The surface radiation budget over South America in a set of regional climate models from the CLARIS-LPB project

The performance of seven regional climate models in simulating the radiation and heat fluxes at the surface over South America (SA) is evaluated. Sources of uncertainty and errors are identified. All simulations have been performed in the context of the CLARIS-LPB Project for the period 1990–2008 and are compared with the GEWEX-SRB, CRU, and GLDAS2 dataset and NCEP-NOAA reanalysis. Results showed that most of the models overestimate the net surface short-wave radiation over tropical SA and La Plata Basin and underestimate it over oceanic regions. Errors in the short-wave radiation are mainly associated with uncertainties in the representation of surface albedo and cloud fraction. For the net surface long-wave radiation, model biases are diverse. However, the ensemble mean showed a good agreement with the GEWEX-SRB dataset due to the compensation of individual model biases. Errors in the net surface long-wave radiation can be explained, in a large proportion, by errors in cloud fraction. For some particular models, errors in temperature also contribute to errors in the net long-wave radiation. Analysis of the annual cycle of each component of the energy budget indicates that the RCMs reproduce generally well the main characteristics of the short- and long-wave radiations in terms of timing and amplitude. However, a large spread among models over tropical SA is apparent. The annual cycle of the sensible heat flux showed a strong overestimation in comparison with the reanalysis and GLDAS2 dataset. For the latent heat flux, strong differences between the reanalysis and GLDAS2 are calculated particularly over tropical SA.     

Leaching of rock-concrete interfaces

Summary  It has been shown that contacts between host rock and engineered barriers may be critical in the design of deep radioactive waste repositories. Water is expected to reach the interface zone after the resaturation of the geological massive and its presence may lead to concrete leaching. Such a phenomenon could increase the interface transmissivity and compromise the confinement of radioactive waste. This paper intends to investigate the influence of concrete leaching on the hydromechanical behaviour of host rock-concrete interfaces. Some concrete specimens have been subjected to an accelerated leaching process using ammonium nitrate. The hydromechanical response of degraded concrete-rock interfaces has been studied under shearing and compared to that of sound interfaces. Consistent with the results available in the literature on bulk concrete, a loss of mechanical strength has been observed for the degraded interface. Unlike the sound specimens, the degraded interfaces do not dilate when sheared and they tend to be closed, thereby preventing water from flowing. Correspondence: O. Buzzi, Centre for Geotechnical and Materials Modelling, School of Engineering, University of Newcastle, 2308 Callaghan NSW, Australia     

Ardières-Morcille in the Beaujolais,France: A research catchment dedicated to study of the transport and impacts of diffuse agricultural pollution in rivers

The 8-km² Morcille catchment, which is a sub-catchment of the 150-km² Ardières catchment in the Beaujolais region of France, is one of the first sites in Europe where research has been conducted on surface water contamination by pesticides. A consolidated hydrological and chemical dataset has been set up with data collected since 2002 on the Morcille River and since 2011 on the Ardières River. Additional data on the ecotoxicological and ecological impacts of pesticides on aquatic microbial communities and macroinvertebrates has also been recorded in both rivers since 2005. The ‘Site Atelier Ardières-Morcille Dataset’ described here combines rainfall and stream water height measurements at gauged stations with concentrations of two trace elements and nine pesticides (mainly herbicides, fungicides and some of their metabolites) in both the Ardières and Morcille rivers. All contaminant concentration data showed spatial and temporal variability in water quality associated with pesticide use and rainfall patterns. This long-term monitoring framework made it possible to estimate the persistence of two herbicides (diuron and norflurazon) after legislation banning them. It took 4 years for diuron and more than 10 years for norflurazon concentrations to fall below 0.1 μg/L. Concurrent biological data showed a gradient of impacts consistent with chemical anthropogenic pressure, and rapid recovery of phototrophic microbial communities after the diuron ban. Finally, monitoring data on pesticide transport in a grassed strip set on a slope of the Morcille catchment confirmed that vegetative filter strips can effectively reduce diuron fluxes in surface runoff (>80% abatement) and infiltration water (>70% abatement). The full dataset offers a valuable resource for the validation of hydrological models and the development of global approaches to better understand the pressure–transport–exposure–impact chain and aquatic community resilience at the small catchment scale.     

