High-reliability zircon separation for hunting the oldest material on Earth: An automatic zircon separator with image-processing/microtweezers-manipulating system and double-step dating

Despite the recent development in radiometric dating of numerous zircons by LA-ICPMS, mineral separation still remains a major obstacle, particularly in the search for the oldest material on Earth. To improve the efficiency in zircon separation by an order of magnitude, we have designed/developed a new machine-an automatic zircon separator(AZS). This is designed particularly for automatic pick-up of100 μm-sized zircon grains out of a heavy mineral fraction after conventional separation procedures. The AZS operates in three modes:(1) image processing to choose targeted individual zircon grains out of all heavy minerals spread on a tray,(2) automatic capturing of the individual zircon grains with microtweezers, and(3) placing them one-by-one in a coordinated alignment on a receiving tray. The automatic capturing was designed/created for continuous mineral selecting without human presence for many hours. This software also enables the registration of each separated zircon grain for dating, by recording digital photo-image, optical(color) indices, and coordinates on a receiving tray. We developed two new approaches for the dating; i.e.(1) direct dating of zircons selected by LA-ICPMS without conventional resin-mounting/polishing,(2) high speed U-Pb dating, combined with conventional sample preparation procedures using the new equipment with multiple-ion counting detectors(LA-MIC-ICPMS).With the first approach, Pb-Pb ages obtained from the surface of a mineral were crosschecked with the interior of the same grain after resin-mounting/polishing. With the second approach, the amount of time required for dating one zircon grain is ca. 20 s, and a sample throughput of 150 grains per hour can be achieved with sufficient precision(ca. 0.5%).We tested the practical efficiency of the AZS, by analyzing an Archean Jack Hills conglomerate in Western Australia with the known oldest(4.3 Ga) zircon on Earth. Preliminary results are positive; we were able to obtain more than 194 zircons that are over 4.0 Ga out of ca. 3800 checked grains, and 9 grains were over 4300 Ma with the oldest at 4371 ± 7 Ma. This separation system by AZS, combined with the new approaches, guarantees much higher yield in the hunt for old zircons.     

Oxygen and Al‐Mg isotopic compositions of grossite‐bearing refractory inclusions from CO3 chondrites

The distribution of the short‐lived radionuclide ²⁶Al in the early solar system remains a major topic of investigation in planetary science. Thousands of analyses are now available but grossite‐bearing Ca‐, Al‐rich inclusions (CAIs) are underrepresented in the database. Recently found grossite‐bearing inclusions in CO3 chondrites provide an opportunity to address this matter. We determined the oxygen and magnesium isotopic compositions of individual phases of 10 grossite‐bearing CAIs in the Dominion Range (DOM) 08006 (CO3.0) and DOM 08004 (CO3.1) chondrites. All minerals in DOM 08006 CAIs as well as hibonite, spinel, and pyroxene in DOM 08004 are uniformly ¹⁶O‐rich (Δ¹⁷O = ?25 to ?20‰) but grossite and melilite in DOM 08004 CAIs are not; Δ¹⁷O of grossite and melilite range from ~ ?11 to ~0‰ and from ~ ?23 up to ~0‰, respectively. Even within this small suite, in the two chondrites a bimodal distribution of the inferred initial ²⁶Al/²⁷Al ratios (²⁶Al/²⁷Al)₀ is seen, with four having (²⁶Al/²⁷Al)₀ ≤1.1 × 10^?5 and six having (²⁶Al/²⁷Al)₀ ≥3.7 × 10^?5. Five of the ²⁶Al‐rich CAIs have (²⁶Al/²⁷Al)₀ within error of 4.5 × 10^?5; these values can probably be considered indistinguishable from the “canonical” value of 5.2 × 10^?5 given the uncertainty in the relative sensitivity factor for grossite measured by secondary ion mass spectrometry. We infer that the ²⁶Al‐poor CAIs probably formed before the radionuclide was fully mixed into the solar nebula. All minerals in the DOM 08006 CAIs, as well as spinel, hibonite, and Al‐diopside in the DOM 08004 CAIs retained their initial oxygen isotopic compositions, indicating homogeneity of oxygen isotopic compositions in the nebular region where the CO grossite‐bearing CAIs originated. Oxygen isotopic heterogeneity in CAIs from DOM 08004 resulted from exchange between the initially ¹⁶O‐rich (Δ¹⁷O ~?24‰) melilite and grossite and ¹⁶O‐poor (Δ¹⁷O ~0‰) fluid during hydrothermal alteration on the CO chondrite parent body; hibonite, spinel, and Al‐diopside avoided oxygen isotopic exchange during the alteration. Grossite and melilite that underwent oxygen isotopic exchange avoided redistribution of radiogenic ²⁶Mg and preserved undisturbed internal Al‐Mg isochrons. The Δ¹⁷O of the fluid can be inferred from O‐isotopic compositions of aqueously formed fayalite and magnetite that precipitated from the fluid on the CO parent asteroid. This and previous studies suggest that O‐isotope exchange during fluid–rock interaction affected most CAIs in CO ≥3.1 chondrites.     

