A natural hydrate dissolution experiment on complex multi-component hydrates on the sea floor

Dissolution of natural hydrate cores was measured using time-lapse photography on the seafloor at Barkley Canyon (850 m depth and 4.17 °C). Two types of hydrate fabrics in close contact with one another were studied: a “yellow” hydrate stained with condensate oil and a “white” hydrate. From thermogenic origins, both fabrics contained methane as well as heavier hydrocarbons. These multi-component hydrates were calculated to be well within p-T stability conditions (<200 m water depth needed at 4.17 °C). While stable in pressure and temperature, the hydrates were bathed in under-saturated seawater, which promoted dissolution. The flux of gas from the shrinking yellow hydrate core was 0.15 ± 0.01 mmol gas/m² s, while the white hydrate dissolved faster at 0.25 ± 0.02 mmol gas/m² s. To determine the controlling mechanism for the observed changes in the hydrate cores, experimental results were compared with an engineering correlation for convective mass transfer. Using water velocity as a fitting parameter, the correlation agreed well with results from a previous dissolution experiment on well-characterized synthetic hydrates. Even with a number of other unknowns, when applied to the natural hydrate, the mass transfer correlation predicted the dissolution rate within 20%. This seafloor-based experiment, along with visual observations of seafloor hydrate dissolution over a 3-day period, were used to further understand the fate of natural seafloor hydrates exposed on the seafloor. By showing that mass transfer is the rate-controlling mechanism for dissolution of these natural hydrate outcrops, proper hydrodynamic calculations can be employed to give a refined estimate on hydrate dissolution rates.     

Gas hydrate measurements at Hydrate Ridge using Raman spectroscopy

Oceanic gas hydrates have been measured near the seafloor for the first time using a seagoing Raman spectrometer at Hydrate Ridge, Oregon, where extensive layers of hydrates have been found to occur near the seafloor. All of the hydrates analyzed were liberated from the upper meter of the sediment column near active gas venting sites in water depths of 770-780 m. Hydrate properties, such as structure and composition, were measured with significantly less disturbance to the sample than would be realized with core recovery. The natural hydrates measured were sI, with methane as the predominant guest component, and minor/trace amounts of hydrogen sulfide present in three of the twelve samples measured. Methane large-to-small cage occupancy ratios of the hydrates varied from 1.01 to 1.30, in good agreement with measurements of laboratory synthesized and recovered natural hydrates. Although the samples visually appeared to be solid, varying quantities of free methane gas were detected, indicating the possible presence of occluded gas in a hydrate bubble fabric.     

Optimal Estimation of Two-Dimensional Contaminant Transport

The state-space estimation technique presented herein provides a method for obtaining optimal estimates of concentrations for two-dimensional plumes in ground water. The concentration of a plume was defined as the state variable. The technique uses the Kalman filter and involves combining two independent estimates of plume concentrations. One estimate is called the process modeling data and the other is called the “measurement” data. The process modeling data is obtained from a numerical model. The “measurement” data is obtained from field measurements; however, for illustration in this paper it was generated by a different numerical model than the one used to obtain the process modeling data. The state-space technique produces a distribution of contaminant concentrations that is more accurate than either of the distributions generated by the process modeling or the “measurement” data. An example is presented to show that the technique produces significant improvements in the prediction of plume concentration distributions.     

Prey and plastic ingestion of Pacific Northern Fulmars (Fulmarus glacialis rogersii) from Monterey Bay,California

Marine plastic pollution affects seabirds, including Pacific Northern Fulmars (Fulmarus glacialis rodgersii), that feed at the surface and mistake plastic for prey or incidentally ingest it. Direct and indirect health issues can result, including satiety and possibly leading to inefficient foraging. Our objective was to examine fulmar body condition, identify cephalopod diet to species, enumerate and weigh ingested plastic, and determine if prey number and size were correlated with ingested plastics in beach-cast fulmars wintering in Monterey Bay California (2003, n = 178: 2007, n = 185). Fulmars consumed mostly Gonatus pyros, G. onyx, and G. californiensis of similar size for both years. We found a significant negative correlation between pectoral muscle index and average size of cephalopod beaks per stomach; a significant increase in plastic categories between 2003 and 2007; and no significant correlation between number and mass of plastic compared with number and size of prey for either year.     

“An oasis for us”: ‘in-between’ spaces of training for people with mental health problems in the Scottish Highlands

Training and Guidance (TAG) units in the Scottish Highlands are sites that people with mental health problems can access for training and learning activities designed to prepare them for (re-)entry into the labour market. These units also perform other, perhaps more intangible, roles in assisting trainees to cope with their mental health problems, thereby offering a supportive setting with therapeutic dimensions (albeit one not explicitly configured as delivering therapy). In this paper we explore the ‘in-between’ quality of the TAG units as spaces that might be said to possess dual economic and social roles. Using primarily qualitative evidence, we investigate both sets of roles, debating the extent to which the economic and social imperatives complement or contradict one another. The paper contributes to critical commentary on how ‘workfare’ initiatives articulate with the experiences and concerns of disabled trainees, the novelty arising in part from centralising the material spaces at the heart of such initiatives.     

Seasonal changes in pasture biomass, production and offtake under the transhumance system in northern Pakistan

An understanding of seasonal changes in pasture biomass, production and offtake of different range types is fundamentally important for the efficient management of livestock grazing. However, few studies have quantified these changes for transhumance systems, despite the fact that transhumance is still the main form of livestock management in several regions of the world and is often critical for the livelihoods of the people. One such area is the Northern Areas of Pakistan, where six villages and their pastures were selected for study. Pastures were categorized within foothill, dry temperate and alpine range types, and seasonal biomass, production and offtake of the vegetation was estimated by clipping paired caged and uncaged quadrats. The alpine range type had by far the highest biomass and offtake; the foothill and dry temperate range types were much more sparsely vegetated. Although alpine pastures were heavily used, particularly in spring, there was no evidence for consistent over-utilization of pasture resources. Within the dry temperate range type, production was highest during spring but significantly under-used. This indicates a potential for increased use of dry temperate pastures during spring, an important period both for early recovery of livestock body condition after winter and to reduce the heavy pressure on the alpine pastures at this time.