Modeling the photosynthetically active radiation in South West Amazonia under all sky conditions

Accurate estimates of photosynthetically active radiation (PAR) are critical for the development of realistic models of plant productivity. However, in many areas such as the vast Amazon region of South America, there have been few empirical studies of PAR. Here, we analyzed the relationship between PAR and broadband solar irradiance (R _s) and formulated models to estimate PAR in two experimental sites (pasture and forest) in the Brazilian Amazon. Three different models of increasing complexity were developed based on information from R _s (model 1), R _s and clearness index (k _t; model 2), and R _s, k _t, and water vapor pressure (model 3). Estimates of PAR were generated for each season and for the entire year. All models had very high determination coefficients and indices of agreement for both pasture and forest sites. This strongly supports the use of R _s and k _t to produce robust estimates of PAR. The results obtained by annual models were close than that found by seasonal models, demonstrating that a single annual model is able to estimate PAR, albeit with lower accuracy.     

Multicomponent diffusion in garnets I: general theoretical considerations and experimental data for Fe–Mg systems

We have carried out a combined theoretical and experimental study of multicomponent diffusion in garnets to address some unresolved issues and to better constrain the diffusion behavior of Fe and Mg in almandine–pyrope-rich garnets. We have (1) improved the convolution correction of concentration profiles measured using electron microprobes, (2) studied the effect of thermodynamic non-ideality on diffusion and (3) explored the use of a mathematical error minimization routine (the Nelder-Mead downhill simplex method) compared to the visual fitting of concentration profiles used in earlier studies. We conclude that incorporation of thermodynamic non-ideality alters the shapes of calculated profiles, resulting in better fits to measured shapes, but retrieved diffusion coefficients do not differ from those retrieved using ideal models by more than a factor of 1.2 for most natural garnet compositions. Diffusion coefficients retrieved using the two kinds of models differ only significantly for some unusual Mg–Mn–Ca-rich garnets. We found that when one of the diffusion coefficients becomes much faster or slower than the rest, or when the diffusion couple has a composition that is dominated by one component (>75 %), then profile shapes become insensitive to one or more tracer diffusion coefficients. Visual fitting and numerical fitting using the Nelder-Mead algorithm give identical results for idealized profile shapes, but for data with strong analytical noise or asymmetric profile shapes, visual fitting returns values closer to the known inputs. Finally, we have carried out four additional diffusion couple experiments (25–35 kbar, 1,260–1,400 °C) in a piston-cylinder apparatus using natural pyrope- and almandine-rich garnets. We have combined our results with a reanalysis of the profiles from Ganguly et al. (1998) using the tools developed in this work to obtain the following Arrhenius parameters in D = D ₀ exp{–[Q _1bar + (P–1)ΔV ⁺]/RT} for D _Mg^* and D _Fe^*: Mg: Q _1bar = 228.3 ± 20.3 kJ/mol, D ₀ = 2.72 (±4.52) × 10⁻¹⁰ m²/s, Fe: Q _1bar = 226.9 ± 18.6 kJ/mol, D ₀ = 1.64 (±2.54) × 10⁻¹⁰ m²/s. ΔV ⁺ values were assumed to be the same as those obtained by Chakraborty and Ganguly (1992).     

Diagnosing GCM errors over West Africa using relaxation experiments. Part II: intraseasonal variability and African easterly waves

A near-global grid-point nudging of the Arpege-Climat atmospheric General Circulation Model towards ECMWF reanalyses is used to diagnose the regional versus remote origin of the summer model biases and variability over West Africa. First part of this study revealed a limited impact on the monsoon climatology compared to a control experiment without nudging, but a significant improvement of interannual variability, although the amplitude of the seasonal anomalies remained underestimated. Focus is given here on intraseasonal variability of monsoon rainfall and dynamics. The reproducible part of these signals is investigated through 30-member ensemble experiments computed for the 1994 rainy season, a year abnormally wet over the Sahel but representative of the model systematic biases. In the control experiment, Arpege-Climat simulates too few rainy days that are associated with too low rainfall amounts over the central and western Sahel, in line with the seasonal dry biases. Nudging the model outside Africa tends to slightly increase the number of rainy days over the Sahel, but has little effect on associated rainfall amounts. However, results do indicate that a significant part of the monsoon intraseasonal variability simulated by Arpege-Climat is controlled by lateral boundary conditions. Parts of the wet/dry spells over the Sahel occur in phase in the 30 members of the nudging experiment, and are therefore embedded in larger-scale variability patterns. Inter-member spread is however not constant across the selected summer season. It is partly controlled by African Easterly Waves, which show dissimilar amplitude from one member to another, but a coherent phasing in all members. A lowpass filtering of the nudging fields suggests that low frequency variations in the lateral boundary conditions can lead to eastward extensions of the African Easterly Jet, creating a favorable environment for easterly waves, while high frequency perturbations seem to control their phasing.     