A refractory inclusion with solar oxygen isotopes and the rarity of such objects in the meteorite record

NASA's Genesis mission revealed that the Sun is enriched in ¹⁶O compared to the Earth and Mars (the Sun's Δ¹⁷O, defined as δ¹⁷O–0.52×δ¹⁸O, is –28.4 ± 3.6‰; McKeegan et al. 2011). Materials as ¹⁶O‐rich as the Sun are extremely rare in the meteorite record. Here, we describe a Ca‐Al‐rich inclusion (CAI) from a CM chondrite that is as ¹⁶O‐enriched as the Sun (Δ¹⁷O = –29.1 ± 0.7‰). This CAI also has large nucleosynthetic anomalies in ⁴⁸Ca and ⁵⁰Ti (δ‐values are –8.1 ± 3.3 and –11.7 ± 2.4‰, respectively) and shows no clear evidence for incorporation of live ²⁶Al; (²⁶Al/²⁷Al)₀ = (0.03 ± 0.11) × 10^–5. Due to their anomalous isotopic characteristics, the rare CAIs consistent with the Genesis value could be among the first materials that formed in the solar system. In contrast to the CAI studied here, the majority of CAIs formed in or interacted with a reservoir characterized by a Δ¹⁷O value near –23.5‰. Combined with ²⁶Al‐²⁶Mg systematics, the oxygen isotopic compositions of FUN (fractionation and unidentified nuclear effects), UN, and normal CAIs suggest that nebular conditions were favorable for solids to inherit this value for an extended period of time. Many later‐formed materials, such as chondrules, planetesimals, and terrestrial planets, formed in reservoirs with Δ¹⁷O near 0‰. The distribution could be easier to explain if the common CAI value of –23.5‰, which is consistent with the Genesis value within 3σ, represented the average composition of the protoplanetary disk.     

Hydrogen fluence in Genesis collectors: Implications for acceleration of solar wind and for solar metallicity

NASA's Genesis mission was flown to capture samples of the solar wind and return them to the Earth for measurement. The purpose of the mission was to determine the chemical and isotopic composition of the Sun with significantly better precision than known before. Abundance data are now available for noble gases, magnesium, sodium, calcium, potassium, aluminum, chromium, iron, and other elements. Here, we report abundance data for hydrogen in four solar wind regimes collected by the Genesis mission (bulk solar wind, interstream low‐energy wind, coronal hole high‐energy wind, and coronal mass ejections). The mission was not designed to collect hydrogen, and in order to measure it, we had to overcome a variety of technical problems, as described herein. The relative hydrogen fluences among the four regimes should be accurate to better than ±5–6%, and the absolute fluences should be accurate to ±10%. We use the data to investigate elemental fractionations due to the first ionization potential during acceleration of the solar wind. We also use our data, combined with regime data for neon and argon, to estimate the solar neon and argon abundances, elements that cannot be measured spectroscopically in the solar photosphere.     

