios, had a positive correlation with their Os/Ir ratios. In addition, the metal grains showed a positive correlation in a Pd/Fe versus Ni/Fe diagram. These correlations suggest that the CB_a metal grains have formed via equilibrium condensation or evaporation from a gaseous reservoir at ~10⁻⁴ bar with enhanced metal abundances. Compared to the Bencubbin metals, the Gujba metals are characterized by having systematically lower Pd/Fe and Ni/Fe ratios that span subchondritic values. Such a difference was most likely induced by the compositionally heterogeneous impact plume from which the metals were condensed.