Shifts in climate suitability for wine production as a result of climate change in a temperate climate wine region of Romania

Climate change is causing important shifts in the suitability of regions for wine production. Fine scale mapping of these shifts helps us to understand the evolution of vineyard climates, and to find solutions through viticultural adaptation. The aim of this study is to identify and map the structural and spatial shifts that occurred in the climatic suitability for wine production of the Cotnari wine growing region (Romania) between 1961 and 2013. Discontinuities in trends of temperature were identified, and the averages and trends of 13 climatic parameters for the 1961 to 1980 and 1981 to 2013 time periods were analysed. Using the averages of these climatic parameters, climate suitability for wine production was calculated at a resolution of 30 m and mapped for each time period, and the changes analysed. The results indicate shifts in the area’s historic climatic profile, due to an increase of heliothermal resources and precipitation constancy. The area’s climate suitability for wine production was modified by the loss of climate suitability for white table wines, sparkling wines and wine for distillates; shifts in suitability to higher altitudes by about 67 m, and a 48.6% decrease in the area suitable for quality white wines; and the occurrence of suitable climates for red wines at lower altitudes. The study showed that climate suitability for wine production has a multi-level spatial structure, with classes requiring a cooler climate being located at a higher altitude than those requiring a warmer climate. Climate change has therefore resulted in the shift of climate suitability classes for wine production to higher altitudes.     

Methodology to evaluate the renewal period of carbonate aquifers: a key tool for their management in arid and semiarid regions,with the example of Becerrero aquifer,Spain

A methodological procedure is proposed for determining the renewal period (RP), which expresses the ratio of total storage to recharge of carbonate aquifers, and it was applied to the overexploited moderate-size Becerrero carbonate aquifer (southern Spain). To this end, geological and subsurface data—time domain electromagnetic (TEM) soundings and borehole logs—were integrated to construct a three-dimensional (3D) geological model of the aquifer. The interconnected porosity was estimated by analyzing 73 rock samples. The resulting 3D geometrical model makes it possible to quantify the fractions of the aquifer having a confined or unconfined behaviour. Based on the total storage capacity (179?·?10⁶–514?·?10⁶ m³) and available aquifer recharge estimation (4.8?·?10⁶–6.4?·?10⁶ m³/year), an RP between 37 and 106 years is obtained. In view of the RP, an exploitation rate slightly lower than the average recharge of the system is recommended, so that the piezometric level will be stable but below the discharge head that is produced through the springs in natural conditions. The proposed methodology to obtain an aquifer RP and the management strategies designed accordingly are of broad interest, especially for carbonate aquifers, which are abundant in arid and semiarid regions.     

The Ardón L6 ordinary chondrite: A long‐hidden Spanish meteorite fall

We report and describe an L6 ordinary chondrite fall that occurred in Ardón, León province, Spain (longitude 5.5605°W, latitude 42.4364°N) on July 9th, 1931. The 5.5 g single stone was kept hidden for 83 yr by Rosa González Pérez, at the time an 11 yr old who had observed the fall and had recovered the meteorite. According to various newspaper reports, the event was widely observed in Northern Spain. Ardón is a very well‐preserved, fresh, strongly metamorphosed (petrologic type 6), and weakly shocked (S3) ordinary chondrite with well‐equilibrated and recrystallized minerals. The mineral compositions (olivine Fa_23.7±0.3, low‐Ca pyroxene Fs_20.4±0.2Wo_1.5±0.2, plagioclase An_10.3±0.5Ab_84.3±1.2), magnetic susceptibility (log χ = 4.95 ± 0.05 × 10^?9 m³ kg^?1), bulk density (3.49 ± 0.05 g   cm^?3), grain density (3.58 ± 0.05 g   cm^?3), and porosity (2.5 vol%) are typical for L6 chondrites. Short‐lived radionuclides confirm that the meteorite constitutes a recent fall. The ²¹Ne and ³⁸Ar cosmic ray exposure ages are both about 20–30 Ma, similar to values for many other L chondrites. The cosmogenic ²²Ne/²¹Ne ratio indicates that preatmospheric Ardón was a relatively large body. The fact that the meteorite was hidden in private hands for 83 yr makes one wonder if other meteorite falls may have experienced the same fate, thus possibly explaining the anomalously low number of falls reported in continental Spain in the 20th century.