Molecular ecological study of <Emphasis Type="Italic">Siganus spinus</Emphasis> and <Emphasis Type="Italic">S. guttatus</Emphasis> from Okinawan waters based on mitochondrial DNA control region sequences

The mitochondrial DNA (mtDNA) control region was sequenced to examine the genetic variability and gene flow of juvenile Siganus spinus and S. guttatus. In total, 461 nucleotide sequences were obtained from 69 specimens of juvenile S. spinus from Okinawa Island and Ishigaki Island, in which 17 variable sites and 22 haplotypes were identified. Haplotype diversity (h) was high (0.9244 in Okinawa and 0.8984 in Ishigaki), whereas nucleotide diversity (π) was low (0.0063 in Okinawa and 0.0059 in Ishigaki). The two populations were not genetically distinct. Siganus guttatus, which do not form large schools at recruitment, in contrast S. spinus, were also analyzed by studying 152 individuals collected off Okinawa Island, Miyako Island, and Ishigaki Island. Of 476 nucleotide sequences, 50 were variable, and 42 haplotypes were identified. Genetic variability values were high (h = 0.8766 and π = 0.0151 in Okinawa; h = 0.9640 and π = 0.0192 in Miyako; h = 0.9161 and π = 0.0199 in Ishigaki). The Okinawa population was genetically isolated from the Miyako and Ishigaki populations. As a result, genetic diversity was high for each of these siganid populations despite their being target species for fisheries; however, the degree of inter-population gene flow was higher for S. spinus than S. guttatus, suggesting that these species exhibit different dispersal strategies.     

On the age difference between the oldest Population I and the extreme Population II stars

The age difference between the oldest Population I stars and the extreme Population II stars is investigated by comparison of observational H-R diagrams with theoretical results using the common input physics and computer program for both Populations. Chemical compositions adopted for Population I and II stars are,X=0.7 andZ=0.02, andX=2×10^–4, respectively. Evidence collected indicates that the open cluster NGC 188 and the globular cluster M92 are the representative samples of the oldest Population I and extreme Population II stars, respectively. Comparison between the observed H-R diagrams and theoretical isochrones in terms of the luminosity of the subgiant region and the turnoff point for NGC 188 and M92, respectively, then suggests that there is a significant age difference between Population I and II objects. The uncertainty of the oxygen abundance in the extreme Population II stars and its effect on their age determination is briefly discussed.     

On the properties of strange modes

Properties of the so-called strange modes occurring in linear stability calculations of stellar models are discussed. The behaviour of these modes is compared for two different sets of stellar models, for very massive zero-age main-sequence stars and for luminous hydrogen-deficient stars, both with high luminosity-to-mass ratios. We have found that the peculiar behaviour of the frequencies of the strange modes with the change of a control parameter is caused by the pulsation amplitude of a particular eigenmode being strongly confined to the outer part of the envelope, around the density inversion zone. The frequency of a strange mode changes because the depth of the confinement zone changes with the control parameter. Weakly non-adiabatic strange modes tend to be overstable because the amplitude confinement quenches the effect of radiative damping. On the other hand, extremely non-adiabatic strange modes become overstable because the perturbation of radiation force (gradient of radiation pressure) provides a restoring force that can be out of phase with the density perturbation. We discuss this mechanism by using a plane-parallel two-zone model.     

Tokaido — megalopolis of Japan

The Tokaido east coast road has been the main road of Japan since Mediaeval times, and the journey from Tokyo at one end to Kyoto or Osaka at the other, which used to take a fortnight, can now be completed in about three hours by bullet train, and an even faster linear-motor car is likely to be in operation in the near future.Already during the 18. cent., Edo (Tokyo) was the largest city in the world, with a population over a million, and the rapid urbanization of Japan's population since Meiji times, and particularly during the post-WW II period, has been quite unprecendented. In 1950, the median size of place was 13,000 and by 1975 it was 140,000. About 60 million lived in the Tokaido zone.The Kanto, Nobi and Osaka plains, adjacent to the good harbours of Tokyo, Ise and Osaka bays, enjoying the relatively mild climate of the Pacific coast, and being within 600 km of each other, have been the focii of urban and industrial development in Japan. The emergence of Tokaido megalopolis was boosted by capital investment in this zone, and was contingent upon the industriousness and high level of education of the people.The concept of megalopolis in Japan is popularly associated with rapid urbanization, poly-nuclear and linear form, and concentration of population, capital and information, all of which elements are typified by the Tokaido zone. The linear megalopolis pattern has been postulated as a more efficient growth form for high-dense society than the radial metropolitan pattern. It has even been suggested that megalopolis is a concept perceived by the intellect, its physical structure determined by information networks, metropolis being perceived by the eye and its physical structure being determined by transport and energy networks.Quite irrespective of the concept of megalopolis, there can be no denying that Japan's society is a high-dense society. In 1975, 57% of the population lived in Densely Inhabited Districts (DIDs) at minimum densities of 40 persons per hectare, and these DIDs covered only 2.2% of the land area of Japan. The current trend is for more and more people to live in DIDs, but for overall DID densities to decrease. During the past 25 years, there has been a huge influx of population into the Tokaido zone, and while until 1960 the greatest increases were in the three main metropolitan centres, as these became saturated, rapid urbanization spread into the neighbouring prefectures. Since the mid-sixties, the central metropolitan wards have begun to lose residents, but the daytime population has continued to increase, giving rise to increasingly complex commuting patterns. To give an example, the commuting field of Yokohama includes almost all the prefectures of Tokaido megalopolis.Like the image of megalopolis itself, life in Tokaido megalopolis has its good and bad aspects. Although per capita space in dwellings is increasing somewhat, housing is extremely expensive and people commute long distances. Incomes are high but environmental problems persist. There is a U-turn phenomenon, but metropolitan suburbs remain a popular choice of residence.Central management functions and knowledge and information oriented occupations are predominantly concentrated in Tokyo and Osaka, the two main nodes of Tokaido megalopolis. In the intermediate cities, new employment opportunities are stimulated by the expansion of second-level managerial functions. The transport and communications networks of Tokaido are becoming congested as mobility and information flow increase.Planning in the eighties will be affected by the switch from industries dependent on raw materials to knowledge intensive industries; from investment in production to investment in public facilities and pollution control. Within Tokaido megalopolis, there is room for local governments to expand efforts to improve the existing situation, and at its fringes to avert some of the less desirable consequences of rapid urbanization.     

Nature of solar-cycle and heliomagnetic-polarity dependence of cosmic rays, inferred from their correlation with heliomagnetic spherical surface harmonics in the period 1976–1985

Correlation of cosmic-ray intensity (I) with the solar magnetic field expanded into the spherical surface harmonics, B_ns(n 9), by Hoeksema and Scherrer has been studied using the following regression equation:

, where are subgroups of B_ns classified in ascending order of n, and τ_i is the time lag of I behind correlation coefficient between the observed and simulated intensities (I_obs, I_sml) in the period 1976–1985 is 0.87 and considerably better than that derived from any single index of solar activity. The lag time τ₃ is greater than others, indicating that the higher order magnetic disturbances effective to the cosmic-ray modulation have a longer lifetime in space than the lower order disturbances. The rigidity spectrum of the cosmic-ray intensity variation responsible for A_I due to the dipole moment is harder than those for others (A₂,A₃), indicating that the lowest order (i.e. largest scale) magnetic disturbances can modulate cosmic rays more effectively than the higher order disturbances. As another result of the present analysis, it has been found that the intensity depends also on the polarity of the polar magnetic field of the Sun; the residual (I_obs−I_sml) of the simulation changes its sign from positive to negative with a time lag (0–5 Carrington rotation periods) behind the directional change of the solar magnetic dipole moment from northward to southward, and has a softer rigidity spectrum than A_iS. The dependence is consistent with the result having been obtained in the previous period, 1936–1976, by one (K.N.) of the present authors. The polarity dependence can be found also in the 22-year variation of the time lags obtained every solar cycle in the period 1936–1985. The theoretical interpretation of these polarity dependences is discussed on the basis of the diffusion-convection-drift model.